Metacinnabar

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Metacinnabar
Metacinnabar-233443.jpg
General
Category Sulfide mineral
Formula
(repeating unit)
HgS
IMA symbol Mcin [1]
Strunz classification 2.CB.05a
Crystal system Cubic
Crystal class Hextetrahedral (43m)
H-M symbol: (4 3m)
Space group F43m
Unit cell a = 5.8717(5) Å; Z = 4
Structure
Jmol (3D) Interactive image
Identification
ColorGrayish black
Crystal habit Massive, rarely as tetrahedral crystals, as incrustations
Twinning Common as lamellae on {111}
Cleavage None
Fracture Subconchoidal
Tenacity Brittle
Mohs scale hardness3
Luster Metallic
Streak Black
Diaphaneity Opaque
Specific gravity 7.7–7.8
References [2] [3] [4]

Metacinnabar is the cubic form of mercury sulfide (HgS). It is the high temperature form and trimorphous with cinnabar (trigonal structure) and the higher temperature hypercinnabar (hexagonal structure). It occurs with cinnabar in mercury deposits and is associated with native mercury, wurtzite, stibnite, marcasite, realgar, calcite, barite, chalcedony and hydrocarbons. [2]

It was first described in 1870 for an occurrence in the Redington mine, Knoxville, Napa County, California. [3] [4]

Related Research Articles

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Cinnabar, or cinnabarite, is the bright scarlet to brick-red form of mercury(II) sulfide (HgS). It is the most common source ore for refining elemental mercury and is the historic source for the brilliant red or scarlet pigment termed vermilion and associated red mercury pigments.

<span class="mw-page-title-main">Sphalerite</span> Zinc-iron sulfide mineral

Sphalerite is a sulfide mineral with the chemical formula (Zn,Fe)S. It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Valley type, and volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite, calcite, dolomite, quartz, rhodochrosite, and fluorite.

<span class="mw-page-title-main">Stibnite</span> Sulfide mineral

Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the Greek στίβι stibi through the Latin stibium as the former name for the mineral and the element antimony.

<span class="mw-page-title-main">Mercury(II) oxide</span> Chemical compound

Mercury(II) oxide, also called mercuric oxide or simply mercury oxide, is the inorganic compound with the formula HgO. It has a red or orange color. Mercury(II) oxide is a solid at room temperature and pressure. The mineral form montroydite is very rarely found.

<span class="mw-page-title-main">Mercury sulfide</span> Chemical compound

Mercury sulfide, or mercury(II) sulfide is a chemical compound composed of the chemical elements mercury and sulfur. It is represented by the chemical formula HgS. It is virtually insoluble in water.

<span class="mw-page-title-main">Idrialite</span>

Idrialite is a rare hydrocarbon mineral with approximate chemical formula C22H14.

<span class="mw-page-title-main">Lorándite</span>

Lorándite is a thallium arsenic sulfosalt with the chemical formula: TlAsS2. Though rare, it is the most common thallium-bearing mineral. Lorandite occurs in low-temperature hydrothermal associations and in gold and mercury ore deposits. Associated minerals include stibnite, realgar, orpiment, cinnabar, vrbaite, greigite, marcasite, pyrite, tetrahedrite, antimonian sphalerite, arsenic and barite.

<span class="mw-page-title-main">Tiemannite</span>

Tiemannite is a mineral, mercury selenide, formula HgSe. It occurs in hydrothermal veins associated with other selenides, or other mercury minerals such as cinnabar, and often with calcite. Discovered in 1855 in Germany, it is named after Johann Carl Wilhelm Tiemann (1848–1899).

<span class="mw-page-title-main">Livingstonite</span>

Livingstonite is a mercury antimony sulfosalt mineral. It occurs in low-temperature hydrothermal veins associated with cinnabar, stibnite, sulfur and gypsum.

<span class="mw-page-title-main">Carpathite</span> Very rare mineral

Carpathite is a very rare hydrocarbon mineral, consisting of exceptionally pure coronene (C24H12), a polycyclic aromatic hydrocarbon. The name has been spelled karpatite and the mineral was improperly renamed pendletonite.

<span class="mw-page-title-main">Corderoite</span> Extremely rare mercury sulfide chloride mineral

Corderoite is an extremely rare mercury sulfide chloride mineral with formula Hg3S2Cl2. It crystallizes in the isometric crystal system. It is soft, 1.5 to 2 on the Mohs scale, and varies in color from light gray to black and rarely pink or yellow.

<span class="mw-page-title-main">Montroydite</span> Mercury(II) oxide mineral, HgO

Montroydite is the mineral form of mercury(II) oxide with formula HgO. It is a rare mercury mineral. It was first described for an occurrence in the mercury deposit at Terlingua, Texas and named for Montroyd Sharp who was an owner of the deposit.

