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Nanoarchitectonics is a technology allowing to arrange nano-sized structural units, usually a group of atoms or molecules, in an intended configuration. It employs two major processes: nano-creation and nano-organization. Nano-organization involves re-arrangement of the structural units in a desired pattern, while nano-creation is synthesis of new materials that do not exist in nature. For example, by peeling atomic sheets off graphite slab, a novel nano-material graphene can be obtained, which has very different properties from graphite.
Nanoarchitectonics is not limited to nano-creation and nano-organization, but rather employs those techniques to understand and use the ultimate functions of materials. The important technologies to achieve this goal involve manipulation of single atoms and molecules through physical interactions, chemical reactions, applied fields, or self-assembly.
A typical example of nano-organization is the development of a nanoelectronics circuit. Challenging electronic devices are produced experimentally, using previously discovered materials, such as carbon nanotubes, fullerenes, graphene, single molecules having functional groups, etc. However, their practical use is impossible without a technology (nano-organization) to integrate and link these devices into a system.
Examples of those technologies are: [1]
The importance of architectonics in nanoscience and nanotechnology was first accentuated in 1999 at the University of California, Los Angeles (UCLA). [1] [2] Next year, the first International Symposium on Nanoarchitectonics has been held in Tsukuba, Japan. In 2003, the term nanoarchitectonics was first mentioned in a peer-reviewed article, by a German group from the Freie Universität Berlin, and the same year a dedicated research center, Functional Engineered Nano Architectonics, has been opened at UCLA. In 2007, similar centers have been established in Tsukuba: the International Center for Materials Nanoarchitectonics at NIMS and Interfacial Nanoarchitectonics at AIST. [1]
Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula BN. It exists in various crystalline forms that are isoelectronic to a similarly structured carbon lattice. The hexagonal form corresponding to graphite is the most stable and soft among BN polymorphs, and is therefore used as a lubricant and an additive to cosmetic products. The cubic variety analogous to diamond is called c-BN; it is softer than diamond, but its thermal and chemical stability is superior. The rare wurtzite BN modification is similar to lonsdaleite but slightly softer than the cubic form.
Nanotechnology is the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). At this scale, commonly known as the nanoscale, surface area and quantum mechanical effects become important in describing properties of matter. This definition of nanotechnology includes all types of research and technologies that deal with these special properties. It is common to see the plural form "nanotechnologies" as well as "nanoscale technologies" to refer to research and applications whose common trait is scale. An earlier understanding of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabricating macroscale products, now referred to as molecular nanotechnology.
Mechanosynthesis is a term for hypothetical chemical syntheses in which reaction outcomes are determined by the use of mechanical constraints to direct reactive molecules to specific molecular sites. There are presently no non-biological chemical syntheses which achieve this aim. Some atomic placement has been achieved with scanning tunnelling microscopes.
Self-assembly is a process in which a disordered system of pre-existing components forms an organized structure or pattern as a consequence of specific, local interactions among the components themselves, without external direction. When the constitutive components are molecules, the process is termed molecular self-assembly.
Nanomaterials describe, in principle, chemical substances or materials of which a single unit is sized between 1 and 100 nm.
Nanoelectromechanical systems (NEMS) are a class of devices integrating electrical and mechanical functionality on the nanoscale. NEMS form the next logical miniaturization step from so-called microelectromechanical systems, or MEMS devices. NEMS typically integrate transistor-like nanoelectronics with mechanical actuators, pumps, or motors, and may thereby form physical, biological, and chemical sensors. The name derives from typical device dimensions in the nanometer range, leading to low mass, high mechanical resonance frequencies, potentially large quantum mechanical effects such as zero point motion, and a high surface-to-volume ratio useful for surface-based sensing mechanisms. Applications include accelerometers and sensors to detect chemical substances in the air.
Graphene is a carbon allotrope consisting of a single layer of atoms arranged in a honeycomb planar nanostructure. The name "graphene" is derived from "graphite" and the suffix -ene, indicating the presence of double bonds within the carbon structure.
James Kazimierz Gimzewski is a Scottish physicist of Polish descent who pioneered research on electrical contacts with single atoms and molecules and light emission using scanning tunneling microscopy (STM).
