Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining.
A flame is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density they are then considered plasma.
Knocking in spark ignition internal combustion engines occurs when combustion of some of the air/fuel mixture in the cylinder does not result from propagation of the flame front ignited by the spark plug, but one or more pockets of air/fuel mixture explode outside the envelope of the normal combustion front. The fuel-air charge is meant to be ignited by the spark plug only, and at a precise point in the piston's stroke. Knock occurs when the peak of the combustion process no longer occurs at the optimum moment for the four-stroke cycle. The shock wave creates the characteristic metallic "pinging" sound, and cylinder pressure increases dramatically. Effects of engine knocking range from inconsequential to completely destructive.
Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol (CH3OH) is less expensive to produce sustainably than ethanol fuel, although it produces more toxic effects than ethanol and has lower energy density than gasoline. Methanol is safer for the environment than gasoline, is an anti-freeze, keeps the engine clean, has a higher flashpoint in case of fire, and is the equivalent of super high-octane gasoline in terms of the resulting horsepower. It can readily be used in most modern engines with a simple software setting tweak and occasionally a change in a cheap fuel seal or line. To prevent vapor lock in any possible circumstances due to being a simple, pure fuel, a small percentage of other fuel or certain additives can be included. Methanol (a methyl group linked to a hydroxyl group) may be made from hydrocarbon or renewable resources, in particular natural gas and biomass respectively. It can also be synthesized from CO2 (carbon dioxide) and hydrogen. Methanol fuel is currently used by racing cars in many countries but has not seen widespread use otherwise.
Homogeneous Charge Compression Ignition (HCCI) is a form of internal combustion in which well-mixed fuel and oxidizer are compressed to the point of auto-ignition. As in other forms of combustion, this exothermic reaction releases energy that can be transformed in an engine into work and heat.
A premixed flame is a flame formed under certain conditions during the combustion of a premixed charge of fuel and oxidiser. Since the fuel and oxidiser—the key chemical reactants of combustion—are available throughout a homogeneous stoichiometric premixed charge, the combustion process once initiated sustains itself by way of its own heat release. The majority of the chemical transformation in such a combustion process occurs primarily in a thin interfacial region which separates the unburned and the burned gases. The premixed flame interface propagates through the mixture until the entire charge is depleted. The propagation speed of a premixed flame is known as the flame speed which depends on the convection-diffusion-reaction balance within the flame, i.e. on its inner chemical structure. The premixed flame is characterised as laminar or turbulent depending on the velocity distribution in the unburned pre-mixture.
Turbulent diffusion is the transport of mass, heat, or momentum within a system due to random and chaotic time dependent motions. It occurs when turbulent fluid systems reach critical conditions in response to shear flow, which results from a combination of steep concentration gradients, density gradients, and high velocities. It occurs much more rapidly than molecular diffusion and is therefore extremely important for problems concerning mixing and transport in systems dealing with combustion, contaminants, dissolved oxygen, and solutions in industry. In these fields, turbulent diffusion acts as an excellent process for quickly reducing the concentrations of a species in a fluid or environment, in cases where this is needed for rapid mixing during processing, or rapid pollutant or contaminant reduction for safety.
Flame lift-off in oil fired pressure jet burners is an unwanted condition in which the flame and burner become separated. This condition is most commonly created by excessive combustion air and often results in the loss of flame as the photoelectric cell fails to register the light of the flame, this in turn results in a safety lockout of the control box.
In combustion engineering and explosion studies, the Markstein number characterizes the effect of local heat release of a propagating flame on variations in the surface topology along the flame and the associated local flame front curvature. The dimensionless Markstein number is defined as:
The eddy break-up model (EBU) is used in combustion engineering. Combustion modeling has a wide range of applications. In most of the combustion systems, fuel and oxygen are separately supplied in the combustion chamber. Due to this, chemical reaction and combustion occur simultaneously in the combustion chamber. However, the rate of the chemical reaction is faster than the rate of mixing fuel and oxygen. Therefore, that rate of combustion is controlled by rate of mixing. Such cases, where formation of pre-mixture is difficult, are called diffusion combustion or diffusion flames.
