The Scientific Assessment of Ozone Depletion is a sequence of reports sponsored by WMO/UNEP. The most recent report is from 2018. The reports were set up to inform the Montreal Protocol and amendments about ozone depletion.
The Montreal and Vienna conventions were installed long before a scientific consensus was established. [1] Until the 1980s, EU, NASA, NAS, UNEP, WMO and the British government had all issued further different scientific reports with dissenting conclusions. [1] Sir Robert (Bob) Watson, Director of the Science Division of at National Aeronautics and Space Administration (NASA), played a crucial role in achieving unified reporting. [1] The IPCC started from scratch with a more unified approach.
(The bracketed 1988, 1985 and 1981 papers are precursor reports relevant to the Montreal Protocol but not directly part of this series).
The Montreal Protocol is an international treaty designed to protect the ozone layer by phasing out the production of numerous substances that are responsible for ozone depletion. It was agreed on 16 September 1987, and entered into force on 1 January 1989. Since then, it has undergone nine revisions, in 1990 (London), 1991 (Nairobi), 1992 (Copenhagen), 1993 (Bangkok), 1995 (Vienna), 1997 (Montreal), 1998 (Australia), 1999 (Beijing) and 2016 (Kigali) As a result of the international agreement, the ozone hole in Antarctica is slowly recovering. Climate projections indicate that the ozone layer will return to 1980 levels between 2040 and 2066. Due to its widespread adoption and implementation, it has been hailed as an example of successful international co-operation. Former UN Secretary-General Kofi Annan stated that "perhaps the single most successful international agreement to date has been the Montreal Protocol". In comparison, effective burden-sharing and solution proposals mitigating regional conflicts of interest have been among the success factors for the ozone depletion challenge, where global regulation based on the Kyoto Protocol has failed to do so. In this case of the ozone depletion challenge, there was global regulation already being installed before a scientific consensus was established. Also, overall public opinion was convinced of possible imminent risks.
The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately 15 to 35 kilometers (9 to 22 mi) above Earth, although its thickness varies seasonally and geographically.
Ozone depletion consists of two related events observed since the late 1970s: a steady lowering of about four percent in the total amount of ozone in Earth's atmosphere, and a much larger springtime decrease in stratospheric ozone around Earth's polar regions. The latter phenomenon is referred to as the ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events.
The stratosphere is the second layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. The stratosphere is an atmospheric layer composed of stratified temperature layers, with the warm layers of air high in the sky and the cool layers of air in the low sky, close to the planetary surface of the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer. The temperature inversion is in contrast to the troposphere, and near the Earth's surface, where temperature decreases with altitude.
Sir Robert Tony Watson CMG FRS is a British chemist who has worked on atmospheric science issues including ozone depletion, global warming and paleoclimatology since the 1980s. Most recently, he is lead author of the February 2021 U.N. report Making Peace with Nature.
The tropopause is the atmospheric boundary that demarcates the troposphere from the stratosphere, which are the lowest two of the five layers of the atmosphere of Earth. The tropopause is a thermodynamic gradient-stratification layer that marks the end of the troposphere, and is approximately 17 kilometres (11 mi) above the equatorial regions, and approximately 9 kilometres (5.6 mi) above the polar regions.
The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth creates pressure, absorbs most meteoroids and ultraviolet solar radiation, warms the surface through heat retention, and reduces temperature extremes between day and night, maintaining conditions allowing life and liquid water to exist on the Earth's surface.
Ground-level ozone (O3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas. Ozone is also an important constituent of the stratosphere, where the ozone layer (2 to 8 parts per million ozone) exists which is located between 10 and 50 kilometers above the Earth's surface. The troposphere extends from the ground up to a variable height of approximately 14 kilometers above sea level. Ozone is least concentrated in the ground layer (or planetary boundary layer) of the troposphere. Ground-level or tropospheric ozone is created by chemical reactions between NOx gases (oxides of nitrogen produced by combustion) and volatile organic compounds (VOCs). The combination of these chemicals in the presence of sunlight form ozone. Its concentration increases as height above sea level increases, with a maximum concentration at the tropopause. About 90% of total ozone in the atmosphere is in the stratosphere, and 10% is in the troposphere. Although tropospheric ozone is less concentrated than stratospheric ozone, it is of concern because of its health effects. Ozone in the troposphere is considered a greenhouse gas, and may contribute to global warming.
