Refuse-derived fuel

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Refuse-derived fuel pellets RDF-pellets.jpg
Refuse-derived fuel pellets

Refuse-derived fuel (RDF) is a fuel produced from various types of waste such as municipal solid waste (MSW), industrial waste or commercial waste.

Contents

The World Business Council for Sustainable Development provides a definition:

"Selected waste and by-products with recoverable calorific value can be used as fuels in a cement kiln, replacing a portion of conventional fossil fuels, like coal, if they meet strict specifications. Sometimes they can only be used after pre-processing to provide ‘tailor-made’ fuels for the cement process".

RDF consists largely of combustible components of such waste, as non recyclable plastics (not including PVC), paper cardboard, labels, and other corrugated materials. These fractions are separated by different processing steps, such as screening, air classification, ballistic separation, separation of ferrous and non ferrous materials, glass, stones and other foreign materials and shredding into a uniform grain size, or also pelletized in order to produce a homogeneous material which can be used as substitute for fossil fuels in e.g. cement plants, lime plants, coal fired power plants or as reduction agent in steel furnaces. If documented according to CEN/TC 343 it can be labeled as solid recovered fuels (SRF). [1]

Others describe the properties, such as:

There is no universal exact classification or specification which is used for such materials. Even legislative authorities have not yet established any exact guidelines on the type and composition of alternative fuels. The first approaches towards classification or specification are to be found in Germany (Bundesgütegemeinschaft für Sekundärbrennstoffe) as well as at European level (European Recovered Fuel Organisation). These approaches which are initiated primarily by the producers of alternative fuels, follow a correct approach: Only through an exactly defined standardisation in the composition of such materials can both production and utilisation be uniform worldwide.

First approaches towards alternative fuel classification:

Solid recovered fuels are part of RDF in the fact that it is produced to reach a standard such as CEN/343 ANAS. [2] A comprehensive review is now available on SRF / RDF production, quality standards and thermal recovery, including statistics on European SRF quality. [3]

History

In the 1950s tyres were used for the first time as refuse derived fuel in the cement industry. Continuous use of various waste-derived alternative fuels then followed in the mid-1980s with “Brennstoff aus Müll“ (BRAM) – fuel from waste – in the Westphalian cement industry in Germany.

At that time the thought of cost reduction through replacement of fossil fuels was the priority as considerable competition pressure weighed down on the industry. Since the eighties the German Cement Works Association (Verein Deutscher Zementwerke e.V. (VDZ, Düsseldorf)) has been documenting the use of alternative fuels in the federal German cement industry. In 1987 less than 5% of fossil fuels were replaced by refuse derived fuels, in 2015 its use increased to almost 62%.

Refuse-derived fuels are used in a wide range of specialized waste to energy facilities, which are using processed refuse-derived fuels with lower calorific values of 8-14MJ/kg in grain sizes of up to 500 mm to produce electricity and thermal energy (heat/steam) for district heating systems or industrial uses.

Processing

Materials such as glass and metals are removed during the treatment processing since they are non-combustible. The metal is removed using a magnet and the glass using mechanical screening. After that, an air knife is used to separate the light materials from the heavy ones. The light materials have higher calorific value and they create the final RDF. The heavy materials will usually continue to a landfill. The residual material can be sold in its processed form (depending on the process treatment) as a plain mixture or it may be compressed into pellet fuel, bricks or logs and used for other purposes either stand-alone or in a recursive recycling process. [4] RDF or SRF is the combustible sub-fraction of municipal solid waste and other similar solid waste, produced using a mix of mechanical and/or biological treatment methods such as biodrying. [5] in mechanical-biological treatment (MBT) plants. [3] During the production of RDF / SRF in MBT plants there are solid loses of otherwise combustible material, [6] which generates a debate whether the production and use of RDF / SRF is resource efficient or not over traditional one-step combustion of residual MSW in incineration (Energy from waste) plants. [7]

In the process of making RDF pellets from shredded SRF, drying is often required. Typically, the moisture content needs to be reduced to below 20% to produce high-calorific, high-density RDF pellets. Drying RDF often requires a substantial amount of energy, so choosing an inexpensive heat source is preferable.

