Phototendering

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Phototendering is the process by which organic fibres and textiles lose strength and flexibility as a result of exposure to sunlight. It is the ultraviolet component of the sun's spectrum which affects fibres, causing chain degradation and hence loss of strength. Fading of colours is a common problem in phototendering.

Ultraviolet Electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays

Ultraviolet (UV) designates a band of the electromagnetic spectrum with wavelength from 10 nm to 400 nm, shorter than that of visible light but longer than X-rays. UV radiation is present in sunlight, and contributes about 10% of the total light output of the Sun. It is also produced by electric arcs and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack the energy to ionize atoms, it can cause chemical reactions and causes many substances to glow or fluoresce. Consequently, the chemical and biological effects of UV are greater than simple heating effects, and many practical applications of UV radiation derive from its interactions with organic molecules.

Chemical decomposition, analysis or breakdown is the separation of a single chemical compound into its two or more elemental parts or to simpler compounds. Chemical decomposition is usually regarded and defined as the exact opposite of chemical synthesis. In short, the chemical reaction in which two or more products are formed from a single reactant is called a decomposition reaction.

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UV Degradation

The rate of deterioration is also affected by pigments and dyes present in the textiles. Pigments themselves can also be affected, generally fading after exposure to both UVA and UVB radiation. Great care is needed to preserve museum artefacts from the harmful effects such as ancient textiles, of UV light, which can also be present in fluorescent lamps. Paintings such as watercolours need protection from sunlight so that the original colours are preserved.

Many synthetic polymers are also degraded by UV light with polypropylene especially susceptible. As a result, UV stabilisers are added to many thermoplastics. Carbon black is also effective in protecting products against UV degradation.

Polypropylene polymer

Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene.

Carbon black Chemical compound

Carbon black is a material produced by the incomplete combustion of heavy petroleum products such as FCC tar, coal tar, or ethylene cracking tar. Carbon black is a form of paracrystalline carbon that has a high surface-area-to-volume ratio, albeit lower than that of activated carbon. It is dissimilar to soot in its much higher surface-area-to-volume ratio and significantly lower polycyclic aromatic hydrocarbon (PAH) content. However, carbon black is widely used as a model compound for diesel soot for diesel oxidation experiments. Carbon black is mainly used as a reinforcing filler in tires and other rubber products. In plastics, paints, and inks, carbon black is used as a color pigment.

Many natural and synthetic polymers are attacked by ultraviolet radiation, and products using these materials may crack or disintegrate if they are not UV-stable. The problem is known as UV degradation, and is a common problem in products exposed to sunlight. Continuous exposure is a more serious problem than intermittent exposure, since attack is dependent on the extent and degree of exposure.

Effect of UV exposure on polypropylene rope Failedrope1.jpg
Effect of UV exposure on polypropylene rope

See also

Polymer degradation is a change in the properties—tensile strength, color, shape, etc.—of a polymer or polymer-based product under the influence of one or more environmental factors such as heat, light or chemicals such as acids, alkalis and some salts. These changes are usually undesirable, such as cracking and chemical disintegration of products or, more rarely, desirable, as in biodegradation, or deliberately lowering the molecular weight of a polymer for recycling. The changes in properties are often termed "aging".

Related Research Articles

Photokeratitis or ultraviolet keratitis is a painful eye condition caused by exposure of insufficiently protected eyes to the ultraviolet (UV) rays from either natural or artificial sources. Photokeratitis is akin to a sunburn of the cornea and conjunctiva, and is not usually noticed until several hours after exposure. Symptoms include increased tears and a feeling of pain, likened to having sand in the eyes.

Sun tanning the darkening of skin in response to ultraviolet light

Sun tanning or simply tanning is the process whereby skin color is darkened or tanned. It is most often a result of exposure to ultraviolet (UV) radiation from sunlight or from artificial sources, such as a tanning lamp found in indoor tanning beds. People who deliberately tan their skin by exposure to the sun engage in a passive recreational activity of sun bathing. Some people use chemical products which can produce a tanning effect without exposure to ultraviolet radiation, known as sunless tanning.

The ultraviolet index or UV Index is an international standard measurement of the strength of sunburn-producing ultraviolet (UV) radiation at a particular place and time. The scale was developed by Canadian scientists in 1992, then adopted and standardized by the UN's World Health Organization and World Meteorological Organization in 1994. It is primarily used in daily forecasts aimed at the general public, and is increasingly available as an hourly forecast as well.

The Blue Wool Scale measures and calibrates the permanence of colouring dyes. Traditionally this test was developed for the textiles industry but it has now been adopted by the printing industry as measure of lightfastness of ink colourants.