The Upper Atmosphere Research Satellite (UARS) was a NASA-operated orbital observatory whose mission was to study the Earth's atmosphere, particularly the protective ozone layer. The 5,900-kilogram (13,000 lb) satellite was deployed from Space Shuttle Discovery during the STS-48 mission on 15 September 1991. It entered Earth orbit at an operational altitude of 600 kilometers (370 mi), with an orbital inclination of 57 degrees.
Polar stratospheric clouds (PSCs) are clouds in the winter polar stratosphere at altitudes of 15,000–25,000 m (49,000–82,000 ft). They are best observed during civil twilight, when the Sun is between 1 and 6 degrees below the horizon, as well as in winter and in more northerly latitudes. One main type of PSC is made up mostly of supercooled droplets of water and nitric acid and is implicated in the formation of ozone holes. The other main type consists only of ice crystals which are not harmful. This type of PSC is also referred to as nacreous.
A circumpolar vortex, or simply polar vortex, is a large region of cold, rotating air; polar vortices encircle both of Earth's polar regions. Polar vortices also exist on other rotating, low-obliquity planetary bodies. The term polar vortex can be used to describe two distinct phenomena; the stratospheric polar vortex, and the tropospheric polar vortex. The stratospheric and tropospheric polar vortices both rotate in the direction of the Earth's spin, but they are distinct phenomena that have different sizes, structures, seasonal cycles, and impacts on weather.
The ozone depletion potential (ODP) of a chemical compound is the relative amount of degradation to the ozone layer it can cause, with trichlorofluoromethane being fixed at an ODP of 1.0. Chlorodifluoromethane (R-22), for example, has an ODP of 0.05. CFC 11, or R-11 has the maximum potential amongst chlorocarbons because of the presence of three chlorine atoms in the molecule.
The ultraviolet index, or UV index, is an international standard measurement of the strength of the sunburn-producing ultraviolet (UV) radiation at a particular place and time. It is primarily used in daily and hourly forecasts aimed at the general public. The UV index is designed as an open-ended linear scale, directly proportional to the intensity of UV radiation, and adjusting for wavelength based on what causes human skin to sunburn. The purpose of the UV index is to help people effectively protect themselves from UV radiation, which has health benefits in moderation but in excess causes sunburn, skin aging, DNA damage, skin cancer, immunosuppression, and eye damage, such as cataracts.
The Dobson spectrophotometer, also known as Dobsonmeter, Dobson spectrometer, or just Dobson is one of the earliest instruments used to measure atmospheric ozone.
Over the last two centuries many environmental chemical observations have been made from a variety of ground-based, airborne, and orbital platforms and deposited in databases. Many of these databases are publicly available. All of the instruments mentioned in this article give online public access to their data. These observations are critical in developing our understanding of the Earth's atmosphere and issues such as climate change, ozone depletion and air quality. Some of the external links provide repositories of many of these datasets in one place. For example, the Cambridge Atmospheric Chemical Database, is a large database in a uniform ASCII format. Each observation is augmented with the meteorological conditions such as the temperature, potential temperature, geopotential height, and equivalent PV latitude.
Tropospheric ozone depletion events are phenomena that reduce the concentration of ozone in the earth's troposphere. Ozone (O3) is a trace gas which has been of concern because of its unique dual role in different layers of the lower atmosphere. Apart from absorbing UV-B radiation and converting solar energy into heat in the stratosphere, ozone in the troposphere provides greenhouse effect and controls the oxidation capacity of the atmosphere.
Polar seas is a collective term for the Arctic Ocean and the southern part of the Southern Ocean. In the coldest years, sea ice can cover around 13 percent of the Earth's total surface at its maximum, but out of phase in the two hemispheres. The polar seas contain a huge biome with many organisms.
The history of the scientific discovery of climate change began in the early 19th century when ice ages and other natural changes in paleoclimate were first suspected and the natural greenhouse effect was first identified. In the late 19th century, scientists first argued that human emissions of greenhouse gases could change Earth's energy balance and climate. The existence of the greenhouse effect, while not named as such, was proposed as early as 1824 by Joseph Fourier. The argument and the evidence were further strengthened by Claude Pouillet in 1827 and 1838. In 1856 Eunice Newton Foote demonstrated that the warming effect of the sun is greater for air with water vapour than for dry air, and the effect is even greater with carbon dioxide.
Ozone depletion and climate change, or Ozone hole global warming in more popular terms, are environmental challenges whose connections have been explored and which have been compared and contrasted, for example in terms of global regulation, in various studies and books.
Patterns of solar irradiance and solar variation have been a main driver of climate change over the millions to billions of years of the geologic time scale.