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In condensed matter physics, an ultracold atom is an atom with a temperature near absolute zero. At such temperatures, an atom's quantum-mechanical properties become important.
To reach such low temperatures, a combination of several techniques typically has to be used. [1] First, atoms are trapped and pre-cooled via laser cooling in a magneto-optical trap. To reach the lowest possible temperature, further cooling is performed using evaporative cooling in a magnetic or optical trap. Several Nobel prizes in physics are related to the development of the techniques to manipulate quantum properties of individual atoms (e.g. 1989, 1996, 1997, 2001, 2005, 2012, 2018).
Experiments with ultracold atoms study a variety of phenomena, including quantum phase transitions, Bose–Einstein condensation (BEC), bosonic superfluidity, quantum magnetism, many-body spin dynamics, Efimov states, Bardeen–Cooper–Schrieffer (BCS) superfluidity and the BEC–BCS crossover. [2] Some of these research directions utilize ultracold atom systems as quantum simulators to study the physics of other systems, including the unitary Fermi gas and the Ising and Hubbard models. [3] Ultracold atoms could also be used for realization of quantum computers. [4] [5]
Samples of ultracold atoms are typically prepared through the interactions of a dilute gas with a laser field. Evidence for radiation pressure, force due to light on atoms, was demonstrated independently by Lebedev, and Nichols and Hull in 1901. In 1933, Otto Frisch demonstrated the deflection of individual sodium particles by light generated from a sodium lamp.
The invention of the laser spurred the development of additional techniques to manipulate atoms with light. Using laser light to cool atoms was first proposed in 1975 by taking advantage of the Doppler effect to make the radiation force on an atom dependent on its velocity, a technique known as Doppler cooling. Similar ideas were also proposed to cool samples of trapped ions. Applying Doppler cooling in three dimensions will slow atoms to velocities that are typically a few cm/s and produce what is known as an optical molasses. [6]
Typically, the source of neutral atoms for these experiments were thermal ovens which produced atoms at temperatures of a few hundred kelvins. The atoms from these oven sources are moving at hundred of meters per second. One of the major technical challenges in Doppler cooling was increasing the amount of time an atom can interact with the laser light. This challenge was overcome by the introduction of a Zeeman Slower. A Zeeman Slower uses a spatially varying magnetic field to maintain the relative energy spacing of the atomic transitions involved in Doppler cooling. This increases the amount of time the atom spends interacting with the laser light. Experiments can also use metal dispensers, which are pure metal (typically alkali metals) rods that can emit when heated up (the vapor pressure is higher) with electrical current.
The development of the first magneto-optical trap (MOT) by Raab et al. in 1987 was an important step towards the creation of samples of ultracold atoms. Typical temperatures achieved with a MOT are tens to hundreds of microkelvins. In essence, a magneto optical trap confines atoms in space by applying a magnetic field so that lasers not only provide a velocity dependent force but also a spatially varying force. The 1997 Nobel prize [6] in physics was awarded for development of methods to cool and trap atoms with laser light and was shared by Steven Chu, Claude Cohen-Tannoudji and William D. Phillips.
Evaporative cooling was used in experimental efforts to reach lower temperatures in an effort to discover a new state of matter predicted by Satyendra Nath Bose and Albert Einstein known as a Bose–Einstein condensate (BEC). In evaporative cooling, the hottest atoms in a sample are allowed to escape which reduces the average temperature of the sample. The Nobel Prize in 2001 [1] was awarded to Eric A. Cornell, Wolfgang Ketterle and Carl E. Wieman for the achievement of Bose–Einstein condensate in dilute gases of alkali atoms, and for early fundamental studies of the properties of the condensates.
In recent years a variety of sub-Doppler cooling techniques, including polarization gradient cooling, gray molasses cooling, and Raman sideband cooling, have enabled the cooling and trapping of single atoms in optical tweezers. [7] [8] [9] Experimental platforms leveraging ultracold neutral atoms in optical tweezers and optical lattices have become an increasingly popular setting for studying quantum computing, quantum simulation, and precision metrology. Atoms with closed cycling transitions, capable of scattering many photons with a low probability of decay into other states, are common choices of species for ultracold neutral atom experiments. The lowest-energy fine structure transitions in alkali atoms enable fluorescence imaging, while a combination of hyperfine and Zeeman sublevels can be used for implementing sub-Doppler cooling. Alkaline earth atoms have also gained popularity owing to narrow-linewidth cooling transitions and ultra-narrow optical clock transitions.