The production of RDF may involve the following steps:

End markets

RDF can be used in a variety of ways to produce electricity or as a replacement of fossil fuels. It can be used alongside traditional sources of fuel in coal power plants. In Europe RDF can be used in the cement kiln industry, where strict air pollution control standards of the Waste Incineration Directive apply. The main limiting factor for RDF / SRF use in cement kilns is its total chlorine (Cl) content, with mean Cl content in average commercially manufactured SRF being at 0.76 w/w on a dry basis (± 0.14% w/wd, 95% confidence). [8] RDF can also be fed into plasma arc gasification modules & pyrolysis plants. Where the RDF is capable of being combusted cleanly or in compliance with the Kyoto Protocol, RDF can provide a funding source where unused carbon credits are sold on the open market via a carbon exchange.[ clarification needed ] However, the use of municipal waste contracts[ clarification needed ] and the bankability[ jargon ] of these solutions is still a relatively new concept, thus RDF's financial advantage may be debatable. The European market for the production of RDF have been grown fast due to the European landfill directive and the imposition of landfill taxes. Refuse derived fuel (RDF) exports from the UK to Europe and beyond are expected to have reached 3.3 million tonnes in 2015, representing a near-500,000 tonnes increase on the previous year.

Measurement of RDF and SRF properties: biogenic content

The biomass fraction of RDF and SRF has a monetary value under multiple greenhouse gas protocols, such as the European Union Emissions Trading Scheme and the Renewable Obligation Certificate program in the United Kingdom. Biomass is considered to be carbon-neutral since the CO2 liberated from the combustion of biomass is recycled in plants. The combusted biomass fraction of RDF/SRF is used by stationary combustion operators to reduce their overall reported CO2 emissions.

Several methods have been developed by the European CEN 343 working group to determine the biomass fraction of RDF/SRF. The initial two methods developed (CEN/TS 15440) were the manual sorting method and the selective dissolution method; a comparative assessment of these two methods is available. [9] An alternative, but more expensive method was developed using the principles of radiocarbon dating. A technical review (CEN/TR 15591:2007) outlining the carbon-14 method was published in 2007, and a technical standard of the carbon dating method (CEN/TS 15747:2008) was published in 2008. [10] In the United States, there is already an equivalent carbon-14 method under the standard method ASTM D6866.

Although carbon-14 dating can determine the biomass fraction of RDF/SRF, it cannot determine directly the biomass calorific value. Determining the calorific value is important for green certificate programs such as the Renewable Obligation Certificate program. These programs award certificates based on the energy produced from biomass. Several research papers, including the one commissioned by the Renewable Energy Association in the UK, have been published that demonstrate how the carbon-14 result can be used to calculate the biomass calorific value.

Quality assurance of RDF and SRF properties: representative laboratory sub-sampling

There are major challenges related to the quality assurance and especially the accurate determination of the RDF / SRF thermal recovery (combustion) properties, due to their inherently variable (heterogeneous) composition. Recent advances enable optimal sub-sampling schemes [11] to arrive from the SRF / SRF sample of say 1 kg to the g or mg to be tested in the analytical devices such as the bomb calorimetry or TGA. With such solutions representative sub-sampling can be secured, but less so for the chlorine content. [12] The new evidence suggests that the theory of sampling (ToS) may be overestimating the processing effort needed, to obtain a representative sub-sample.

