PhostrEx

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PhostrEx is a fire suppression agent developed for use in aviation applications to replace halon, a greenhouse gas (GHG). It was developed by Eclipse Aviation for use aboard their Eclipse 500 very light jets as an engine fire suppression system, and is now being marketed to other aviation manufacturers. [1]

Halomethane compounds are derivatives of methane (CH4) with one or more of the hydrogen atoms replaced with halogen atoms (F, Cl, Br, or I). Halomethanes are both naturally occurring, especially in marine environments, and man-made, most notably as refrigerants, solvents, propellants, and fumigants. Many, including the chlorofluorocarbons, have attracted wide attention because they become active when exposed to ultraviolet light found at high altitudes and destroy the Earth's protective ozone layer.

Greenhouse gas gas in an atmosphere that absorbs and emits radiation within the thermal infrared range

A greenhouse gas is a gas that absorbs and emits radiant energy within the thermal infrared range. Greenhouse gases cause the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor, carbon dioxide, methane, nitrous oxide and ozone. Without greenhouse gases, the average temperature of Earth's surface would be about −18 °C (0 °F), rather than the present average of 15 °C (59 °F). The atmospheres of Venus, Mars and Titan also contain greenhouse gases.

Eclipse Aviation 1998-2009 aircraft manufacturer in the United States

The Eclipse Aviation Corporation was the Albuquerque, New Mexico, United States-based manufacturer of the Eclipse 500 very light jet (VLJ), and also at one time proposed developing the Eclipse 400 single-engined jet.

Contents

Overview

The PhostrEx fire suppression system addresses many of the problems with halon, from system weight to environmental concerns. These concerns, including halon's ozone-depleting and global warming characteristics, prompted the Montreal Protocol to outlaw its use. The only exception allowed by this international treaty was in aviation applications, and only until a suitable replacement became available.

Montreal Protocol environmental protocol

The Montreal Protocol on Substances that Deplete the Ozone Layer is an international treaty designed to protect the ozone layer by phasing out the production of numerous substances that are responsible for ozone depletion. It was agreed on 16 September 1987, and entered into force on 16 September 1989, following a first meeting in Helsinki, May 1989. Since then, it has undergone nine revisions, in 1990 (London), 1991 (Nairobi), 1992 (Copenhagen), 1993 (Bangkok), 1995 (Vienna), 1997 (Montreal), 1998 (Australia), 1999 (Beijing) and 2016 (Kigali) As a result of the international agreement, the ozone hole in Antarctica is slowly recovering. Climate projections indicate that the ozone layer will return to 1980 levels between 2050 and 2070. Due to its widespread adoption and implementation it has been hailed as an example of exceptional international co-operation, with Kofi Annan quoted as saying that "perhaps the single most successful international agreement to date has been the Montreal Protocol". In comparison, effective burden sharing and solution proposals mitigating regional conflicts of interest have been among the success factors for the ozone depletion challenge, where global regulation based on the Kyoto Protocol has failed to do so. In this case of the ozone depletion challenge, there was global regulation already being installed before a scientific consensus was established. Also, overall public opinion was convinced of possible imminent risks.

PhostrEx meets the requirements of both the Montreal Protocol and the Clean Air Act, and is the first commercially viable Federal Aviation Authority and United States Environmental Protection Agency certified halon replacement fire extinguishing agent. The EPA awarded the company with a 2007 Stratospheric Ozone Protection Award for the development of its PhostrEx fire-suppression system. [2]

Clean Air Act (United States) United States federal law designed to control air pollution on a national level

The Clean Air Act is a United States federal law designed to control air pollution on a national level. It is one of the United States' first and most influential modern environmental laws, and one of the most comprehensive air quality laws in the world. As with many other major U.S. federal environmental statutes, it is administered by the U.S. Environmental Protection Agency (EPA), in coordination with state, local, and tribal governments. Its implementing regulations are codified at 40 C.F.R. Sub-chapter C, Parts 50-97.

United States Environmental Protection Agency Agency of the U.S. Federal Government

The Environmental Protection Agency (EPA) is an independent agency of the United States federal government for environmental protection. President Richard Nixon proposed the establishment of EPA on July 9, 1970 and it began operation on December 2, 1970, after Nixon signed an executive order. The order establishing the EPA was ratified by committee hearings in the House and Senate. The agency is led by its Administrator, who is appointed by the President and approved by Congress. The current Administrator is former Deputy Administrator Andrew R. Wheeler, who had been acting administrator since July 2018. The EPA is not a Cabinet department, but the Administrator is normally given cabinet rank.

