Photodarkening

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Photodarkening is an optical effect observed in the interaction of laser radiation with amorphous media (glasses) in optical fibers. Until now, such creation of color centers was reported only in glass fibers . [1] [2] Photodarkening limits the density of excitations in fiber lasers and amplifiers. The experimental results suggest that operating at a saturated regime helps to reduce photodarkening. [3]

Contents

Definition

One could expect the term photodarkening to refer to any process when any object becomes non-transparent (dark) due to illumination with light. Formally, the darkening of the photo-emulsion also could be considered as photodarkening. However, recent papers use this term meaning reversible creation of absorbing color centers in optical fibers. One may expect that the effect is not specific for fibers; therefore, the definition should cover wide class of phenomena, excluding, perhaps, non-reversible darkening of photographic emulsions.[ citation needed ]

According to the Encyclopedia of Laser Physics and Technology, [4] photodarkening is the effect that the optical losses in a medium can grow when the medium is irradiated with light at certain wavelengths. We may also define photodarkening as reversible creation of absorption centers in optical media at the illumination with light.

Photodarkening rate

The inverse of the timescale at which photodarkening occurs can be interpreted as photodarkening rate [2]

Color centers

Usually, photodarkening is attributed to creation of color centers due to resonant interaction of electromagnetic field with an active medium [5]

Possible mechanisms of photodarkening

The phenomenon, similar to photodarkening in fibers, was recently observed in chunks of Yb-doped ceramics and crystals. At the high concentration of excitations, the absorption jumps up, causing the avalanche of the broadband luminescence. [6] Increase of absorption can be caused by formation of color centers by electrons in the conduction band, created by several neighboring excited ions. (The energy of one or two excitations is not sufficient to pop an electron into the conduction band). This explains, why the rate of darkening is strong function of the intensity of the exciting beam (as in the case with optical fibers discussed above). In the experiments, [6] the thermal effects are important; therefore only the initial stage of the avalanche can be interpreted as photodarkening, and such interpretation is not yet confirmed. Recent work [7] pointed out the role of thulium contamination. Through laser pump and signal absorption, and energy transfer from ytterbium; thulium is able to emit UV light, known to create color centers in silica glass. Although the actual mechanism of photodarkening is still unknown, a reliable setup to test the photodarkening properties of different types of fibers has been recently reported. [8]

Related Research Articles

Erbium Chemical element with atomic number 68

Erbium is a chemical element with the symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare earth element, originally found in the gadolinite mine in Ytterby in Sweden, from which it got its name.

Laser Device which emits light via optical amplification

A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The term "laser" originated as an acronym for "light amplification by stimulated emission of radiation". The first laser was built in 1960 by Theodore H. Maiman at Hughes Research Laboratories, based on theoretical work by Charles Hard Townes and Arthur Leonard Schawlow.

Ytterbium Chemical element with atomic number 70

Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. However, like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides.

Optical amplifier device that amplifies an optical signal

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Transparency and translucency Property of an object or substance to transmit light with minimal scattering

In the field of optics, transparency is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale, the photons can be said to follow Snell's Law. Translucency allows light to pass through, but does not necessarily follow Snell's law; the photons can be scattered at either of the two interfaces, or internally, where there is a change in index of refraction. In other words, a translucent material is made up of components with different indices of refraction. A transparent material is made up of components with a uniform index of refraction. Transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. The opposite property of translucency is opacity.

Yttrium aluminium garnet

Yttrium aluminium garnet (YAG, Y3Al5O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM).

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A solid-state laser is a laser that uses a gain medium that is a solid, rather than a liquid as in dye lasers or a gas as in gas lasers. Semiconductor-based lasers are also in the solid state, but are generally considered as a separate class from solid-state lasers.

Optical fiber Light-conducting fiber

An optical fiber is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to transmit light between the two ends of the fiber and find wide usage in fiber-optic communications, where they permit transmission over longer distances and at higher bandwidths than electrical cables. Fibers are used instead of metal wires because signals travel along them with less loss; in addition, fibers are immune to electromagnetic interference, a problem from which metal wires suffer. Fibers are also used for illumination and imaging, and are often wrapped in bundles so they may be used to carry light into, or images out of confined spaces, as in the case of a fiberscope. Specially designed fibers are also used for a variety of other applications, some of them being fiber optic sensors and fiber lasers.

Double-clad fiber

Double-clad fiber (DCF) is a class of optical fiber with a structure consisting of three layers of optical material instead of the usual two. The inner-most layer is called the core. It is surrounded by the inner cladding, which is surrounded by the outer cladding. The three layers are made of materials with different refractive indices.