Regional use

Campania

In 2009, in response to the Naples waste management issue in Campania, Italy, the Acerra incineration facility was completed at a cost of over €350 million. The incinerator burns 600,000 tons of waste per year. [13] The energy produced from the facility is enough to power 200,000 households per year. [14]

Iowa

The first full-scale waste-to-energy facility in the US was the Arnold O. Chantland Resource Recovery Plant, built in 1975 located in Ames, Iowa. This plant also produces RDF that is sent to a local power plant for supplemental fuel. [15]

Manchester

The city of Manchester, in the north west of England, is in the process of awarding a contract for the use of RDF which will be produced by proposed mechanical biological treatment facilities as part of a huge PFI contract. The Greater Manchester Waste Disposal Authority has recently announced there is significant market interest in initial bids for the use of RDF which is projected to be produced in tonnages up to 900,000 tonnes per annum. [16] [17]

Bollnäs

During spring 2008 Bollnäs Ovanåkers Renhållnings AB (BORAB) in Sweden, started their new waste-to-energy plant. Municipal solid waste as well as industrial waste is turned into refuse-derived fuel. The 70,000-80,000 tonnes RDF that is produced per annum is used to power the nearby BFB-plant, which provides the citizens of Bollnäs with electricity and district heating. [18] [19]

Israel

In late March 2017, Israel launched its own RDF plant at the Hiriya Recycling Park; which daily will intake about 1,500 tonnes of household waste, which will amount to around half a million tonnes of waste each year, with an estimated production of 500 tonnes of RDF daily. [20] The plant is part of Israel's "diligent effort to improve and advance waste management in Israel." [21]

United Arab Emirates

In October 2018, the UAE's Ministry of Climate Change and Environment signed a concession agreement with Emirates RDF (BESIX, Tech Group Eco Single Owner, Griffin Refineries) to develop and operate a RDF facility in the Emirate of Umm Al Quwain. The facility will receive 1,000 tons per day of household waste and convert the waste of 550,000 residents from the emirates of Ajman and Umm Al Quwain into RDF. RDF will be used in cement factories to partially replace the traditional use of gas or coal. [22]

See also

Related Research Articles

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<span class="mw-page-title-main">Pyrolysis</span> Thermal decomposition of materials

Pyrolysis is the process of thermal decomposition of materials at elevated temperatures, often in an inert atmosphere without access to oxygen.

<span class="mw-page-title-main">Gasification</span> Form of energy conversion

Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.

<span class="mw-page-title-main">Solid fuel</span> Solid material that can be burnt to release energy

Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels include wood, charcoal, peat, coal, hexamine fuel tablets, dry dung, wood pellets, corn, wheat, rice, rye, and other grains. Solid fuels are extensively used in rocketry as solid propellants. Solid fuels have been used throughout human history to create fire and solid fuel is still in widespread use throughout the world in the present day.

<span class="mw-page-title-main">Briquette</span> Compressed block of biomass used for fueling a fire

A briquette is a compressed block of coal dust or other combustible biomass material used for fuel and kindling to start a fire. The term is a diminutive derived from the French word brique, meaning brick.

<span class="mw-page-title-main">Anaerobic digestion</span> Processes by which microorganisms break down biodegradable material in the absence of oxygen

Anaerobic digestion is a sequence of processes by which microorganisms break down biodegradable material in the absence of oxygen. The process is used for industrial or domestic purposes to manage waste or to produce fuels. Much of the fermentation used industrially to produce food and drink products, as well as home fermentation, uses anaerobic digestion.

<span class="mw-page-title-main">Bioenergy</span> Renewable energy made from biomass

Bioenergy is a type of renewable energy that is derived from plants and animal waste. The biomass that is used as input materials consists of recently living organisms, mainly plants. Thus, fossil fuels are not regarded as biomass under this definition. Types of biomass commonly used for bioenergy include wood, food crops such as corn, energy crops and waste from forests, yards, or farms.

<span class="mw-page-title-main">Pellet fuel</span> Solid fuel made from compressed organic material

Pellet fuels are a type of solid fuel made from compressed organic material. Pellets can be made from any one of five general categories of biomass: industrial waste and co-products, food waste, agricultural residues, energy crops, and untreated lumber. Wood pellets are the most common type of pellet fuel and are generally made from compacted sawdust and related industrial wastes from the milling of lumber, manufacture of wood products and furniture, and construction. Other industrial waste sources include empty fruit bunches, palm kernel shells, coconut shells, and tree tops and branches discarded during logging operations. So-called "black pellets" are made of biomass, refined to resemble hard coal and were developed to be used in existing coal-fired power plants. Pellets are categorized by their heating value, moisture and ash content, and dimensions. They can be used as fuels for power generation, commercial or residential heating, and cooking.