PhostrEx reacts very quickly with atmospheric moisture, breaking down into phosphorus acid and hydrogen bromide. Neither of these harms the ozone layer. High concentrations of PhostrEx can cause skin blistering and eye irritation, however low concentrations are typically used due to its effectiveness.

Phosphorus oxoacids are oxoacids of phosphorus. Phosphorus exhibits oxidation states from +1 to +5. Oxygen may be in oxidation state -2 or -1, depending on whether a compound contains the peroxide group.

Hydrogen bromide chemical compound

Hydrogen bromide is the diatomic molecule with the formula HBr. It is a colorless compound and a hydrogen halide. Hydrobromic acid is a solution of HBr in water. Both the anhydrous and aqueous solutions of HBr are common reagents in the preparation of bromide compounds.

Ozone layer The region of Earths stratosphere that absorbs most of the Suns UV radiation

The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains high concentration of ozone (O3) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately 15 to 35 kilometers (9.3 to 21.7 mi) above Earth, although its thickness varies seasonally and geographically.

Any persons with skin or eye contact with PhostrEx should rinse the affected area with water as soon as possible. PhostrEx is not very corrosive to metals, but it can tarnish.

Spectrum Aeronautical will incorporate the PhostrEx fire suppression system into its future aircraft. [3]

Spectrum Aeronautical is a business jet developer based in Carlsbad, California with its development center located in Spanish Fork, Utah.

Problems with halon

Most fire extinguishing agents pose a corrosion hazard to aircraft. The extinguishing effect of Halon is through interference of the thermal balance of the flame, and to a small extent by interfering with the chemical reaction of the fire. Halons are chlorofluorocarbons which cause damage to the ozone layer. It is being phased out for environmentally friendlier alternatives. However, most of these alternatives will not fit in an aircraft engine.

Halon is mildly toxic in confined spaces.

Strengths

Weaknesses

See also

Related Research Articles

Chlorofluorocarbons (CFCs) are fully halogenated paraffin hydrocarbons that contain only carbon (C), chlorine (Cl), and fluorine (F), produced as volatile derivative of methane, ethane, and propane. They are also commonly known by the DuPont brand name Freon. The most common representative is dichlorodifluoromethane. Many CFCs have been widely used as refrigerants, propellants, and solvents. Because CFCs contribute to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs) and R-134a.

Bromomethane, commonly known as methyl bromide, is an organobromine compound with formula CH3Br. This colorless, odorless, nonflammable gas is produced both industrially and biologically. It has a tetrahedral shape and it is a recognized ozone-depleting chemical. It was used extensively as a pesticide until being phased out by most countries in the early 2000s.

Bromochlorodifluoromethane chemical compound

Bromochlorodifluoromethane, also known by the trade name Halon 1211, or BCF, or Halon 1211 BCF, or Freon 12B1, is a haloalkane with the chemical formula CF2ClBr.

Bromotrifluoromethane, commonly known as Halon 1301, R13B1, Halon 13B1 or BTM, is an organic halide with the chemical formula CBrF3. It is used for fire suppression and refrigeration. Human exposure to Halon 1301 can be toxic, affecting the central nervous system and other bodily functions. Additionally, it is known to contribute to the depletion of Earth's atmospheric ozone layer when released. As such Halon's use as a refrigerant has been virtually eliminated and alternatives are being used increasingly for fire suppression.

1,1,1,2,3,3,3-Heptafluoropropane colourless, odourless gaseous halocarbon

1,1,1,2,3,3,3-Heptafluoropropane, also called heptafluoropropane, HFC-227ea, HFC-227 or FM200, as well as apaflurane (INN), is a colourless, odourless gaseous halocarbon commonly used as a gaseous fire suppression agent.

Trifluoroiodomethane, also referred to as trifluoromethyl iodide is a halomethane with the formula CF3I. It is an experimental alternative to Halon 1301 (CBrF3) in unoccupied areas. It would be used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires.

Fire class is a term used to denote the type of fire, in relation to the combustion materials which have ignited. This has onward impacts on the type of suppression or extinguishing materials which can be used. Class letters are often assigned to the different types of fire, but these differ between territories. There are separate standards in the United States, Europe, and Australia.

Bromochloromethane chemical compound

Bromochloromethane or methylene bromochloride and Halon 1011 is a mixed halomethane. It is a heavy low-viscosity liquid with refractive index 1.4808.

