In mathematical physics and mathematics, the Pauli matrices are a set of three 2 × 2 complex matrices which are Hermitian, involutory and unitary. Usually indicated by the Greek letter sigma, they are occasionally denoted by tau when used in connection with isospin symmetries.
In linear algebra, an orthogonal matrix, or orthonormal matrix, is a real square matrix whose columns and rows are orthonormal vectors.
In mathematics, particularly in linear algebra, matrix multiplication is a binary operation that produces a matrix from two matrices. For matrix multiplication, the number of columns in the first matrix must be equal to the number of rows in the second matrix. The resulting matrix, known as the matrix product, has the number of rows of the first and the number of columns of the second matrix. The product of matrices A and B is denoted as AB.
In linear algebra, an invertible complex square matrix U is unitary if its conjugate transpose U* is also its inverse, that is, if
In mathematics, the orthogonal group in dimension , denoted , is the group of distance-preserving transformations of a Euclidean space of dimension that preserve a fixed point, where the group operation is given by composing transformations. The orthogonal group is sometimes called the general orthogonal group, by analogy with the general linear group. Equivalently, it is the group of orthogonal matrices, where the group operation is given by matrix multiplication. The orthogonal group is an algebraic group and a Lie group. It is compact.
In mechanics and geometry, the 3D rotation group, often denoted SO(3), is the group of all rotations about the origin of three-dimensional Euclidean space under the operation of composition.
In mathematics, particularly in linear algebra, a skew-symmetricmatrix is a square matrix whose transpose equals its negative. That is, it satisfies the condition
In mathematics, particularly in matrix theory, a permutation matrix is a square binary matrix that has exactly one entry of 1 in each row and each column and 0s elsewhere. Each such matrix, say P, represents a permutation of m elements and, when used to multiply another matrix, say A, results in permuting the rows or columns of the matrix A.
An infinitesimal rotation matrix or differential rotation matrix is a matrix representing an infinitely small rotation.
In mathematics, the circle group, denoted by or , is the multiplicative group of all complex numbers with absolute value 1, that is, the unit circle in the complex plane or simply the unit complex numbers
In Euclidean geometry, two-dimensional rotations and reflections are two kinds of Euclidean plane isometries which are related to one another.
In quantum mechanics, a quantum operation is a mathematical formalism used to describe a broad class of transformations that a quantum mechanical system can undergo. This was first discussed as a general stochastic transformation for a density matrix by George Sudarshan. The quantum operation formalism describes not only unitary time evolution or symmetry transformations of isolated systems, but also the effects of measurement and transient interactions with an environment. In the context of quantum computation, a quantum operation is called a quantum channel.
In linear algebra, a rotation matrix is a transformation matrix that is used to perform a rotation in Euclidean space. For example, using the convention below, the matrix
In geometry, Euler's rotation theorem states that, in three-dimensional space, any displacement of a rigid body such that a point on the rigid body remains fixed, is equivalent to a single rotation about some axis that runs through the fixed point. It also means that the composition of two rotations is also a rotation. Therefore the set of rotations has a group structure, known as a rotation group.
In mathematics, an ordered basis of a vector space of finite dimension n allows representing uniquely any element of the vector space by a coordinate vector, which is a sequence of n scalars called coordinates. If two different bases are considered, the coordinate vector that represents a vector v on one basis is, in general, different from the coordinate vector that represents v on the other basis. A change of basis consists of converting every assertion expressed in terms of coordinates relative to one basis into an assertion expressed in terms of coordinates relative to the other basis.
In mathematics, especially in probability and combinatorics, a doubly stochastic matrix (also called bistochastic matrix) is a square matrix of nonnegative real numbers, each of whose rows and columns sums to 1, i.e.,
The Hückel method or Hückel molecular orbital theory, proposed by Erich Hückel in 1930, is a simple method for calculating molecular orbitals as linear combinations of atomic orbitals. The theory predicts the molecular orbitals for π-electrons in π-delocalized molecules, such as ethylene, benzene, butadiene, and pyridine. It provides the theoretical basis for Hückel's rule that cyclic, planar molecules or ions with π-electrons are aromatic. It was later extended to conjugated molecules such as pyridine, pyrrole and furan that contain atoms other than carbon and hydrogen (heteroatoms). A more dramatic extension of the method to include σ-electrons, known as the extended Hückel method (EHM), was developed by Roald Hoffmann. The extended Hückel method gives some degree of quantitative accuracy for organic molecules in general and was used to provide computational justification for the Woodward–Hoffmann rules. To distinguish the original approach from Hoffmann's extension, the Hückel method is also known as the simple Hückel method (SHM).
In mathematics, a unistochastic matrix is a doubly stochastic matrix whose entries are the squares of the absolute values of the entries of some unitary matrix.
In mathematics, a matrix is a rectangular array or table of numbers, symbols, or expressions, arranged in rows and columns, which is used to represent a mathematical object or a property of such an object.