Luminous paint


Luminous paint or luminescent paint is paint that exhibits luminescence. In other words, it gives off visible light through fluorescence, phosphorescence, or radioluminescence. There are three types of luminous paints..

Photodegradation is the alteration of materials by light. Typically, the term refers to the combined action of sunlight and air. Photodegradation is usually oxidation and hydrolysis. Often photodegradation is avoided, since it destroys paintings and other artifacts. It is however partly responsible for remineralization of biomass and is used intentionally in some disinfection technologies. Photodegradation does not apply to how materials may be aged or degraded via infrared light or heat, but does include degradation in all of the ultraviolet light wavebands.

UV tattoo

UV tattoos or blacklight tattoos are tattoos made with dyes that fluoresce visibly under an ultraviolet light, not unlike fluorescein or rhodamine. Depending upon the ink chosen a UV tattoo can be nearly invisible when illuminated only by light within the visible spectrum. Therefore, they have found popularity with people seeking a subtler tattoo. UV tattoos are particularly popular in the raver subculture for their distinctive appearance.

Sailcloth strong fabric of the type used to make ships sails

Sailcloth encompasses a wide variety of materials that span those from natural fibers, such as flax, hemp or cotton in various forms of sail canvas, to synthetic fibers, including nylon, polyester, aramids, and carbon fibers in a variety of woven, spun and molded textiles.

Ultraviolet photography is a photographic process of recording images by using light from the ultraviolet (UV) spectrum only. Images taken with ultraviolet light serve a number of scientific, medical or artistic purposes. Images may reveal deterioration of art works or structures not apparent under visible light. Diagnostic medial images may be used to detect certain skin disorders or as evidence of injury. Some animals, particularly insects, use ultraviolet wavelengths for vision; ultraviolet photography can help investigate the markings of plants that attract insects, while invisible to the unaided human eye. Ultraviolet photography of archaeological sites may reveal artifacts or traffic patterns not otherwise visible.

Sun protective clothing

Sun protective clothing is clothing specifically designed for sun protection and is produced from a fabric rated for its level of ultraviolet (UV) protection. A novel weave structure and denier may produce sun protective properties. In addition, some textiles and fabrics employed in the use of sun protective clothing may be pre-treated with UV-inhibiting ingredients during manufacture to enhance their effectiveness.

Biological pigment substance produced by living organisms that has a color resulting from selective color absorption

Biological pigments, also known simply as pigments or biochromes, are substances produced by living organisms that have a color resulting from selective color absorption. Biological pigments include plant pigments and flower pigments. Many biological structures, such as skin, eyes, feathers, fur and hair contain pigments such as melanin in specialized cells called chromatophores.

Weather testing of polymers is the controlled polymer degradation and polymer coating degradation under lab or natural conditions.

Sunburn burning of the skin by the suns radiation

Sunburn is a form of radiation burn that affects living tissue, such as skin, that results from an overexposure to ultraviolet (UV) radiation, commonly from the sun. Common symptoms in humans and other animals include red or reddish skin that is hot to the touch, pain, general fatigue, and mild dizziness. An excess of UV radiation can be life-threatening in extreme cases. Excessive UV radiation is the leading cause of primarily non-malignant skin tumors.

The aging of natural and artificial polymeric materials is a natural phenomenon in metals, glass, minerals and other inorganic materials. The main environmental parameters influencing the degradation of polymeric materials is daylight combined with the effects of temperature, moisture and oxygen. These act as the main parameters of stress for outdoor weathering.

FRP is a modern composite material of construction for chemical plant equipment like tanks and vessels. Chemical equipment that range in size from less than a metre to 20 metres are fabricated using FRP as material of construction.

Twinwall plastic

Twin-wall plastic, specifically twin-wall polycarbonate, is an extruded multi-wall polymer product created for applications where its strength, thermally insulative properties, and moderate cost are ideal. Polycarbonate, which is most commonly formed through the reaction of Bisphenol A and Carbonyl Chloride, is an extremely versatile material. It is significantly lighter than glass, while managing to be stronger, more flexible, and more impact resistant. Twin-wall polycarbonate is used most commonly for green houses, where it can support itself in a structurally sound configuration, limit the amount of UV light due to its nominal translucence, and can withstand the rigors of daily abuse in an outdoor environment. The stagnant air in the cellular space between sheets provides insulation, and additional cell layers can be extruded to enhance insulative properties at the cost of light transmission.

Lightfastness

Lightfastness is a property of a colourant such as dye or pigment that describes how resistant to fading it is when exposed to light. Dyes and pigments are used for example for dyeing of fabrics, plastics or other materials and manufacturing paints or printing inks.