Hydrogen fuel is a zero-emission fuel when burned with oxygen. It can be used in electrochemical cells or internal combustion engines to power vehicles or electric devices. It has begun to be used in commercial fuel cell vehicles such as passenger cars, and has been used in fuel cell buses for many years. It is also used as a fuel for the propulsion of spacecraft.
The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of 150–300 °C (302–572 °F) and pressures of one to several tens of atmospheres. The process was first developed by Franz Fischer and Hans Tropsch at the Kaiser-Wilhelm-Institut für Kohlenforschung in Mülheim an der Ruhr, Germany, in 1925.
Iron(II,III) oxide is the chemical compound with formula Fe3O4. It occurs in nature as the mineral magnetite. It is one of a number of iron oxides, the others being iron(II) oxide (FeO), which is rare, and iron(III) oxide (Fe2O3) also known as hematite. It contains both Fe2+ and Fe3+ ions and is sometimes formulated as FeO ∙ Fe2O3. This iron oxide is encountered in the laboratory as a black powder. It exhibits permanent magnetism and is ferrimagnetic, but is sometimes incorrectly described as ferromagnetic. Its most extensive use is as a black pigment. For this purpose, it is synthesised rather than being extracted from the naturally occurring mineral as the particle size and shape can be varied by the method of production.
Steam reforming or steam methane reforming is a chemical synthesis for producing syngas, hydrogen, carbon monoxide from hydrocarbon fuels such as natural gas. This is achieved in a processing device called a reformer which reacts steam at high temperature and pressure with methane in the presence of a nickel catalyst. The steam methane reformer is widely used in industry to make hydrogen, also called "blue hydrogen", from natural gas. With the use of CCUS technology it is possible to capture the carbon dioxide in the process and thus decarbonised natural gas.
Serpentinite is a rock composed of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Minerals in this group, which are rich in magnesium and water, light to dark green, greasy looking and slippery feeling, are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.
The water-gas shift reaction (WGSR) describes the reaction of carbon monoxide and water vapor to form carbon dioxide and hydrogen (the mixture of carbon monoxide and hydrogen (not water) is known as water gas):
Direct reduced iron (DRI), also called sponge iron, is produced from the direct reduction of iron ore to iron by a reducing gas or elemental carbon produced from natural gas or coal. Many ores are suitable for direct reduction.
Ammonia is one of the most highly produced inorganic chemicals. There are numerous large-scale ammonia production plants worldwide, producing a total of 144 million tonnes of nitrogen in 2016. China produced 31.9% of the worldwide production, followed by Russia with 8.7%, India with 7.5%, and the United States with 7.1%. 80% or more of the ammonia produced is used for fertilizing agricultural crops. Ammonia is also used for the production of plastics, fibers, explosives, nitric acid and intermediates for dyes and pharmaceuticals.
Hydrogen production is the family of industrial methods for generating hydrogen. Hydrogen is primarily produced by steam reforming of natural gas. Other major sources include naphtha or oil reforming of refinery or other industrial off-gases, and partial oxidation of coal and other hydrocarbons. A small amount is obtained by water electrolysis and other sources.
Chemical looping combustion (CLC) is a technological process typically employing a dual fluidized bed system. The CLC operated with an interconnected moving bed with a fluidized bed system has also been employed as a technology process. In CLC, a metal oxide is employed as a bed material providing the oxygen for combustion in the fuel reactor. The reduced metal is then transferred to the second bed and re-oxidized before being reintroduced back to the fuel reactor completing the loop. Fig 1 shows a simplified diagram of the CLC process. Fig 2 shows an example of a dual fluidized bed circulating reactor system and a moving bed-fluidized bed circulating reactor system.
Hydrogen corrosion is a form of metal corrosion occurring in the presence of anoxic water. Hydrogen corrosion involves a redox reaction that reduces hydrogen ions, forming molecular hydrogen.
The iron oxide cycle (Fe3O4/FeO) is the original two-step thermochemical cycle proposed for use for hydrogen production. It is based on the reduction and subsequent oxidation of iron ions, particularly the reduction and oxidation from Fe3+ to Fe2+. The ferrites, or iron oxide, begins in the form of a spinel and depending on the reaction conditions, dopant metals and support material forms either Wüstites or different spinels.
The zinc–zinc oxide cycle or Zn–ZnO cycle is a two step thermochemical cycle based on zinc and zinc oxide for hydrogen production with a typical efficiency around 40%.
The Lane hydrogen producer was an apparatus for hydrogen production based on the steam-iron process and water gas invented in 1903 by British engineer, Howard Lane.
The Schikorr reaction formally describes the conversion of the iron(II) hydroxide (Fe(OH)2) into iron(II,III) oxide (Fe3O4).
The first time a catalyst was used in the industry was in 1746 by J. Hughes in the manufacture of lead chamber sulfuric acid. Since then catalysts have been in use in a large portion of the chemical industry. In the start only pure components were used as catalysts, but after the year 1900 multicomponent catalysts were studied and are now commonly used in the industry.
Chemical looping reforming (CLR) and gasification (CLG) are the operations that involve the use of gaseous carbonaceous feedstock and solid carbonaceous feedstock, respectively, in their conversion to syngas in the chemical looping scheme. The typical gaseous carbonaceous feedstocks used are natural gas and reducing tail gas, while the typical solid carbonaceous feedstocks used are coal and biomass. The feedstocks are partially oxidized to generate syngas using metal oxide oxygen carriers as the oxidant. The reduced metal oxide is then oxidized in the regeneration step using air. The syngas is an important intermediate for generation of such diverse products as electricity, chemicals, hydrogen, and liquid fuels.