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3D optical data storage

3D optical data storage is any form of optical data storage in which information can be recorded or read with three-dimensional resolution.

Laser-heated pedestal growth

Laser-heated pedestal growth (LHPG) or laser floating zone (LFZ) is a crystal growth technique. A narrow region of a crystal is melted with a powerful CO2 or YAG laser. The laser and hence the floating zone, is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it. This technique for growing crystals from the melt is used in materials research.

A dopant, also called a doping agent, is a trace of impurity element that is introduced into a chemical material to alter its original electrical or optical properties. The amount of dopant necessary to cause changes is typically very low. When doped into crystalline substances, the dopant's atoms get incorporated into its crystal lattice. The crystalline materials are frequently either crystals of a semiconductor such as silicon and germanium for use in solid-state electronics, or transparent crystals for use in the production of various laser types; however, in some cases of the latter, noncrystalline substances such as glass can also be doped with impurities.

Photon upconversion

Photon upconversion (UC) is a process in which the sequential absorption of two or more photons leads to the emission of light at shorter wavelength than the excitation wavelength. It is an anti-Stokes type emission. An example is the conversion of infrared light to visible light. Upconversion can take place in both organic and inorganic materials, through a number of different mechanisms. Organic molecules that can achieve photon upconversion through triplet-triplet annihilation are typically polycyclicaromatic hydrocarbons (PAHs). Inorganic materials capable of photon upconversion often contain ions of d-block or f-block elements. Examples of these ions are Ln3+, Ti2+, Ni2+, Mo3+, Re4+, Os4+, and so on.

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References

  1. J. Koponen; M. Söderlund; H.J. Hoffman; D. Kliner; J. Koplow; J.L. Archambault; L. Reekie; P.St.J. Russell; D.N. Payne (2007). "Photodarkening measurements in large mode area fibers". Proceedings of SPIE. 6553 (5): 783–9. Bibcode:2007SPIE.6453E..40K. doi:10.1117/12.712545.[ dead link ]
  2. 1 2 L. Dong; J. L. Archambault; L. Reekie; P. St. J. Russell; D. N. Payne (1995). "Photoinduced absorption change in germanosilicate preforms: evidence for the color-center model of photosensitivity". Applied Optics. 34 (18): 3436–40. Bibcode:1995ApOpt..34.3436D. doi:10.1364/AO.34.003436. PMID   21052157.
  3. N. Li; S. Yoo; X. Yu; D. Jain; J. K. Sahu (2014)“Pump Power Depreciation by Photodarkening in Ytterbium-Doped Fibers and Amplifiers”, IEEE Photonics Technology Letters, Vol. 26, Issue 2, pp.115-118
  4. "Encyclopedia of Laser Physics and Technology - photodarkening, photochromic damage, photo-induced loss, ultraviolet, gray tracking, color centers".
  5. L.C. Courrol; I.M. Ranieri; W.B. Izilda; S.L. Baldochi; R.E. Ricardo; A.Z. de Freitas; L. Gomes; N.D.J. Vieira (2007). "Study of color centers produced in thulium doped YLF crystals irradiated by electron beam and femtosecond laser pulses". Optics Communications. 270 (2): 340–342. Bibcode:2007OptCo.270..340C. doi:10.1016/j.optcom.2006.09.071.
  6. 1 2 J.-F.Bisson; Kouznetsov, Dmitrii; Ueda, Ken-Ichi; Fredrich-Thornton, Susanne T.; Petermann, Klaus; Huber, Guenter; et al. (2007). "Switching of emissivity and photoconductivity in highly doped Yb3+:Y2O3 and Lu2O3 ceramics". Applied Physics Letters. 90 (20): 066101. Bibcode:2007ApPhL..90t1901B. doi:10.1063/1.2739318.
  7. R. Peretti; A-M. Jurdyc; B. Jacquier; Cédric Gonnet; Alain Pastouret; Ekaterina Burov; Olivier Cavani (2010). "How do traces of thulium can explain photodarkening in Yb doped fibers?". Optics Express. 18 (19): 20455–20460. Bibcode:2010OExpr..1820455P. doi: 10.1364/OE.18.020455 . PMID   20940938.
  8. S. Taccheo; H. Gebavi; D. Tregoat; T. Robin; B. Cadier; D. Milanese; L. Leick (2012). "Photodarkening: measure, characterization, and figure of merit" (PDF). SPIE Newsroom. doi:10.1117/2.1201209.004387. Archived from the original (PDF) on 2019-12-30.