Marine diesel oil

Last updated

Marine diesel oil (MDO) is a type of distillate diesel oil. Marine diesel oil is also called distillate marine diesel. [1] MDO is widely used by medium speed and medium/high speed marine diesel engines. It is also used in the larger low speed and medium speed propulsion engine which normally burn residual fuel. [1] Those fuels result from a catalytic cracking and visbreaking refinery. [1] Marine diesel oil has been condemned for its nimiety of sulfur, so many countries and organizations established regulations and laws on MDO use. Due to its lower price compared to more refined fuel, MDO is favored particularly by the shipping industry. [2]

Contents

Specification

ISO 8217 of the International Standards Organization (ISO) is the primary standard of MDO. [2]

Marine fuels range in viscosity from less than one centistoke (cSt) to about 700 cSt at 50°C (122°F). [2] (1 cSt = 1 mm2/s.) And higher viscosity grades are preheated during use to bring their viscosity into the range suitable for fuel injection (8 to 27 cSt). [2] But MDO does not need to be preheated before using. According to Chevron, MDO has a sulfur limit varies from 1 to 4.5 percent by mass for different grades and Sulfur Emission Control Areas (SECAs). [2]

Manufacturing procedure

MDO is made from a catalytic cracking and visbreaking refinery. [3] The catalytic cracking operation breaks large molecules into small molecules. It happens in high temperature and with appropriate catalyst. [3] Visbreaking is a process that turn the bottom product of the vacuum unit, which has extremely high viscosity, into lower viscosity, marketable product. [3] In visbreaking, a relatively mild thermal cracking operation is performed. [3] And the amount of cracking is limited by the overruling requirement to safeguard the heavy fuel stability. [3]

Use

The market of MDO is much smaller than on-highway diesel. According to the 2004 US diesel fuel sales statistics from US Department of Energy, Energy Information Administration, marine shipping only makes up 3.7% of the total diesel market. [2] On the other hand, on-highway diesel makes up 59.5% of diesel fuel sales. [2] This small sales share of MDO is due to the high proportion of petroleum resid that made it can be used on large marine engines. [2] According to Chevron, petroleum resid, or inorganic salts, in the fuel result in injector tip deposits that prevent the injector from creating the desired fuel spray pattern. [2] But those low-speed, large marine diesel engines are appropriate for using fuel containing large amounts of petroleum resid. [2]

Regulations and restrictions

The International Maritime Organization (IMO) develops regulations for marine shipping. Among those regulations, MARPOL (the International Convention for the Prevention of Pollution from Ships) is the most widely adopted one. [2] MARPOL is the main international convention covering the prevention of operational or accidental pollution of the marine environment by ships. [2] Inside the IMO, there is a committee called the Marine Environment Protection Committee (MEPC). MEPC has meetings periodically to discusses resolutions to current marine pollution. [4]

Related Research Articles

<span class="mw-page-title-main">International Maritime Organization</span> Specialised agency of the United Nations

The International Maritime Organization is a specialised agency of the United Nations responsible for regulating maritime transport. The IMO was established following agreement at a UN conference held in Geneva in 1948 and the IMO came into existence ten years later, meeting for the first time on 17 March 1958. Headquartered in London, United Kingdom, the IMO, in 2024, has 176 Member States and three Associate Members.

<span class="mw-page-title-main">Diesel fuel</span> Liquid fuel used in diesel engines

Diesel fuel, also called diesel oil, heavy oil (historically) or simply diesel, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel. Therefore, diesel fuel needs good compression ignition characteristics.

<span class="mw-page-title-main">Oil refinery</span> Facility that processes crude oil

An oil refinery or petroleum refinery is an industrial process plant where petroleum is transformed and refined into products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemical feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day.

<span class="mw-page-title-main">MARPOL 73/78</span> International marine environmental convention

The International Convention for the Prevention of Pollution from Ships, 1973 as modified by the Protocol of 1978, or "MARPOL 73/78" is one of the most important international marine environmental conventions. It was developed by the International Maritime Organization with an objective to minimize pollution of the oceans and seas, including dumping, oil and air pollution.

