| Period | Name | Party / Group | Notes |
|---|
| 1959–1965 | Jean-Éric Bousch | Union for the New Republic (UNR) | |
| Paul Driant | Union for the New Republic (UNR) | |
| René Jager | Popular Republican Movement (MRP) | |
| René Schwartz | Independent Republicans (RI) | |
| Pierre Fastinger | Independent Republicans (RI) | Replaced René Schwartz |
| 1965–1974 | Paul Driant | Centrist Union of Democrats for Progress (UCDP) | |
| René Jager | Centrist Union group (UC) | |
| Robert Schmitt | Independent Republicans (RI) | |
| Jean-Éric Bousch | Union for the New Republic (UNR) | |
| 1974–1983 | Jean-Marie Rausch | European Democratic and Social Rally group (RDSE) | |
| André Bohl | Centrist Union group (UC) | |
| René Jager | Centrist Union of Democrats for Progress (UCDP) | Died in 1983 |
| Rémi Cabocel | RASNAG | Replaced René Jager |
| Robert Schmitt | Independent Republicans (RI) | |
| 1983–1992 | Jean-Marie Rausch | European Democratic and Social Rally group (RDSE) | Appointed to cabinet in 1988 |
| Jean-Éric Bousch | Rally for the Republic (RPR) | Replaced Jean-Marie Rausch in 1988 |
| Roger Husson | Rally for the Republic (RPR) | |
| André Bohl | Centrist Union group (UC) | |
| Paul Souffrin | French Communist Party (PCF) | |
| Jean-Pierre Masseret | Socialist Party (PS) | |
| 1992–2001 | André Bohl | Centrist Union group (UC) | |
| Charles Metzinger | Socialist Party (PS) | |
| Jean-Pierre Masseret | Socialist Party (PS) | Appointed to cabinet in 1997 |
| Roger Hesling | Socialist and Republican group | From 1997, replacing Jean-Pierre Masseret |
| Jean-Marie Rausch | European Democratic and Social Rally group (RDSE) | |
| Roger Husson | Rally for the Republic (RPR) | Died in 2000 |
| Alain Hethener | Rally for the Republic (RPR) | Replaced Roger Husson in 2000 |
| 2001–2011 | Philippe Leroy | Union for a Popular Movement (UMP) | |
| Jean-Pierre Masseret | Socialist Party (PS) | |
| Jean-Louis Masson | Union for a Popular Movement (UMP) | |
| Gisèle Printz | Socialist Party (PS) | |
| Jean-Marc Todeschini | Socialist Party (PS) | |
| 2011–2017 | Philippe Leroy | Union for a Popular Movement (UMP) then The Republicans (LR) | |
| François Grosdidier | Union for a Popular Movement (UMP) then The Republicans (LR) | |
| Jean-Louis Masson | Miscellaneous right (DVD) | |
| Jean-Marc Todeschini | Socialist Party (PS) | Appointed to cabinet from 2014 to 2017 |
| Patrick Abate | Communist, Republican, Citizen and Ecologist group | Replaced Jean-Marc Todeschini from 2014 to 2017 |
| Gisèle Printz | Socialist Party (PS) | Resigned in 2014 |
| Jean-Pierre Masseret | La République En Marche (REM) | Replaced Gisèle Printz in 2014 |
| 2017–2023 | Christine Herzog | Miscellaneous right (DVD) | |
| François Grosdidier | The Republicans (LR) | |
| Jean-Louis Masson | Miscellaneous right (DVD) | |
| Jean-Marc Todeschini | Socialist Party (PS) | |
| Jean-Marie Mizzon | Miscellaneous right (DVD) – Centrist Union group (UC) | |