The history of nanotechnology traces the development of the concepts and experimental work falling under the broad category of nanotechnology. Although nanotechnology is a relatively recent development in scientific research, the development of its central concepts happened over a longer period of time. The emergence of nanotechnology in the 1980s was caused by the convergence of experimental advances such as the invention of the scanning tunneling microscope in 1981 and the discovery of fullerenes in 1985, with the elucidation and popularization of a conceptual framework for the goals of nanotechnology beginning with the 1986 publication of the book Engines of Creation. The field was subject to growing public awareness and controversy in the early 2000s, with prominent debates about both its potential implications as well as the feasibility of the applications envisioned by advocates of molecular nanotechnology, and with governments moving to promote and fund research into nanotechnology. The early 2000s also saw the beginnings of commercial applications of nanotechnology, although these were limited to bulk applications of nanomaterials rather than the transformative applications envisioned by the field.
Nanoelectronics refers to the use of nanotechnology in electronic components. The term covers a diverse set of devices and materials, with the common characteristic that they are so small that inter-atomic interactions and quantum mechanical properties need to be studied extensively. Some of these candidates include: hybrid molecular/semiconductor electronics, one-dimensional nanotubes/nanowires or advanced molecular electronics.
The following outline is provided as an overview of and topical guide to nanotechnology:
Molecular scale electronics, also called single-molecule electronics, is a branch of nanotechnology that uses single molecules, or nanoscale collections of single molecules, as electronic components. Because single molecules constitute the smallest stable structures imaginable, this miniaturization is the ultimate goal for shrinking electrical circuits.
National Institute for Materials Science is an Independent Administrative Institution and one of the largest scientific research centers in Japan.
International Center for Materials Nanoarchitectonics is a special research unit established in 2007 at the National Institute for Materials Science (NIMS) within the World Premier International (WPI) Research Center Initiative by the Japan Society for the Promotion of Science (JSPS).
Graphite oxide (GO), formerly called graphitic oxide or graphitic acid, is a compound of carbon, oxygen, and hydrogen in variable ratios, obtained by treating graphite with strong oxidizers and acids for resolving of extra metals. The maximally oxidized bulk product is a yellow solid with C:O ratio between 2.1 and 2.9, that retains the layer structure of graphite but with a much larger and irregular spacing.
Kang Lung Wang is recognized as the discoverer of chiral Majorana fermions by IUPAP. Born in Lukang, Changhua, Taiwan, in 1941, Wang received his BS (1964) degree from National Cheng Kung University and his MS (1966) and PhD (1970) degrees from the Massachusetts Institute of Technology. In 1970 to 1972 he was the Assistant Professor at MIT. From 1972 to 1979, he worked at the General Electric Corporate Research and Development Center as a physicist/engineer. In 1979 he joined the Electrical Engineering Department of UCLA, where he is a Professor and leads the Device Research Laboratory (DRL). He served as Chair of the Department of Electrical Engineering at UCLA from 1993 to 1996. His research activities include semiconductor nano devices, and nanotechnology; self-assembly growth of quantum structures and cooperative assembly of quantum dot arrays Si-based Molecular Beam Epitaxy, quantum structures and devices; Nano-epitaxy of hetero-structures; Spintronics materials and devices; Electron spin and coherence properties of SiGe and InAs quantum structures for implementation of spin-based quantum information; microwave devices. He was the inventor of strained layer MOSFET, quantum SRAM cell, and band-aligned superlattices. He holds 45 patents and published over 700 papers. He is a passionate teacher and has mentored hundreds of students, including MS and PhD candidates. Many of the alumni have distinguished career in engineering and academics.
A rapidly increasing list of graphene production techniques have been developed to enable graphene's use in commercial applications.
Directed assembly of micro- and nano-structures are methods of mass-producing micro to nano devices and materials. Directed assembly allows the accurate control of assembly of micro and nano particles to form even the most intricate and highly functional devices or materials.
This glossary of nanotechnology is a list of definitions of terms and concepts relevant to nanotechnology, its sub-disciplines, and related fields.
Artificial lattice is a term encompassing every atomic-scale structures designed and controlled to confine electrons onto a chosen lattice. Research has been done on multiple geometries and one of the most notable being what is called molecular graphene. Molecular graphene is a part of two-dimensional artificial lattices.
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