<span class="mw-page-title-main">Fuel oil</span> Petroleum product burned to generate motive power or heat

Fuel oil is any of various fractions obtained from the distillation of petroleum. Such oils include distillates and residues. Fuel oils include heavy fuel oil, marine fuel oil (MFO), furnace oil (FO), gas oil (gasoil), heating oils, diesel fuel, and others.

<span class="mw-page-title-main">Exhaust gas</span> Gases emitted as a result of fuel reactions in combustion engines

Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through an exhaust pipe, flue gas stack, or propelling nozzle. It often disperses downwind in a pattern called an exhaust plume.

A visbreaker is a processing unit in an oil refinery whose purpose is to reduce the quantity of residual oil produced in the distillation of crude oil and to increase the yield of more valuable middle distillates by the refinery. A visbreaker thermally cracks large hydrocarbon molecules in the oil by heating in a furnace to reduce its viscosity and to produce small quantities of light hydrocarbons.. The process name of "visbreaker" refers to the fact that the process reduces the viscosity of the residual oil. The process is non-catalytic.

<span class="mw-page-title-main">Petroleum coke</span> Solid carbon-rich material

Petroleum coke, abbreviated coke, pet coke or petcoke, is a final carbon-rich solid material that derives from oil refining, and is one type of the group of fuels referred to as cokes. Petcoke is the coke that, in particular, derives from a final cracking process—a thermo-based chemical engineering process that splits long chain hydrocarbons of petroleum into shorter chains—that takes place in units termed coker units. Stated succinctly, coke is the "carbonization product of high-boiling hydrocarbon fractions obtained in petroleum processing ". Petcoke is also produced in the production of synthetic crude oil (syncrude) from bitumen extracted from Canada's tar sands and from Venezuela's Orinoco oil sands. In petroleum coker units, residual oils from other distillation processes used in petroleum refining are treated at a high temperature and pressure leaving the petcoke after driving off gases and volatiles, and separating off remaining light and heavy oils. These processes are termed "coking processes", and most typically employ chemical engineering plant operations for the specific process of delayed coking.

An oily water separator (OWS) (marine) is a piece of equipment specific to the shipping or marine industry. It is used to separate oil and water mixtures into their separate components. This page refers exclusively to oily water separators aboard marine vessels. They are found on board ships where they are used to separate oil from oily waste water such as bilge water before the waste water is discharged into the environment. These discharges of waste water must comply with the requirements laid out in Marpol 73/78.

<span class="mw-page-title-main">Mazut</span> Fuel oil

Mazut is a low-quality heavy fuel oil, used in power plants and similar applications in Iran and some countries of the former Soviet Union. In the West, through fluid catalytic cracking, mazut is distilled into diesel and other light distillates. Mazut may be used for heating houses in some parts of the former USSR and in countries of the Far East that do not have the facilities to blend or break it down into more conventional petro-chemicals.

<span class="mw-page-title-main">Marine propulsion</span> Systems for generating thrust for ships and boats on water

Marine propulsion is the mechanism or system used to generate thrust to move a watercraft through water. While paddles and sails are still used on some smaller boats, most modern ships are propelled by mechanical systems consisting of an electric motor or internal combustion engine driving a propeller, or less frequently, in pump-jets, an impeller. Marine engineering is the discipline concerned with the engineering design process of marine propulsion systems.

<span class="mw-page-title-main">Automotive oil recycling</span> The process of recycling used engine and motor oils

Automotive oil recycling involves the recycling of used oils and the creation of new products from the recycled oils, and includes the recycling of motor oil and hydraulic oil. Oil recycling also benefits the environment: increased opportunities for consumers to recycle oil lessens the likelihood of used oil being dumped on lands and in waterways. For example, one gallon of motor oil dumped into waterways has the potential to pollute one million gallons of water.

<span class="mw-page-title-main">Environmental impact of shipping</span> Ocean pollution

The environmental impact of shipping include air pollution, water pollution, acoustic, and oil pollution. Ships are responsible for more than 18% of nitrogen oxides pollution, and 3% of greenhouse gas emissions.

<span class="mw-page-title-main">Petroleum refining processes</span> Methods of transforming crude oil

Petroleum refining processes are the chemical engineering processes and other facilities used in petroleum refineries to transform crude oil into useful products such as liquefied petroleum gas (LPG), gasoline or petrol, kerosene, jet fuel, diesel oil and fuel oils.

