In quantum mechanics, quantum revival is a periodic recurrence of the quantum wave function during its time-evolution. [1] This can be either many times in space as multiple scaled copies of the initial wave function (fractional revival), or approximately or exactly to its original form (full revival). A quantum wave function that is periodic in time therefore exhibits a full revival every period. The phenomenon of revival is most readily observable in wave functions that are well-localized wave packets at the beginnings of their time-evolutions, such as in the hydrogen atom. For hydrogen, fractional revivals show up as multiple angular Gaussian bumps around the circle drawn by the radial maximum of the leading circular-state component (that with the highest amplitude in the eigenstate expansion) of the original localized state, and the full revival as the original Gaussian. [2] Full revivals are exact for the infinite quantum well, harmonic oscillator, or hydrogen atom, while for shorter times are approximate for the hydrogen atom and many other quantum systems. [3]
Consider a quantum system with the energies and the eigenstates
and let the energies be the rational fractions of some constant :
(for example, for the hydrogen atom, , , and ).
Then the truncated (till of states) solution of the time-dependent Schrödinger equation is
Let be the least common multiple of all , and be the greatest common divisor of all . Then for each , the quantity is an integer, for each the quantity is an integer, is the full multiple of angle, and
after the full revival time
For a quantum system as small as hydrogen and as small as 100, a full revival may take quadrillions of years. For example, a Trojan wave packet in a hydrogen atom repeats itself after sweeping almost the whole hypercube of quantum phases exactly every full revival time.
In a system with rational energies—that is, where exact full revival exists—its existence immediately proves the quantum Poincaré recurrence theorem, and the time of the full quantum revival equals the Poincaré recurrence time. While the rational numbers are dense in real numbers, and the arbitrary function of the quantum number can be approximated arbitrarily closely with Padé approximants, for the arbitrarily long times, each quantum system therefore revives almost exactly. It also means that Poincaré recurrence and full revival are mathematically the same thing, [5] and it is commonly accepted that the recurrence is called the full revival if it occurs after a reasonable and physically measurable time that is detectable by realistic apparatus. This happens due to a very special energy spectrum having a large basic energy spacing gap of which the energies are arbitrary (not necessarily harmonic) multiples.