Patricia Stallings (born 1964 or 1965) is an American woman who was wrongfully convicted of murder after the death of her son Ryan on September 7, 1989. Because testing seemed to indicate an elevated level of ethylene glycol in Ryan's blood, authorities suspected antifreeze poisoning and they arrested Stallings the next day. She was convicted of murder in early 1991 and sentenced to life in prison.
Stallings gave birth to another child while incarcerated awaiting trial; he was diagnosed with methylmalonic acidemia (MMA), a rare genetic disorder that can mimic antifreeze poisoning. Prosecutors initially did not believe that the sibling's diagnosis had anything to do with Ryan's case and Stallings' lawyer was forbidden from producing available evidence as proof of the possibility. After a professor in biochemistry and molecular biology had some of Ryan's blood samples tested, he was able to prove that the child had also died from MMA and not ethylene glycol poisoning. Test samples were sent to several commercial labs that used the same method as used on Ryan's sample. Nearly half of the test results were incorrect.
After spending nearly two years incarcerated, Stallings was released in July 1991. Prosecutors decided to close the case two months later. Stallings sued the hospital and laboratories that were involved in Ryan's care and reached an out-of-court settlement.
Stallings lived in Jefferson County, Missouri, and was a convenience store clerk in the mid-1980s. David Stallings frequently came into her store and they began to date in 1986. They got married in 1988. [1] Their first son, Ryan, was born in April 1989. [2] Patricia took Ryan to Cardinal Glennon Children's Hospital in early July 1989. He was experiencing vomiting and difficulty breathing, and he was admitted to the pediatric intensive care unit. [3] [1]
Noting a high level of what they then believed to be ethylene glycol in the baby's blood, physicians suspected that the boy had been poisoned with antifreeze. [3] The infant was placed in protective custody. On August 31 of that year, Stallings was allowed a short visit with her son. [2] Ryan's illness seemed to recur 4 days after the visit, and Stallings was arrested on assault charges on September 5. Ryan was treated for ethylene glycol poisoning but died two days later. The charges were revised to first-degree murder. [2]
While she was in jail awaiting trial, Stallings gave birth to another son, David Jr., on February 17, 1990. He was placed in foster care, but in March, he developed similar symptoms as those that had affected Ryan, despite having no contact with Stallings. He was diagnosed with methylmalonic acidemia (MMA), a genetic condition in which the body produces propionic acid, a compound that differs from ethylene glycol by one carbon atom. David Jr. recovered and was returned to foster care. [4]
During the investigation and ensuing trial, Stallings's defense attorney wanted to introduce the theory that Ryan had died of MMA, but the prosecutor, George B. McElroy, considered the sibling's diagnosis irrelevant to Ryan's death and the judge, Gary Kramer, would not allow him to advance the theory without any evidence that Ryan was actually affected by MMA. Stallings wanted her attorney to call character witnesses to testify on her behalf, but he did not do so. She was convicted of first-degree murder and given a life sentence. [4]
In May 1990, defense attorney Eric Rathbone obtained copies of notes determined to have been written by assistant prosecutor John S. Appelbaum. The notes indicated that the doctor who pronounced Ryan dead had considered the possibility of an MMA diagnosis, but also that he had not tested Ryan for it at the time. After the discovery of the note, prosecutors said that they believed that there were important differences between ethylene glycol and propylene glycol, and they said that even if Ryan had had MMA, they thought that he had also been poisoned. [5]
The Stallings case was featured on the Unsolved Mysteries television program, and biochemist William Sly of Saint Louis University saw the episode. He agreed to test Ryan's blood, and gave it to James Shoemaker, M.D., Ph.D., Director of the Metabolic Screening Lab at St Louis University. Shoemaker immediately confirmed that Ryan had had MMA. However, ethylene glycol is not a human metabolite, even in cases of MMA, and Stallings went to trial with no explanation linking MMA to ethylene glycol. Much later, after the case was featured on Unsolved Mysteries, Shoemaker asked prosecutor George McElroy for the methods that had been used to measure ethylene glycol in Ryan's blood, and McElroy supplied that information. When the method was used on blood from Ryan and David Jr., it was seen that propionic acid, which is produced in MMA, caused a result that careless observers might mistake for ethylene glycol. [6] Shoemaker then sent samples of propionate-spiked blood to several laboratories, who tested it with the same methods used in the Stallings case. Some of the laboratories came to the incorrect conclusion that the blood reflected ethylene glycol poisoning. [4] At Sly's and Shoemaker's request, Piero Rinaldo of Yale University also looked at the case and concluded that Ryan had died of MMA. His testimony helped to convince McElroy that Ryan might not have been poisoned. [7] [8]