Mosesite is a very rare mineral found in few locations. It is a mercury mineral found as an accessory in deposits of mercury, often in conjunction with limestone. It is known to be found in the U.S. states of Texas and Nevada, and the Mexican states of Guerrero and Querétaro. It was named after Professor Alfred J. Moses (1859–1920) for his contributions to the field of mineralogy in discovering several minerals found alongside mosesite. The mineral itself is various shades of yellow and a high occurrence of spinel twinning. It becomes isotropic when heated to 186 °C (367 °F).

<span class="mw-page-title-main">Moschellandsbergite</span> Isometric mineral made up of a silver-white amalgam of mercury and silver

Moschellandsbergite is a rare isometric mineral made up of a silver-white amalgam of mercury and silver with the chemical makeup Ag2Hg3.

<span class="mw-page-title-main">Mercury (element)</span> Chemical element, symbol Hg and atomic number 80

Mercury is a chemical element; it has symbol Hg and atomic number 80. It is also known as quicksilver and was formerly named hydrargyrum from the Greek words hydor (water) and argyros (silver). A heavy, silvery d-block element, mercury is the only metallic element that is known to be liquid at standard temperature and pressure; the only other element that is liquid under these conditions is the halogen bromine, though metals such as caesium, gallium, and rubidium melt just above room temperature.

Clearcreekite is a carbonate mineral, polymorphous with peterbaylissite. The chemical formula of clearcreekite is Hg(1+)3CO3(OH)∙2H2O. It has a pale greenish yellow color and streak with tabular subhedral crystals and good cleavage on {001}. It is transparent with vitreous luster and uneven fracture. Its density (calculated from the idealized formula) is 6.96 g/cm3. The mineral is monoclinic with the space group P2/c. Clearcreekite is an extremely rare mineral from the Clear Creek mercury mine, New Idria district, San Benito County, California. It was probably formed after the alteration of other mercury minerals such as cinnabar. The mineral is named after the locality where it was found.

<span class="mw-page-title-main">Getchellite</span>

Getchellite is a rare sulfide of arsenic and antimony, AsSbS3, that was discovered by B. G. Weissberg of the New Zealand Department of Scientific and Industrial Research in 1963, and approved as a new species by the International Mineralogical Association in 1965. Many metal sulfides are grey to black, but a few are brightly colored. Orpiment is yellow to brownish gold, cinnabar is deep red and getchellite is a bright orange red.

<span class="mw-page-title-main">Wattersite</span>

Wattersite is a rare mercury chromate mineral with the formula Hg+14Hg+2Cr+6O6. It occurs in association with native mercury and cinnabar in a hydrothermally altered serpentinite. It was first described from Clear Creek claim, San Benito County, California, USA in 1961. It was named to honor Californian mineral collector Lucius "Lu" Watters.

<span class="mw-page-title-main">Kenhsuite</span> Halide-sulfide mineral

Kenhsuite is a mercury sulfide with chloride ions. It was described as a species from specimens obtained at the McDermitt mine, in Opalite, Humboldt Nevada county, (USA). The name is a tribute to Dr. Kenneth Junghwa Hsu. Professor Emeritus of the Swiss Federal Institute of Technology, Zurich (Switzerland).

<span class="mw-page-title-main">Edoylerite</span>

Edoylerite is a rare mercury containing mineral. Edoylerite was first discovered in 1961 by Edward H. Oyler, whom the mineral is named after, in a meter-sized boulder at the Clear Creek claim in San Benito County, California. The Clear Creek claim is located near the abandoned Clear Creek mercury mine. The material from the boulder underwent several analyses including, X-ray powder diffraction (XRD), a single crystal study, and a preliminary electron microprobe analysis (EMA). Using these analyses it was determined that this was a new mineral but the nature of the material at the time prevented further investigation. It was not until 1986, with the discovery of crystals large enough for a crystal structure determination and a sufficient quantity for a full mineralogical characterization, that the study was renewed. The new edoylerite crystals were found in the same area at the Clear Creek claim but were situated in an outcrop of silica-carbonate rock. This silica-carbonate rock was mineralized by cinnabar following the hydrothermal alteration of the serpentinite in the rock. Edoylerite is a primary alteration product of cinnabar. Though found with cinnabar, the crystals of edoylerite do not typically exceed 0.5mm in length. The ideal chemical formula for edoylerite is Hg32+Cr6+O4S2

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Metacinnabar in the Handbook of Mineralogy
  3. 1 2 Metacinnabar on Mindat.org
  4. 1 2 Metacinnabar data on Webmineral