Magnesioferrite | |
---|---|
General | |
Category | Oxide minerals Spinel group Spinel structural group |
Formula (repeating unit) | Mg(Fe3+)2O4 |
IMA symbol | Mfr [1] |
Strunz classification | 4.BB.05 |
Crystal system | Cubic |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fd3m |
Unit cell | a = 8.3866 Å; Z = 8 |
Identification | |
Color | Black to brownish black |
Crystal habit | As octahedral crystals, massive granular |
Twinning | Twin plane {111}, contact twins |
Cleavage | On {111} |
Fracture | Uneven |
Tenacity | Brittle |
Mohs scale hardness | 6 - 6.5 |
Luster | Metallic, semimetallic, dull |
Streak | Dark red |
Diaphaneity | Opaque, transparent in thin fragments |
Specific gravity | 4.55 – 4.65 measured |
Optical properties | Isotropic |
Refractive index | n = 2.38 |
Other characteristics | Magnetic |
References | [2] [3] [4] |
Magnesioferrite is a magnesium iron oxide mineral, a member of the magnetite series of spinels. Magnesioferrite crystallizes as black metallic octahedral crystals. It is named after its chemical composition of magnesium and ferric iron. The density is 4.6 - 4.7 (average = 4.65), and the diaphaniety is opaque. Occurs as well-formed fine sized crystals or massive and granular. Its hardness is 6-6.5. It has a metallic luster and a dark red streak.
It occurs in fumaroles, as a result of combustion metamorphism and coal seam fires, in glass spherules related to meteorite impacts, and as accessory phase in kimberlites and carbonatites. [2]
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
Actinolite is an amphibole silicate mineral with the chemical formula Ca2(Mg4.5-2.5Fe2+0.5-2.5)Si8O22(OH)2.
Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc and manganese substitute in the iron site and trivalent iron can substitute for aluminium.
Chalcanthite is a richly colored blue-green water-soluble sulfate mineral CuSO4 · 5H2O. It is commonly found in the late-stage oxidation zones of copper deposits. Due to its ready solubility, chalcanthite is more common in arid regions.
Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO2) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass.
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).
Erythrite or red cobalt is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula Ni
3(AsO
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Rhodonite is a manganese inosilicate, (Mn, Fe, Mg, Ca)SiO3 and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (the name comes from the Greek ῥόδος rhodos, rosy), often tending to brown because of surface oxidation.
Tephroite is the manganese endmember of the olivine group of nesosilicate minerals with the formula Mn2SiO4. A solid solution series exists between tephroite and its analogues, the group endmembers fayalite and forsterite. Divalent iron or magnesium may readily replace manganese in the olivine crystal structure.
Braunite is a silicate mineral containing both di- and tri-valent manganese with the chemical formula: Mn2+Mn3+6[O8|SiO4]. Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium.
Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.
Aegirine is a member of the clinopyroxene group of inosilicate minerals. Aegirine is the sodium endmember of the aegirine-augite series. Aegirine has the chemical formula NaFeSi2O6 in which the iron is present as Fe3+. In the aegirine-augite series the sodium is variably replaced by calcium with iron(II) and magnesium replacing the iron(III) to balance the charge. Aluminium also substitutes for the iron(III). Acmite is a fibrous, green-colored variety.
Lazulite ((Mg,Fe2+)Al2(PO4)2(OH)2) is a blue, phosphate mineral containing magnesium, iron, and aluminium phosphate. Lazulite forms one endmember of a solid solution series with the darker iron rich scorzalite.
Fukuchilite, Cu
3FeS
8, is a copper iron sulfide named after the Japanese mineralogist Nobuyo Fukuchi (1877–1934), that occurs in ore bodies of gypsum-anhydrite at the intersection points of small masses of barite, covellite, gypsum and pyrite, and is mostly found in the Hanawa mine in the Akita prefecture of Honshū, Japan where it was first discovered in 1969. It occurs in masses within the third geologic unit of the Kuroko type deposits within the mine.
Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula Mn2+Al2O4.
Xonotlite, or eakleite, is a mineral of general formula Ca6Si6O17(OH)2 named by the German mineralogist Karl Friedrich August Rammelsberg in 1866. The name originates from its discovery locality, Tetela de Xonotla, Puebla, Mexico. Although it was discovered in 1866, it was first described in 1959. It is approved by the IMA, but it is a grandfathered species, meaning the name supposedly represents a valid species til this day.
Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2Al
4Si
2O
10(OH)
4. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.
Cylindrite is a sulfosalt mineral containing tin, lead, antimony and iron with formula: Pb3Sn4FeSb2S14. It forms triclinic pinacoidal crystals which often occur as tubes or cylinders which are in fact rolled sheets. It has a black to lead grey metallic colour with a Mohs hardness of 2 to 3 and a specific gravity of 5.4.
Gatehouseite is a manganese hydroxy phosphate mineral with formula Mn5(PO4)2(OH)4. First discovered in 1987, it was identified as a new mineral species in 1992 and named for Bryan M. K. C. Gatehouse (born 1932). As of 2012, it is known from only one mine in South Australia.
Dorrite is a silicate mineral that is isostructural to the aenigmatite group. Although it is most chemically similar to the mineral rhönite [Ca2Mg5Ti(Al2Si4)O20], the lack of titanium (Ti) and presence of Fe3+ influenced dorrite's independence. Dorrite is named for Dr. John (Jack) A. Dorr, a late professor at the University of Michigan that researched in outcrops where dorrite was found in 1982. This mineral is sub-metallic resembling colors of brownish-black, dark brown, to reddish brown.