In July 1991, Stallings was released from jail pending a new trial. She was placed on house arrest. [9] In September 1991, prosecutors apologized to Stallings and dropped the case against her. [4]
Stallings said that she lost a lot of weight due to the stress of being imprisoned. She said that her Buddhist faith helped to keep her strong during that time. [1]
Stallings won a settlement against Cardinal Glennon Children's Hospital and the laboratory that tested Ryan's blood. [4] She later said that the perception of her case may have been influenced by the case of Paula Sims, which had unfolded around the same time. In that case, a mother had been tried and convicted of killing her two daughters, and there was considerable public outcry over the murders. [2]
In 1994, McElroy ran for reelection as Jefferson County prosecutor, and Stallings donated $10,000 to his opponent, Robert Wilkins. [10] Wilkins won the race. When McElroy offered to show Wilkins his information on the Stallings case, Stallings found out and asked a court to have her arrest record expunged. Some of the information was ordered to be expunged, but a judge said that Missouri law mandated that prosecutors confidentially maintain some of the information related to felony arrests. [11]
The Stallings case continues to be cited as an extreme case of a metabolic disorder that mimics a criminal act. [12] [13] [8]
Methylmalonic acidemia, also called methylmalonic aciduria, is an autosomal recessive metabolic disorder that disrupts normal amino acid metabolism. It is a classical type of organic acidemia. The result of this condition is the inability to properly digest specific fats and proteins, which in turn leads to a buildup of a toxic level of methylmalonic acid in the blood.
An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, allowing higher coolant temperature. However, all common antifreeze additives also have lower heat capacities than water, and do reduce water's ability to act as a coolant when added to it.
Michael Malloy, later known as either Mike the Durable or Iron Mike, was a homeless Irishman from County Donegal who lived in New York City during the 1920s and 1930s. A former firefighter, he survived multiple murder attempts by five acquaintances, who attempted to commit homicide to perpetrate life insurance fraud.
Isovaleric acidemia is a rare autosomal recessive metabolic disorder which disrupts or prevents normal metabolism of the branched-chain amino acid leucine. It is a classical type of organic acidemia.
Diethylene glycol (DEG) is an organic compound with the formula (HOCH2CH2)2O. It is a colorless, practically odorless, and hygroscopic liquid with a sweetish taste. It is a four carbon dimer of ethylene glycol. It is miscible in water, alcohol, ether, acetone, and ethylene glycol. DEG is a widely used solvent. It can be a normal ingredient in various consumer products, and it can be a contaminant. DEG has also been misused to sweeten wine and beer, and to viscosify oral and topical pharmaceutical products. Its use has resulted in many epidemics of poisoning since the early 20th century.
Methylmalonic acid (MMA) is a dicarboxylic acid that is a C-methylated derivative of malonic acid.
Julia Lynn Turner was an American woman who was convicted in the poisoning deaths of her two husbands.
This is a list of notable overturned convictions in the United States.
It is possible to convict someone of murder without the purported victim's body in evidence. However, cases of this type have historically been hard to prove, often forcing the prosecution to rely on circumstantial evidence, and in England there was for centuries a mistaken view that in the absence of a body a killer could not be tried for murder. Developments in forensic science in recent decades have made it more likely that a murder conviction can be obtained even if a body has not been found.
On December 3, 1998, Mark Jensen, an American man, murdered his wife, Julie Carol Jensen in Pleasant Prairie, Wisconsin by poisoning her with antifreeze. The case is notable for the eventual admission into evidence of a letter written by the deceased prior to her death expressing suspicion of her husband's intentions.