<span class="mw-page-title-main">Waste-to-energy</span> Process of generating energy from the primary treatment of waste

Waste-to-energy (WtE) or energy-from-waste (EfW) refers to a series of processes designed to convert waste materials into usable forms of energy, typically electricity or heat. As a form of energy recovery, WtE plays a crucial role in both waste management and sustainable energy production by reducing the volume of waste in landfills and providing an alternative energy source.

A mechanical biological treatment (MBT) system is a type of waste processing facility that combines a sorting facility with a form of biological treatment such as composting or anaerobic digestion. MBT plants are designed to process mixed household waste as well as commercial and industrial wastes.

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Plasma gasification is an extreme thermal process using plasma which converts organic matter into a syngas which is primarily made up of hydrogen and carbon monoxide. A plasma torch powered by an electric arc is used to ionize gas and catalyze organic matter into syngas, with slag remaining as a byproduct. It is used commercially as a form of waste treatment, and has been tested for the gasification of refuse-derived fuel, biomass, industrial waste, hazardous waste, and solid hydrocarbons, such as coal, oil sands, petcoke and oil shale.

<span class="mw-page-title-main">Cement kiln</span> High temperature rotating oven used for producing clinker

Cement kilns are used for the pyroprocessing stage of manufacture of portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates. Over a billion tonnes of cement are made per year, and cement kilns are the heart of this production process: their capacity usually defines the capacity of the cement plant. As the main energy-consuming and greenhouse-gas–emitting stage of cement manufacture, improvement of kiln efficiency has been the central concern of cement manufacturing technology. Emissions from cement kilns are a major source of greenhouse gas emissions, accounting for around 2.5% of non-natural carbon emissions worldwide.

Biodrying is the process by which biodegradable waste is rapidly heated through initial stages of composting to remove moisture from a waste stream and hence reduce its overall weight. In biodrying processes, the drying rates are augmented by biological heat in addition to forced aeration. The major portion of biological heat, naturally available through the aerobic degradation of organic matter, is utilized to evaporate surface and bound water associated with the mixed sludge. This heat generation assists in reducing the moisture content of the biomass without the need for supplementary fossil fuels, and with minimal electricity consumption. It can take as little as 8 days to dry waste in this manner. This enables reduced costs of disposal if landfill is charged on a cost per tonne basis. Biodrying may be used as part of the production process for refuse-derived fuels. Biodrying does not however greatly affect the biodegradability of the waste and hence is not stabilised. Biodried waste will still break down in a landfill to produce landfill gas and hence potentially contribute to climate change. In the UK this waste will still impact upon councils LATS allowances. Whilst biodrying is increasingly applied within commercial mechanical biological treatment (MBT) plants, it is also still subject to on-going research and development.

Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.

This is a glossary of environmental science.

<span class="mw-page-title-main">Fuel</span> Material used to create heat and energy

A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy.

<span class="mw-page-title-main">Bioenergy with carbon capture and storage</span>

Bioenergy with carbon capture and storage (BECCS) is the process of extracting bioenergy from biomass and capturing and storing the carbon dioxide (CO2) that is produced.

<span class="mw-page-title-main">Torrefaction</span>

Torrefaction of biomass, e.g., wood or grain, is a mild form of pyrolysis at temperatures typically between 200 and 320 °C. Torrefaction changes biomass properties to provide a better fuel quality for combustion and gasification applications. Torrefaction produces a relatively dry product, which reduces or eliminates its potential for organic decomposition. Torrefaction combined with densification creates an energy-dense fuel carrier of 20 to 21 GJ/ton lower heating value (LHV). Torrefaction makes the material undergo Maillard reactions. Torrefied biomass can be used as an energy carrier or as a feedstock used in the production of bio-based fuels and chemicals.

References

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  2. CEN/TC 343 - Published standards
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  10. European Committee for Standardization, list of published standards
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