The Centre for Fire, Explosive and Environment Safety (CFEES) is an Indian defence laboratory of the Defence Research and Development Organisation (DRDO). Located in Timarpur, Delhi, its main function is the development of technologies and products in the area of explosive, fire and environmental safety. CFEES is organised under the Armaments Directorate of DRDO. The present director of CFEES is Rajiv Narang

Fire extinguisher an active fire protection device

A fire extinguisher is an active fire protection device used to extinguish or control small fires, often in emergency situations. It is not intended for use on an out-of-control fire, such as one which has reached the ceiling, endangers the user, or otherwise requires the expertise of a fire brigade. Typically, a fire extinguisher consists of a hand-held cylindrical pressure vessel containing an agent which can be discharged to extinguish a fire. Fire extinguishers manufactured with non-cylindrical pressure vessels also exist but are less common.

Automatic fire suppression

Automatic fire suppression systems control and extinguish fires without human intervention. Examples of automatic systems include fire sprinkler system, gaseous fire suppression, and condensed aerosol fire suppression. When fires are extinguished in the early stages loss of life is minimal since 93% of all fire-related deaths occur once the fire has progressed beyond the early stages.

Refrigerant reclamation is the act of processing used refrigerant gas which has previously been used in some type of refrigeration loop such that it meets specifications for new refrigerant gas. In the United States, the Clean Air Act of 1990 requires that used refrigerant be processed by a certified reclaimer, which must be licensed by the United States Environmental Protection Agency (EPA), and the material must be recovered and delivered to the reclaimer by EPA-certified technicians.

Pentafluoroethane chemical compound

Pentafluoroethane is a refrigerant with the formula CF3CHF2. Although it has zero ozone depletion potential, it has high global warming potential, reported by the United States Environmental Protection Agency (EPA) as 3450 times that of carbon dioxide.

Condensed aerosol fire suppression

Condensed aerosol fire suppression is a particle-based form of fire extinction. It is similar to gaseous fire suppression. It employs a fire extinguishing agent consisting of: very fine solid particles as well as gaseous matter. The condensed aerosol microparticles and effluent gases are generated by the exothermic reaction; the particles remain in vapor state until the process of being discharged from the device. Then, it is "condensed" and cooled within the device and discharged as solid particles.

Clean agent FS 49 C2

Clean agent FS 49 C2 is an environmentally engineered, human safe, fast extinguishing Clean Agent fire extinguishing gas for gaseous fire suppression installed in a suited fire suppression system. It is a gaseous solution of 60-80% tetrafluoroethane (R-134a), 10-30% pentafluoroethane (R-125) and 10-30% carbon dioxide (CO2). The Clean agent FS 49 C2 is an extinguishing gas mixture that suppresses fire while maintaining breathable concentrations of oxygen in the air. This makes it possible to extinguish a fire with less danger to people in the room at extinguishing concentrations in contrast to pure carbon dioxide (CO2) based fire suppression system which is deadly to humans when released. In the beginning the gas was called Halotron II B/FS49C2 but later only the name FS 49 C2 is used. Former fire chief Einar Gjessing made an article about the product to inform firemen how this gas works in case they need to enter a fire site with FS 49 C2.

Stephen Oliver Andersen is the American Director of Research at the Institute for Governance and Sustainable Development (IGSD) and former Co-Chair of the Montreal Protocol Technology and Economic Assessment Panel (TEAP). He is considered one of the founders and leading figures in the success of the Montreal Protocol that has phased out the chemicals that deplete the stratospheric ozone that protects the Earth against the harmful effects of ultraviolet radiation that causes skin cancer, cataracts, and suppression of the human immune system, and destroys agricultural crops and natural ecosystems. Because ozone-depleting chemicals are also powerful greenhouse gases the Montreal Protocol also protected climate.

Bromofluorocarbon hydrocarbon derivative that contains only carbon, bromine and fluorine

Bromofluorocarbons (BFCs) are molecules based on carbon, bromine, and fluorine. The most common use has traditionally been in fire suppression systems. The brand name "Halon" is frequently used interchangeably for BFCs. However, not all Halons are technically BFCs.

FirePro Systems, is a European active fire protection engineering company specializing in the design, production and distribution of environmentally friendly fire suppression systems. It is considered the leading brand of the condensed aerosol technology with official representation in 75 countries and operations in more than 110. The company and its R&D division are headquartered in Limassol along with its Manufacturing facilities.

References

  1. Eclipse introduces new chemical fire-suppression system New Mexico Business Weekly, July 26, 2005
  2. EPA Recognizes Eclipse's PhostrEx AVweb May 2, 2007
  3. "Spectrum to get Eclipse fire protection" FlightGlobal, 25 September 2007
  4. "Demise of Eclipse opens the field for mx service" By Matt Thurber, Aviation International News, May 1, 2009