Ultracold atoms have a variety of applications owing to their unique quantum properties and the great experimental control available in such systems. For instance, ultracold atoms have been proposed as a platform for quantum computation and quantum simulation, [10] accompanied by very active experimental research to achieve these goals.
Quantum simulation is of great interest in the context of condensed matter physics, where it may provide valuable insights into the properties of interacting quantum systems. The ultracold atoms are used to implement an analogue of the condensed matter system of interest, which can then be explored using the tools available in the particular implementation. Since these tools may differ greatly from those available in the actual condensed matter system, one can thus experimentally probe otherwise inaccessible quantities. Furthermore, ultracold atoms may even allow to create exotic states of matter, which cannot otherwise be observed in nature.
All atoms are identical, making ensembles of atoms ideal for universal timekeeping. In 1967, the SI definition of the second was changed to reference a hyperfine transition frequency in Cesium atoms. Atomic clocks based on alkaline earth atoms or alkaline earth like ions (such as Al+) have now been developed making use of narrow-line optical transitions. To achieve high numbers of non-interacting atoms, which assists in the precision of these clocks, neutral atoms can be trapped in optical lattices. On the other hand, ion traps permit long interrogation times.
Ultracold atoms are also used in experiments for precision measurements enabled by the low thermal noise and, in some cases, by exploiting quantum mechanics to exceed the standard quantum limit. In addition to potential technical applications, such precision measurements may serve as tests of our current understanding of physics.
In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low densities is cooled to temperatures very close to absolute zero. Under such conditions, a large fraction of bosons occupy the lowest quantum state, at which microscopic quantum-mechanical phenomena, particularly wavefunction interference, become apparent macroscopically. More generally, condensation refers to the appearance of macroscopic occupation of one or several states: for example, in BCS theory, a superconductor is a condensate of Cooper pairs. As such, condensation can be associated with phase transition, and the macroscopic occupation of the state is the order parameter.
Laser cooling includes several techniques where atoms, molecules, and small mechanical systems are cooled with laser light. The directed energy of lasers is often associated with heating materials, e.g. laser cutting, so it can be counterintuitive that laser cooling often results in sample temperatures approaching absolute zero. Laser cooling relies on the change in momentum when an object, such as an atom, absorbs and re-emits a photon. For example, if laser light illuminates a warm cloud of atoms from all directions and the laser's frequency is tuned below an atomic resonance, the atoms will be cooled. This common type of laser cooling relies on the Doppler effect where individual atoms will preferentially absorb laser light from the direction opposite to the atom's motion. The absorbed light is re-emitted by the atom in a random direction. After repeated emission and absorption of light the net effect on the cloud of atoms is that they will expand more slowly. The slower expansion reflects a decrease in the velocity distribution of the atoms, which corresponds to a lower temperature and therefore the atoms have been cooled. For an ensemble of particles, their thermodynamic temperature is proportional to the variance in their velocity. More homogeneous velocities between particles corresponds to a lower temperature. Laser cooling techniques combine atomic spectroscopy with the aforementioned mechanical effect of light to compress the velocity distribution of an ensemble of particles, thereby cooling the particles.
Deborah Shiu-lan Jin was an American physicist and fellow with the National Institute of Standards and Technology (NIST); Professor Adjunct, Department of Physics at the University of Colorado; and a fellow of the JILA, a NIST joint laboratory with the University of Colorado.
Quantum optics is a branch of atomic, molecular, and optical physics dealing with how individual quanta of light, known as photons, interact with atoms and molecules. It includes the study of the particle-like properties of photons. Photons have been used to test many of the counter-intuitive predictions of quantum mechanics, such as entanglement and teleportation, and are a useful resource for quantum information processing.
Wolfgang Ketterle is a German physicist and professor of physics at the Massachusetts Institute of Technology (MIT). His research has focused on experiments that trap and cool atoms to temperatures close to absolute zero, and he led one of the first groups to realize Bose–Einstein condensation in these systems in 1995. For this achievement, as well as early fundamental studies of condensates, he was awarded the Nobel Prize in Physics in 2001, together with Eric Allin Cornell and Carl Wieman.
