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A superinsulator is a material that at low but finite temperatures does not conduct electricity, i.e. has an infinite resistance so that no electric current passes through it. [1] The phenomenon of superinsulation can be regarded as an exact dual to superconductivity.
The superinsulating state can be destroyed by increasing the temperature and applying an external magnetic field and voltage. A superinsulator was first predicted by M. C. Diamantini, P. Sodano, and C. A. Trugenberger in 1996 [2] who found a superinsulating ground state dual to superconductivity, emerging at the insulating side of the superconductor-insulator transition in the Josephson junction array due to electric-magnetic duality. Superinsulators were independently rediscovered by T. Baturina and V. Vinokur in 2008 [3] on the basis of duality between two different symmetry realizations of the uncertainty principle and experimentally found in titanium nitride (TiN) films. The 2008 measurements revealed giant resistance jumps interpreted as manifestations of the voltage threshold transition to a superinsulating state which was identified as the low-temperature confined phase emerging below the charge Berezinskii-Kosterlitz-Thouless transition. These jumps were similar to earlier findings of the resistance jumps in indium oxide (InO) films. [4] The finite-temperature phase transition into the superinsulating state was finally confirmed by Mironov et al. in NbTiN films in 2018. [5]
Other researchers have seen the similar phenomenon in disordered indium oxide films. [6]
Both superconductivity and superinsulation rest on the pairing of conduction electrons into Cooper pairs. In superconductors, all the pairs move coherently, allowing for the electric current without resistance. In superinsulators, both Cooper pairs and normal excitations are confined and the electric current cannot flow. A mechanism behind superinsulation is the proliferation of magnetic monopoles at low temperatures. [7] In two dimensions (2D), magnetic monopoles are quantum tunneling events (instantons) that are often referred to as monopole “plasma”. In three dimensions (3D), monopoles form a Bose condensate. Monopole plasma or monopole condensate squeezes Faraday's electric field lines into thin electric flux filaments or strings dual to Abrikosov vortices in superconductors. Cooper pairs of opposite charges at the end of these electric strings feel an attractive linear potential. When the corresponding string tension is large, it is energetically favorable to pull out of vacuum many charge-anticharge pairs and to form many short strings rather than to continue stretching the original one. As a consequence, only neutral “electric pions” exist as asymptotic states and the electric conduction is absent. This mechanism is a single-color version of the confinement mechanism that binds quarks into hadrons.
Because the electric forces are much weaker than strong forces of the particle physics, the typical size of “electric pions” well exceeds the size of corresponding elementary particles. This implies that preparing the samples that are sufficiently small, one can peer inside an “electric pion,” where electric strings are loose and Coulomb interactions are screened, hence electric charges are effectively unbound and move as if they were in the metal. The low-temperature saturation of the resistance to metallic behavior has been observed in TiN films with small lateral dimensions.
Superinsulators could potentially be used as a platform for high-performance sensors and logical units. Combined with superconductors, superinsulators could be used to create switching electrical circuits with no energy loss as heat. [8]
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered, even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source.
Unconventional superconductors are materials that display superconductivity which is not explained by the usual BCS theory or its extension, the Eliashberg theory. The pairing in unconventional superconductors may originate from some other mechanism than the electron–phonon interaction. Alternatively, a superconductor is called unconventional if the superconducting order parameter transforms according to a non-trivial irreducible representation of the point group or space group of the system.
High-temperature superconductors are defined as materials with critical temperature above 77 K, the boiling point of liquid nitrogen. They are only "high-temperature" relative to previously known superconductors, which function at even colder temperatures, close to absolute zero. The "high temperatures" are still far below ambient, and therefore require cooling. The first breakthrough of high-temperature superconductor was discovered in 1986 by IBM researchers Georg Bednorz and K. Alex Müller. Although the critical temperature is around 35.1 K, this new type of superconductor was readily modified by Ching-Wu Chu to make the first high-temperature superconductor with critical temperature 93 K. Bednorz and Müller were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-Tc materials are type-II superconductors.
A room-temperature superconductor is a hypothetical material capable of displaying superconductivity above 0 °C, operating temperatures which are commonly encountered in everyday settings. As of 2023, the material with the highest accepted superconducting temperature was highly pressurized lanthanum decahydride, whose transition temperature is approximately 250 K (−23 °C) at 200 GPa.
Magnesium diboride is the inorganic compound with the formula MgB2. It is a dark gray, water-insoluble solid. The compound has attracted attention because it becomes superconducting at 39 K (−234 °C). In terms of its composition, MgB2 differs strikingly from most low-temperature superconductors, which feature mainly transition metals. Its superconducting mechanism is primarily described by BCS theory.
The Little–Parks effect was discovered in 1962 by William A. Little and Ronald D. Parks in experiments with empty and thin-walled superconducting cylinders subjected to a parallel magnetic field. It was one of the first experiments to indicate the importance of Cooper-pairing principle in BCS theory.
