Quantum materials

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Quantum materials is an umbrella term in condensed matter physics that encompasses all materials whose essential properties cannot be described in terms of semiclassical particles and low-level quantum mechanics. [1] These are materials that present strong electronic correlations or some type of electronic order, such as superconducting or magnetic orders, or materials whose electronic properties are linked to non-generic quantum effects – topological insulators, Dirac electron systems such as graphene, as well as systems whose collective properties are governed by genuinely quantum behavior, such as ultra-cold atoms, cold excitons, polaritons, and so forth. On the microscopic level, four fundamental degrees of freedom – that of charge, spin, orbit and lattice – become intertwined, resulting in complex electronic states; [1] the concept of emergence is a common thread in the study of quantum materials. [2]

Quantum materials exhibit puzzling properties with no counterpart in the macroscopic world: quantum entanglement, quantum fluctuations, robust boundary states dependent on the topology of the materials' bulk wave functions, etc. [1] Quantum anomalies such as the chiral magnetic effect link some quantum materials with processes in high-energy physics of quark-gluon plasmas. [3]

History

In 2012, Joseph Orenstein published an article in Physics Today about "ultrafast spectroscopy of quantum materials". [4] Orenstein stated,

Quantum materials is a label that has come to signify the area of condensed-matter physics formerly known as strongly correlated electronic systems. Although the field is broad, a unifying theme is the discovery and investigation of materials whose electronic properties cannot be understood with concepts from contemporary condensed-matter textbooks.

As a paradigmatic example, Orenstein refers to the breakdown of Landau Fermi liquid theory due to strong correlations. The use of the term "quantum materials" has been extended and applied to other systems, such as topological insulators, and Dirac electron materials. The term has gained momentum since the article "The rise of quantum materials" was published in Nature Physics in 2016. [2] Quoting:

on a trivial level all materials exist thanks to the laws of quantum mechanics, and there are cynics who will privately wonder if the description isn't too broad and, well, catchy for its own good. But given the history of condensed-matter physics that we have just outlined, there are good reasons to embrace quantum materials. In essence, they provide a common thread linking disparate communities of researchers working on a variety of problems at the frontiers of physics, materials science and engineering.

Related Research Articles

<span class="mw-page-title-main">Condensed matter physics</span> Branch of physics

Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases that arise from electromagnetic forces between atoms and electrons. More generally, the subject deals with condensed phases of matter: systems of many constituents with strong interactions among them. More exotic condensed phases include the superconducting phase exhibited by certain materials at extremely low cryogenic temperatures, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, the Bose–Einstein condensates found in ultracold atomic systems, and liquid crystals. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other physics theories to develop mathematical models and predict the properties of extremely large groups of atoms.

Solid-state physics is the study of rigid matter, or solids, through methods such as solid-state chemistry, quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the large-scale properties of solid materials result from their atomic-scale properties. Thus, solid-state physics forms a theoretical basis of materials science. Along with solid-state chemistry, it also has direct applications in the technology of transistors and semiconductors.

<span class="mw-page-title-main">Magnetic monopole</span> Hypothetical particle with one magnetic pole

In particle physics, a magnetic monopole is a hypothetical elementary particle that is an isolated magnet with only one magnetic pole. A magnetic monopole would have a net north or south "magnetic charge". Modern interest in the concept stems from particle theories, notably the grand unified and superstring theories, which predict their existence. The known elementary particles that have electric charge are electric monopoles.

<span class="mw-page-title-main">Kondo effect</span> Physical phenomenon due to impurities

In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Experiments in the 1960s by Myriam Sarachik at Bell Laboratories provided the first data that confirmed the Kondo effect. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.

In condensed matter physics, the Fermi surface is the surface in reciprocal space which separates occupied from unoccupied electron states at zero temperature. The shape of the Fermi surface is derived from the periodicity and symmetry of the crystalline lattice and from the occupation of electronic energy bands. The existence of a Fermi surface is a direct consequence of the Pauli exclusion principle, which allows a maximum of one electron per quantum state. The study of the Fermi surfaces of materials is called fermiology.

In physics, the zitterbewegung (German pronunciation:[ˈtsɪtɐ.bəˌveːɡʊŋ], from German zittern 'to tremble, jitter', and Bewegung 'motion') is the theoretical prediction of a rapid oscillatory motion of elementary particles that obey relativistic wave equations. This prediction was first discussed by Gregory Breit in 1928 and later by Erwin Schrödinger in 1930 as a result of analysis of the wave packet solutions of the Dirac equation for relativistic electrons in free space, in which an interference between positive and negative energy states produces an apparent fluctuation (up to the speed of light) of the position of an electron around the median, with an angular frequency of 2mc2/, or approximately 1.6×1021 radians per second.

<span class="mw-page-title-main">Topological order</span> Type of order at absolute zero

In physics, topological order is a kind of order in the zero-temperature phase of matter. Macroscopically, topological order is defined and described by robust ground state degeneracy and quantized non-Abelian geometric phases of degenerate ground states. Microscopically, topological orders correspond to patterns of long-range quantum entanglement. States with different topological orders cannot change into each other without a phase transition.

<span class="mw-page-title-main">Mesoscopic physics</span> Subdiscipline of condensed matter physics that deals with materials of an intermediate size

Mesoscopic physics is a subdiscipline of condensed matter physics that deals with materials of an intermediate size. These materials range in size between the nanoscale for a quantity of atoms and of materials measuring micrometres. The lower limit can also be defined as being the size of individual atoms. At the microscopic scale are bulk materials. Both mesoscopic and macroscopic objects contain many atoms. Whereas average properties derived from constituent materials describe macroscopic objects, as they usually obey the laws of classical mechanics, a mesoscopic object, by contrast, is affected by thermal fluctuations around the average, and its electronic behavior may require modeling at the level of quantum mechanics.