Emission control areas (ECAs), or sulfur emission control areas (SECAs), are sea areas in which stricter controls were established to minimize airborne emissions from ships as defined by Annex VI of the 1997 MARPOL Protocol.

Marpol Annex I is the first implementation made by Marpol 73/78, one of the most important international marine environmental conventions. The convention was designed to minimize pollution of the seas from ships. The objective of the convention is to preserve the marine environment through the complete elimination of pollution by oil and other harmful substances and the minimization of accidental discharge of such substances. The Marpol Annex I began to be enforced on October 2, 1983, and it details the prevention of pollution by oil and oily water.

Port reception facilities are a place that international shipping ports must provide to collect residues, oily mixtures, and garbage generated from an ocean-going vessel. contaminants generated by ships cannot be discharged directly to the ocean. According to MARPOL 73/78 they must be collected by the Port reception facilities all around the world. The Port reception facility must be able to receive dirty oil and other contaminants, and also provide quick and efficient services.

<span class="mw-page-title-main">Heavy fuel oil</span> Fuel oils of a tar-like consistency

Heavy fuel oil (HFO) is a category of fuel oils of a tar-like consistency. Also known as bunker fuel, or residual fuel oil, HFO is the result or remnant from the distillation and cracking process of petroleum. For this reason, HFO is contaminated with several different compounds including aromatics, sulfur, and nitrogen, making emissions upon combustion more polluting compared to other fuel oils. HFO is predominantly used as a fuel source for marine vessel propulsion using marine diesel engines due to its relatively low cost compared to cleaner fuel sources such as distillates. The use and carriage of HFO on-board vessels presents several environmental concerns, namely the risk of oil spill and the emission of toxic compounds and particulates including black carbon. The use of HFOs is banned as a fuel source for ships travelling in the Antarctic as part of the International Maritime Organization's (IMO) International Code for Ships Operating in Polar Waters (Polar Code). For similar reasons, an HFO ban in Arctic waters is currently being considered.

<span class="mw-page-title-main">Cruise ship pollution in Europe</span>

Cruise ship pollution in Europe is a major part of the environmental impact of shipping. Most cruise ship companies operating in European exclusive economic zones (EEZs) are part of two mega corporations: Carnival Corporation & plc and the Royal Caribbean Group. In 2017, Carnival's cruise ships alone caused ten times more sulfur oxide (SOx) air pollution than all of Europe's cars (over 260 million) combined, as the ship fuel emits about 2,000 times more sulfur oxides than normal diesel fuel. All cruise ships together also accounted for 15% of the nitrogen oxide (NOx) particles emitted by all of Europe's passenger vehicles, and released large amounts of carbon dioxide (CO2), phosphorus (P4), soot, heavy metals, and other particulates into the atmosphere as well.

<span class="mw-page-title-main">Initial IMO Strategy on the reduction of GHG emissions from ships</span> Framework on greenhouse gases and maritime shipping

The Initial IMO Strategy on the reduction of GHG emissions from ships, or Initial IMO GHG Strategy, is the framework through which the International Maritime Organization (IMO) aims to reduce greenhouse gas (GHG) emissions from international maritime shipping. GHG emissions from shipping are about 3% of total GHG emissions, and under this strategy the IMO envisions their elimination within this century. However many companies and organizations say shipping should be decarbonized by 2050.

References

  1. 1 2 3 "Marine Diesel Fuel Oil" (PDF). Environment Canada Oil Properties Database. Environment Canada, Emergencies Science and Technology Division. Retrieved 23 April 2015.
  2. 1 2 3 4 5 6 7 8 9 10 11 12 Chevron. "Diesel Fuels Technical Review" (PDF). Chevron Global Marketing. Chevron. Archived from the original (PDF) on 11 April 2015. Retrieved 4 May 2015.
  3. 1 2 3 4 5 "Everything You Need to Know About Marine Fuels" (PDF). Chevron Global Marine Products. Chevron. Archived from the original (PDF) on 30 March 2015. Retrieved 4 May 2015.
  4. "MEPC Official Documents". Marine Environment Protection Committee. IMO. Retrieved 7 May 2015.