In condensed matter physics, a pseudogap describes a state where the Fermi surface of a material possesses a partial energy gap, for example, a band structure state where the Fermi surface is gapped only at certain points.
A charge density wave (CDW) is an ordered quantum fluid of electrons in a linear chain compound or layered crystal. The electrons within a CDW form a standing wave pattern and sometimes collectively carry an electric current. The electrons in such a CDW, like those in a superconductor, can flow through a linear chain compound en masse, in a highly correlated fashion. Unlike a superconductor, however, the electric CDW current often flows in a jerky fashion, much like water dripping from a faucet due to its electrostatic properties. In a CDW, the combined effects of pinning and electrostatic interactions likely play critical roles in the CDW current's jerky behavior, as discussed in sections 4 & 5 below.
Proximity effect or Holm–Meissner effect is a term used in the field of superconductivity to describe phenomena that occur when a superconductor (S) is placed in contact with a "normal" (N) non-superconductor. Typically the critical temperature of the superconductor is suppressed and signs of weak superconductivity are observed in the normal material over mesoscopic distances. The proximity effect is known since the pioneering work by R. Holm and W. Meissner. They have observed zero resistance in SNS pressed contacts, in which two superconducting metals are separated by a thin film of a non-superconducting metal. The discovery of the supercurrent in SNS contacts is sometimes mistakenly attributed to Brian Josephson's 1962 work, yet the effect was known long before his publication and was understood as the proximity effect.
Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductors are the highest temperature superconductors known. However, the mechanism by which superconductivity occurs is still not understood.
Ferromagnetic superconductors are materials that display intrinsic coexistence of ferromagnetism and superconductivity. They include UGe2, URhGe, and UCoGe. Evidence of ferromagnetic superconductivity was also reported for ZrZn2 in 2001, but later reports question these findings. These materials exhibit superconductivity in proximity to a magnetic quantum critical point.
Iron-based superconductors (FeSC) are iron-containing chemical compounds whose superconducting properties were discovered in 2006. In 2008, led by recently discovered iron pnictide compounds, they were in the first stages of experimentation and implementation..
Superstripes is a generic name for a phase with spatial broken symmetry that favors the onset of superconducting or superfluid quantum order. This scenario emerged in the 1990s when non-homogeneous metallic heterostructures at the atomic limit with a broken spatial symmetry have been found to favor superconductivity. Before a broken spatial symmetry was expected to compete and suppress the superconducting order. The driving mechanism for the amplification of the superconductivity critical temperature in superstripes matter has been proposed to be the shape resonance in the energy gap parameters ∆n that is a type of Fano resonance for coexisting condensates.
Piers Coleman is a British-born theoretical physicist, working in the field of theoretical condensed matter physics. Coleman is professor of physics at Rutgers University in New Jersey and at Royal Holloway, University of London.
Iron(II) selenide refers to a number of inorganic compounds of ferrous iron and selenide (Se2−). The phase diagram of the system Fe–Se reveals the existence of several non-stoichiometric phases between ~49 at. % Se and ~53 at. % Fe, and temperatures up to ~450 °C. The low temperature stable phases are the tetragonal PbO-structure (P4/nmm) β-Fe1−xSe and α-Fe7Se8. The high temperature phase is the hexagonal, NiAs structure (P63/mmc) δ-Fe1−xSe. Iron(II) selenide occurs naturally as the NiAs-structure mineral achavalite.
In solid-state physics, the kagome metal or kagome magnet is a type of ferromagnetic quantum material. The atomic lattice in a kagome magnet has layered overlapping triangles and large hexagonal voids, akin to the kagome pattern in traditional Japanese basket-weaving. This geometry induces a flat electronic band structure with Dirac crossings, in which the low-energy electron dynamics correlate strongly.
Lanthanum decahydride is a polyhydride or superhydride compound of lanthanum and hydrogen (LaH10) that has shown evidence of being a high-temperature superconductor. It was the first metal superhydride to be theoretically predicted, synthesized, and experimentally confirmed to superconduct at near room-temperatures. It has a superconducting transition temperature TC around 250 K (−23 °C; −10 °F) at a pressure of 150 gigapascals (22×10 6 psi), and its synthesis required pressures above approximately 160 gigapascals (23×10 6 psi).
Uranium ditelluride is an inorganic compound with the formula UTe2. It was discovered to be an unconventional superconductor in 2018.
Alexander Avraamovitch Golubov is a doctor of physical and mathematical sciences, associate professor at the University of Twente (Netherlands). He specializes in condensed matter physics with the focus on theory of electronic transport in superconducting devices. He made key contributions to theory of Josephson effect in novel superconducting materials and hybrid structures, and to theory of multiband superconductivity.