Evaporative cooling is an atomic physics technique to achieve high phase space densities which optical cooling techniques alone typically can not reach.
Lene Vestergaard Hau is a Danish physicist and educator. She is the Mallinckrodt Professor of Physics and of Applied Physics at Harvard University.
An optical lattice is formed by the interference of counter-propagating laser beams, creating a spatially periodic polarization pattern. The resulting periodic potential may trap neutral atoms via the Stark shift. Atoms are cooled and congregate at the potential extrema. The resulting arrangement of trapped atoms resembles a crystal lattice and can be used for quantum simulation.
Doppler cooling is a mechanism that can be used to trap and slow the motion of atoms to cool a substance. The term is sometimes used synonymously with laser cooling, though laser cooling includes other techniques.
In atomic, molecular, and optical physics, a magneto-optical trap (MOT) is an apparatus which uses laser cooling and a spatially-varying magnetic field to create a trap which can produce samples of cold, neutral atoms. Temperatures achieved in a MOT can be as low as several microkelvin, depending on the atomic species, which is two or three times below the photon recoil limit. However, for atoms with an unresolved hyperfine structure, such as 7Li, the temperature achieved in a MOT will be higher than the Doppler cooling limit.
Cryochemistry is the study of chemical interactions at temperatures below −150 °C. It is derived from the Greek word cryos, meaning 'cold'. It overlaps with many other sciences, including chemistry, cryobiology, condensed matter physics, and even astrochemistry.
Joannes Theodorus Maria (Jook) Walraven is a Dutch experimental physicist at the Van der Waals-Zeeman Institute for experimental physics in Amsterdam. From 1967 he studied physics at the University of Amsterdam. Both his doctoral research and PhD research was with Isaac Silvera, on the subject of Bose-Einstein Condensation. Because of the difficulty of his research subject, his promotion took six years instead of four. The aim of his PhD research was to make a gas of atomic hydrogen, which could become the world's first quantum gas. This might then be a suitable candidate for a Bose-Einstein Condensate (BEC).
In atomic physics, Raman cooling is a sub-recoil cooling technique that allows the cooling of atoms using optical methods below the limitations of Doppler cooling, Doppler cooling being limited by the recoil energy of a photon given to an atom. This scheme can be performed in simple optical molasses or in molasses where an optical lattice has been superimposed, which are called respectively free space Raman cooling and Raman sideband cooling. Both techniques make use of Raman scattering of laser light by the atoms.
Superfluidity is the characteristic property of a fluid with zero viscosity which therefore flows without any loss of kinetic energy. When stirred, a superfluid forms vortices that continue to rotate indefinitely. Superfluidity occurs in two isotopes of helium when they are liquefied by cooling to cryogenic temperatures. It is also a property of various other exotic states of matter theorized to exist in astrophysics, high-energy physics, and theories of quantum gravity. The theory of superfluidity was developed by Soviet theoretical physicists Lev Landau and Isaak Khalatnikov.
Tilman Esslinger is a German experimental physicist. He is Professor at ETH Zurich, Switzerland, and works in the field of ultracold quantum gases and optical lattices.
Bose–Einstein condensation can occur in quasiparticles, particles that are effective descriptions of collective excitations in materials. Some have integer spins and can be expected to obey Bose–Einstein statistics like traditional particles. Conditions for condensation of various quasiparticles have been predicted and observed. The topic continues to be an active field of study.
The I. I. Rabi Prize in Atomic, Molecular, and Optical Physics is given by the American Physical Society to recognize outstanding work by mid-career researchers in the field of atomic, molecular, and optical physics. The award was endowed in 1989 in honor of the physicist I. I. Rabi and has been awarded biannually since 1991.
Gretchen K. Campbell is an American atomic, molecular, and optical physicist associated with the National Institute of Standards and Technology. She works in the field of atomtronics and has received awards in recognition of her research contributions on Bose-Einstein condensates.
Monika Aidelsburger is a German quantum physicist, Professor and Group Leader at the Ludwig Maximilian University of Munich. Her research considers quantum simulation and ultra cold atomic gases trapped in optical lattices. In 2021, she was awarded both the Alfried-Krupp-Förderpreis and Klung Wilhelmy Science Award.