The quantum spin Hall state is a state of matter proposed to exist in special, two-dimensional semiconductors that have a quantized spin-Hall conductance and a vanishing charge-Hall conductance. The quantum spin Hall state of matter is the cousin of the integer quantum Hall state, and that does not require the application of a large magnetic field. The quantum spin Hall state does not break charge conservation symmetry and spin- conservation symmetry.

<span class="mw-page-title-main">Xiao-Gang Wen</span> Chinese-American physicist

Xiao-Gang Wen is a Chinese-American physicist. He is a Cecil and Ida Green Professor of Physics at the Massachusetts Institute of Technology and Distinguished Visiting Research Chair at the Perimeter Institute for Theoretical Physics. His expertise is in condensed matter theory in strongly correlated electronic systems. In Oct. 2016, he was awarded the Oliver E. Buckley Condensed Matter Prize.

<span class="mw-page-title-main">Topological insulator</span> State of matter with insulating bulk but conductive boundary

A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.

<span class="mw-page-title-main">Kondo insulator</span>

In solid-state physics, Kondo insulators are understood as materials with strongly correlated electrons, that open up a narrow band gap at low temperatures with the chemical potential lying in the gap, whereas in heavy fermion materials the chemical potential is located in the conduction band.

In quantum mechanics, fractionalization is the phenomenon whereby the quasiparticles of a system cannot be constructed as combinations of its elementary constituents. One of the earliest and most prominent examples is the fractional quantum Hall effect, where the constituent particles are electrons but the quasiparticles carry fractions of the electron charge. Fractionalization can be understood as deconfinement of quasiparticles that together are viewed as comprising the elementary constituents. In the case of spin–charge separation, for example, the electron can be viewed as a bound state of a 'spinon' and a 'chargon', which under certain conditions can become free to move separately.

<span class="mw-page-title-main">Shoucheng Zhang</span> Chinese-American physicist

Shoucheng Zhang was a Chinese-American physicist who was the JG Jackson and CJ Wood professor of physics at Stanford University. He was a condensed matter theorist known for his work on topological insulators, the quantum Hall effect, the quantum spin Hall effect, spintronics, and high-temperature superconductivity. According to the National Academy of Sciences:

He discovered a new state of matter called topological insulator in which electrons can conduct along the edge without dissipation, enabling a new generation of electronic devices with much lower power consumption. For this ground breaking work he received numerous international awards, including the Buckley Prize, the Dirac Medal and Prize, the Europhysics Prize, the Physics Frontiers Prize and the Benjamin Franklin Medal.

Girsh Blumberg is an Estonian-American physicist working in the experimental physics fields of condensed matter physics, spectroscopy, nano-optics, and plasmonics. Blumberg is an elected fellow of the American Physical Society (APS), an elected Fellow of the American Association for the Advancement of Science (FAAAS) , and a Distinguished Professor of Physics at Rutgers University.

Weyl semimetals are semimetals or metals whose quasiparticle excitation is the Weyl fermion, a particle that played a crucial role in quantum field theory but has not been observed as a fundamental particle in vacuum. In these materials, electrons have a linear dispersion relation, making them a solid-state analogue of relativistic massless particles.

<span class="mw-page-title-main">Dirac cone</span> Quantum effect in some non-metals

In physics, Dirac cones are features that occur in some electronic band structures that describe unusual electron transport properties of materials like graphene and topological insulators. In these materials, at energies near the Fermi level, the valence band and conduction band take the shape of the upper and lower halves of a conical surface, meeting at what are called Dirac points.

The term Dirac matter refers to a class of condensed matter systems which can be effectively described by the Dirac equation. Even though the Dirac equation itself was formulated for fermions, the quasi-particles present within Dirac matter can be of any statistics. As a consequence, Dirac matter can be distinguished in fermionic, bosonic or anyonic Dirac matter. Prominent examples of Dirac matter are graphene and other Dirac semimetals, topological insulators, Weyl semimetals, various high-temperature superconductors with -wave pairing and liquid helium-3. The effective theory of such systems is classified by a specific choice of the Dirac mass, the Dirac velocity, the gamma matrices and the space-time curvature. The universal treatment of the class of Dirac matter in terms of an effective theory leads to a common features with respect to the density of states, the heat capacity and impurity scattering.

Nai Phuan Ong is an American experimental physicist, specializing in "condensed matter physics focusing on topological insulators, Dirac/Weyl semimetals, superconductors and quantum spin liquids."

References

  1. 1 2 3 Cava, Robert; de Leon, Nathalie; xie3, Weiwei (10 March 2021). "Introduction: Quantum Materials". Chemical Reviews. 121 (5): 2777–2779. doi: 10.1021/acs.chemrev.0c01322 . ISSN   0009-2665. PMID   33715377.{{cite journal}}: CS1 maint: numeric names: authors list (link)
  2. 1 2 "The rise of quantum materials". Nature Physics. 12 (2): 105. 1 February 2016. Bibcode:2016NatPh..12..105.. doi: 10.1038/nphys3668 . ISSN   1745-2473.
  3. Kharzeev, Dmitri E. (1 March 2014). "The Chiral Magnetic Effect and anomaly-induced transport". Progress in Particle and Nuclear Physics. 75: 133–151. arXiv: 1312.3348 . Bibcode:2014PrPNP..75..133K. doi:10.1016/j.ppnp.2014.01.002. ISSN   0146-6410. S2CID   118508661.
  4. Orenstein, Joseph (31 August 2012). "Ultrafast spectroscopy of quantum materials". Physics Today. 65 (9): 44–50. Bibcode:2012PhT....65i..44O. doi:10.1063/PT.3.1717.