Combustion models for CFD refers to combustion models for computational fluid dynamics. Combustion is defined as a chemical reaction in which a hydrocarbon fuel reacts with an oxidant to form products, accompanied with the release of energy in the form of heat. Being the integral part of various engineering applications like: internal combustion engines, aircraft engines, rocket engines, furnaces, and power station combustors, combustion manifests itself as a wide domain during the design, analysis and performance characteristics stages of the above-mentioned applications. With the added complexity of chemical kinetics and achieving reacting flow mixture environment, proper modeling physics has to be incorporated during computational fluid dynamic (CFD) simulations of combustion. Hence the following discussion presents a general outline of the various adequate models incorporated with the Computational fluid dynamic code to model the process of combustion.
The SRM Engine Suite is an engineering software tool used for simulating fuels, combustion and exhaust gas emissions in internal combustion engine applications. It is used worldwide by leading IC engine development organisations and fuel companies. The software is developed, maintained and supported by CMCL Innovations, Cambridge, U.K.
An internal combustion engine is a heat engine in which the combustion of a fuel occurs with an oxidizer in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combustion engine, the expansion of the high-temperature and high-pressure gases produced by combustion applies direct force to some component of the engine. The force is typically applied to pistons, turbine blades, a rotor, or a nozzle. This force moves the component over a distance, transforming chemical energy into kinetic energy which is used to propel, move or power whatever the engine is attached to. This replaced the external combustion engine for applications where the weight or size of an engine was more important.
Chemical reaction models transform physical knowledge into a mathematical formulation that can be utilized in computational simulation of practical problems in chemical engineering. Computer simulation provides the flexibility to study chemical processes under a wide range of conditions. Modeling of a chemical reaction involves solving conservation equations describing convection, diffusion, and reaction source for each component species.
The laminar flamelet model is one of the methods of modelling turbulent combustions apart from SCRS, eddy flamelet model and others. Combustion is a very important thermochemical process with significant material and aerodynamic implications and thus CFD modeling of combustion has become indispensable. The laminar flamelet model is basically for non pre-mixed fuel.
In combustion, the Karlovitz number is defined as the ratio of chemical time scale to Kolmogorov time scale , named after Béla Karlovitz. The number reads as
Partially premixed combustion (PPC), also known as PPCI or GDCI is a modern combustion process intended to be used in internal combustion engines of automobiles and other motorized vehicles in the future. Its high specific power, high fuel efficiency and low exhaust pollution have made it a promising technology. As a compression-ignition engine, the fuel mixture ignites due to the increase in temperature that occurs with compression rather than a spark from a spark plug. A PPC engine injects and premixes a charge during the compression stroke. This premixed charge is too lean to ignite during the compression stroke – the charge will ignite after the last fuel injection ends near TDC. The fuel efficiency and working principle of a PPC engine resemble those of Diesel engine, but the PPC engine can be run with a variety of fuels. Also, the partially premixed charge burns clean. Challenges with using gasoline in a PPC engine arise due to the low lubricity of gasoline and the low cetane value of gasoline. Use of fuel additives or gasoline-diesel or gasoline-biodiesel blends can mitigate the various problems with gasoline.
Paul Andrews Libby was a professor of mechanical and aerospace engineering at the University of California, San Diego, a specialist in the field of combustion and aerospace engineering.
Thierry Poinsot, born 22 March 1958, is a French researcher, research director at the CNRS, researcher at the Institute of Fluid Mechanics in Toulouse, scientific advisor at CERFACS and senior research fellow at Stanford University. He has been a member of the French Academy of sciences since 2019.
David S-K Ting is a Canadian academic, author and researcher. He is a professor of mechanical, automotive & materials engineering at the University of Windsor. He is the founder of the Turbulence & Energy Laboratory.