The health of domestic cats is a well studied area in veterinary medicine.
Ethylene glycol poisoning is poisoning caused by drinking ethylene glycol. Early symptoms include intoxication, vomiting and abdominal pain. Later symptoms may include a decreased level of consciousness, headache, and seizures. Long term outcomes may include kidney failure and brain damage. Toxicity and death may occur after drinking even in a small amount as ethylene glycol is more toxic than other diols.
Stacey Ruth Castor was an American convicted murderer from Weedsport, New York. In 2009, she was found guilty of murdering her then-husband David Castor with antifreeze in 2005 and attempting to murder her daughter, Ashley Wallace, by spiking her drinks with pills in 2007. In addition, she was suspected of having murdered her first husband, Michael Wallace, in 2000; his grave lay next to David's until the latter's remains were disinterred and buried elsewhere in 2016. The story made national news, and Castor was subsequently named the "Black Widow" by media outlets.
Angelina Rodriguez is an American woman from Montebello, California who was sentenced to death for the September 2000 murder of Jose Francisco "Frank" Rodriguez, her fourth husband. She also was accused of killing her infant daughter in 1993 by suffocating her with a pacifier. Rodriguez is incarcerated at the Central California Women's Facility in Chowchilla, California, where she is on death row awaiting execution.
Making a Murderer is an American true crime documentary television series written and directed by Laura Ricciardi and Moira Demos. The show tells the story of Steven Avery, a man from Manitowoc County, Wisconsin, who served 18 years in prison (1985–2003) after his wrongful conviction for the sexual assault and attempted murder of Penny Beerntsen. He was later charged with and convicted of the 2005 murder of Teresa Halbach. The connected story is that of Avery's nephew Brendan Dassey, who was accused and convicted as an accessory in the murder of Halbach.
William S. Sly is an internationally known physician and scientist who, except for sabbatical years at Oxford and Stanford, spent his entire academic career in St. Louis. Following M.D. training at Saint Louis University School of Medicine, he trained in internal medicine at Washington University in St. Louis and in research laboratories at the NIH, in Paris, and in Madison, Wisconsin. He then joined the faculty at Washington University, where he directed the division of medical genetics for 20 years. In 1984, he was recruited to St. Louis University School of Medicine and appointed Alice A. Doisy Professor and chairman of the Edward A. Doisy Department of Biochemistry and Molecular Biology. He chaired that department for 26 years. In February 2007, he was also named the inaugural holder of the James B. and Joan C. Peters Endowed Chair in Biochemistry and Molecular Biology. He became an emeritus professor in July 2014.
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The Staudte Family Murders case, also known as "The Antifreeze Murders", was a series of killings and attempted killings within the Staudte family of Springfield, Missouri, during a five-month period in 2012. Family matriarch Diane Staudte and her daughter, Rachel Staudte, committed the crimes together using antifreeze purchased off the internet, with the rationale that antifreeze sold online would not contain the added bittering agent in commercial chemicals making the ethylene glycol poison detectable. Diane's husband, Mark Staudte, was murdered first, followed five months later by her autistic 26-year-old son, Shaun Staudte. 24-year-old daughter Sarah Staudte had also been poisoned with the antifreeze, being taken to hospital in critical condition. Sarah survived the poisoning and later recovered, albeit with physical and neurological damage. Diane Staudte was sentenced to life in prison without the possibility of parole in 2016, while Rachel Staudte pleaded guilty to second-degree murder in May 2015 as part of a plea deal in exchange for testifying against her mother at her trial, eventually being sentenced in March 2016 to life in prison with the possibility of parole.
Combined malonic and methylmalonic aciduria (CMAMMA), also called combined malonic and methylmalonic acidemia is an inherited metabolic disease characterized by elevated levels of malonic acid and methylmalonic acid. Some researchers have hypothesized that CMAMMA might be one of the most common forms of methylmalonic acidemia, and possibly one of the most common inborn errors of metabolism. Due to being infrequently diagnosed, it most often goes undetected.
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