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Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalysed or un-catalysed and is distinct from other forms of depolymerisation which may rely on the use of chemicals or biological action. This process is associated with an increase in entropy.
The pyrolysis process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. Temperature can be understood as thermal vibration. At high temperatures, excessive vibration causes long chain molecules to break into smaller molecules. The word is coined from the Greek-derived elements pyro "fire", "heat", "fever" and lysis "separating".
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.
Fluidization is a process similar to liquefaction whereby a granular material is converted from a static solid-like state to a dynamic fluid-like state. This process occurs when a fluid is passed up through the granular material.
Plastic recycling is the processing of plastic waste into other products. Recycling can reduce dependence on landfill, conserve resources and protect the environment from plastic pollution and greenhouse gas emissions. Recycling rates lag those of other recoverable materials, such as aluminium, glass and paper. Through 2015, the world produced some 6.3 billion tonnes of plastic waste, only 9% of which has been recycled, and only ~1% has been recycled more than once. Additionally, 12% was incinerated and the remaining 79% sent to landfill or to the environment including the ocean.
A fluidized bed is a physical phenomenon that occurs when a solid particulate substance is under the right conditions so that it behaves like a fluid. The usual way to achieve a fluidized bed is to pump pressurized fluid into the particles. The resulting medium then has many properties and characteristics of normal fluids, such as the ability to free-flow under gravity, or to be pumped using fluid technologies.
This is an alphabetical list of articles pertaining specifically to chemical engineering.
Waste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste, or the processing of waste into a fuel source. WtE is a form of energy recovery. Most WtE processes generate electricity and/or heat directly through combustion, or produce a combustible fuel commodity, such as methane, methanol, ethanol or synthetic fuels, often derived from the product syngas.
Plasma gasification is an extreme thermal process using plasma which converts organic matter into a syngas which is primarily made up of hydrogen and carbon monoxide. A plasma torch powered by an electric arc is used to ionize gas and catalyze organic matter into syngas, with slag remaining as a byproduct. It is used commercially as a form of waste treatment, and has been tested for the gasification of refuse-derived fuel, biomass, industrial waste, hazardous waste, and solid hydrocarbons, such as coal, oil sands, petcoke and oil shale.
A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. In this type of reactor, a fluid is passed through a solid granular material at high enough speeds to suspend the solid and cause it to behave as though it were a fluid. This process, known as fluidization, imparts many important advantages to an FBR. As a result, FBRs are used for many industrial applications.
Chemical looping combustion (CLC) is a technological process typically employing a dual fluidized bed system. CLC operated with an interconnected moving bed with a fluidized bed system, has also been employed as a technology process. In CLC, a metal oxide is employed as a bed material providing the oxygen for combustion in the fuel reactor. The reduced metal is then transferred to the second bed and re-oxidized before being reintroduced back to the fuel reactor completing the loop. Fig 1 shows a simplified diagram of the CLC process. Fig 2 shows an example of a dual fluidized bed circulating reactor system and a moving bed-fluidized bed circulating reactor system.
Waste are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor economic value. A waste product may become a by-product, joint product or resource through an invention that raises a waste product's value above zero.
Recycling can be carried out on various raw materials. Recycling is an important part of creating more sustainable economies, reducing the cost and environmental impact of raw materials. Not all materials are easily recycled, and processing recyclable into the correct waste stream requires considerable energy. Some particular manufactured goods are not easily separated, unless specially process therefore have unique product-based recycling processes.
The extended discrete element method (XDEM) is a numerical technique that extends the dynamics of granular material or particles as described through the classical discrete element method (DEM) by additional properties such as the thermodynamic state, stress/strain or electro-magnetic field for each particle. Contrary to a continuum mechanics concept, the XDEM aims at resolving the particulate phase with its various processes attached to the particles. While the discrete element method predicts position and orientation in space and time for each particle, the extended discrete element method additionally estimates properties such as internal temperature and/or species distribution or mechanical impact with structures.
Fluidisation is a phenomenon whereby solid particulate is placed under certain conditions to cause it to behave like a fluid. A fluidized bed is a system conceived to facilitate the fluidisation. Fluidized beds have a wide range of applications including but not limited to: assisting with chemical reactions, heat transfer, mixing and drying. A recent concept devised and patented by Outotec, "An annular fluidized bed consists of a large central nozzle surrounded be a stationary fluidized".
The circulating fluidized bed (CFB) is a type of Fluidized bed combustion that utilizes a recirculating loop for even greater efficiency of combustion. while achieving lower emission of pollutants. Reports suggest that up to 95% of pollutants can be absorbed before being emitted into the atmosphere. The technology is limited in scale however, due to its extensive use of limestone, and the fact that it produces waste byproducts.
Vibratory Fluidized Bed (VFB) is a type of fluidized bed where the mechanical vibration enhances the performance of fluidization process. Since the first discovery of vibratory fluidized bed, its vibration properties proves to be more efficient in dealing with fine particles which appears to be very difficult to achieve with normal fluidized bed. Even though numerous publications and its popularity in industrial applications, the knowledge about vibratory dynamics and properties are very limited. Future research and development are needed to further improve this technology to bring it to another level.
Biosolarization is an alternative technology to soil fumigation used in agriculture. It is closely related to biofumigation and soil solarization, or the use of solar power to control nematodes, bacteria, fungi and other pests that damage crops. In solarization, the soil is mulched and covered with a tarp to trap solar radiation and heat the soil to a temperature that kills pests. Biosolarization adds the use of organic amendments or compost to the soil before it is covered with plastic, which speeds up the solarization process by decreasing the soil treatment time through increased microbial activity. Research conducted in Spain on the use of biosolarization in strawberry fruit production has shown it to be a sustainable and cost effective option. The practice of biosolarization is being used among small agricultural operations in California. Biosolarization is a growing practice in response to the need for methods for organic soil solarization. The option for more widespread use of biosolarization is being studied by researchers at the Western Center for Agricultural Health and Safety at the University of California at Davis in order to validate the effectiveness of biosolarization in commercial agriculture in California, where it has the potential to greatly reduce the use of conventional fumigants. Biosolarization can also use as organic waste management practice. Recent studies showed the potential of food industrial residues as soil amendments that can improve the efficiency of biosolarization.
Chemical looping reforming (CLR) and gasification (CLG) are the operations that involve the use of gaseous carbonaceous feedstock and solid carbonaceous feedstock, respectively, in their conversion to syngas in the chemical looping scheme. The typical gaseous carbonaceous feedstocks used are natural gas and reducing tail gas, while the typical solid carbonaceous feedstocks used are coal and biomass. The feedstocks are partially oxidized to generate syngas using metal oxide oxygen carriers as the oxidant. The reduced metal oxide is then oxidized in the regeneration step using air. The syngas is an important intermediate for generation of such diverse products as electricity, chemicals, hydrogen, and liquid fuels.
Peter Noël Rowe FREng FIChemE, ) was a Ramsay professor of chemical engineering at University College London and former president of the Institution of Chemical Engineers.
References
- ↑ Lettieri, Paola (1999). A study of the influence of temperature on the flow behaviour of solid materials in a gas fluidized bed (Thesis). OCLC 53571505.
- ↑ UCL (8 October 2018). "Prof Paola Lettieri". UCL Department of Chemical Engineering. Retrieved 22 September 2021.
- ↑ "Fluidization: Overview". www.ucl.ac.uk. Retrieved 22 September 2021.
- 1 2 3 4 Andrew Wade (26 November 2015). "Women at the workface: the variety of roles in engineering". The Engineer. Retrieved 22 September 2021.
- ↑ "New Fellows 2021 Professor Paola Lettieri". Royal Academy of Engineering.
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