Supersonic gas separation is a technology to remove one or several gaseous components out of a mixed gas (typically raw natural gas). The process condensates the target components by cooling the gas through expansion in a Laval nozzle and then separates the condensates from the dried gas through an integrated cyclonic gas/liquid separator. The separator is only using a part of the field pressure as energy and has technical and commercial advantages when compared to commonly used conventional technologies.
Raw natural gas out of a well is usually not a salable product but a mix of various hydro-carbonic gases with other gases, liquids and solid contaminants. This raw gas needs gas conditioning to get it ready for pipeline transport and processing in a gas processing plant to separate it into its components.
Some of the common processing steps are CO2 removal, dehydration, LPG extraction, dew-pointing. Technologies used to achieve these steps are adsorption, absorption, membranes and low temperature systems achieved by refrigeration or expansion through a Joule Thomson Valve or a Turboexpander. If such expansion is done through the Supersonic Gas Separator instead, frequently mechanical, economical and operational advantages can be gained as detailed below.
A supersonic gas separator consists of several consecutive sections in tubular form, usually designed as flanged pieces of pipe.
The feed gas (consisting of at least two components) first enters a section with an arrangement of static blades or wings, which induce a fast swirl in the gas. Thereafter the gas stream flows through a Laval nozzle, where it accelerates to supersonic speeds and undergoes a deep pressure drop to about 30% of feed pressure. This is a near isentropic process and the corresponding temperature reduction leads to condensation of target components of the mixed feed gas, which form a fine mist. The droplets agglomerate to larger drops, and the swirl of the gas causes cyclonic separation. [1] The dry gas continues forward, while the liquid phase together with some slip gas (about 30% of the total stream) is separated by a concentric divider and exits the device as a separate stream. The final section are diffusers for both streams, where the gas is slowed down and about 80% of the feed pressure (depending on application) is recovered. This section might also include another set of static devices to undo the swirling motion. [2]
The supersonic separator requires a certain process scheme, which includes further auxiliary equipment and often forms a skid or processing block. The typical basic scheme for supersonic separation is an arrangement where the feed gas is pre-cooled in a heat exchanger by the dry stream of the separator unit.
The liquid phase from the supersonic separator goes into a 2-phase or 3-phase separator, where the slip gas is separated from water and/or from liquid hydrocarbons. The gaseous phase of this secondary separator joins the dry gas of the supersonic separator, the liquids go for transport, storage or further processing and the water for treatment and disposal.
Depending on the task at hand other schemes are possible and for certain cases have advantages. Those variations are very much part of the supersonic gas separation process to achieve thermodynamic efficiency and several of them are protected by patents. [3]
The supersonic gas separator recovers part of the pressure drop needed for cooling and as such has a higher efficiency than a JT valve in all conditions of operation.
The supersonic gas separator can in many cases have a 10–20% higher efficiency than a turboexpander.
The supersonic separator has a smaller footprint and a lower weight than a turboexpander or contactor columns. This is of particular advantage for platforms, FPSOs and crowded installations. It needs a lower capital investment and lower operating expenditure as it is completely static. Very little maintenance is required and no (or greatly reduced) amounts of chemicals.
The fact that no operational or maintenance personnel is required might enable unmanning of usually manned platforms with the associated large savings in capital and operational expenditure.
The fields of application commercially developed until today on an industrial scale are:
Applications in the development stage for near term commercialization are:
There are several patents on supersonic gas separation, relating to features of the device as well as methods. The technology has been researched and proven in laboratory installations since about 1998, special HYSYS modules have been developed as well as 3D gas computer modeling. The supersonic gas separation technology has meanwhile moved successfully into industrial applications (e.g. in Nigeria, Malaysia and Russia) for dehydration as well as for LPG extraction. Consultancy, engineering and equipment for supersonic gas separation are being offered by ENGO Engineering Ltd. under the brand "3S". [4] They are also provided by Twister BV, a Dutch firm affiliated with Royal Dutch Shell, under the brand "Twister Supersonic Separator". [5]
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heating of solid materials to produce gaseous products ; this may involve chemical changes such as destructive distillation or cracking. Distillation may result in essentially complete separation, or it may be a partial separation that increases the concentration of selected components; in either case, the process exploits differences in the relative volatility of the mixture's components. In industrial applications, distillation is a unit operation of practically universal importance, but is a physical separation process, not a chemical reaction. An installation used for distillation, especially of distilled beverages, is a distillery. Distillation includes the following applications:
Spray drying is a method of forming a dry powder from a liquid or slurry by rapidly drying with a hot gas. This is the preferred method of drying of many thermally-sensitive materials such as foods and pharmaceuticals, or materials which may require extremely consistent, fine particle size. Air is the heated drying medium; however, if the liquid is a flammable solvent such as ethanol or the product is oxygen-sensitive then nitrogen is used.
Pervaporation is a processing method for the separation of mixtures of liquids by partial vaporization through a non-porous or porous membrane.
Natural-gas condensate, also called natural gas liquids, is a low-density mixture of hydrocarbon liquids that are present as gaseous components in the raw natural gas produced from many natural gas fields. Some gas species within the raw natural gas will condense to a liquid state if the temperature is reduced to below the hydrocarbon dew point temperature at a set pressure.
In the upstream oil industry, a gas–oil separation plant (GOSP) is temporary or permanent facilities that separate wellhead fluids into constituent vapor (gas) and liquid components.
A turboexpander, also referred to as a turbo-expander or an expansion turbine, is a centrifugal or axial-flow turbine, through which a high-pressure gas is expanded to produce work that is often used to drive a compressor or generator.
Merox is an acronym for mercaptan oxidation. It is a proprietary catalytic chemical process developed by UOP used in oil refineries and natural gas processing plants to remove mercaptans from LPG, propane, butanes, light naphthas, kerosene and jet fuel by converting them to liquid hydrocarbon disulfides.
The Twister supersonic separator is a compact tubular device which is used for removing water and/or hydrocarbon dewpointing of natural gas. The principle of operation is similar to the near isentropic Brayton cycle of a turboexpander. The gas is accelerated to supersonic velocities within the tube using a De Laval nozzle and inlet guide vanes spin the gas around an inner-body which creates the "ballerina effect" and centrifugally separates the water and liquids in the tube. Hydrates do not form in the Twister tube due to the very short residence time of the gas in the tube. A secondary separator treats the liquids and slip gas and also acts as a hydrate control vessel. Twister is able to dehydrate to typical pipeline dewpoint specifications and relies on a pressure drop from the inlet of about 25%, dependent on the performance required. The fundamental mathematics behind supersonic separation can be found in the Society of Petroleum Engineers paper entitled "Selective Removal of Water from Supercritical Natural Gas". The closed Twister system enables gas treatment subsea.
Natural-gas processing is a range of industrial processes designed to purify raw natural gas by removing contaminants such as solids, water, carbon dioxide (CO2), hydrogen sulfide (H2S), mercury and higher molecular mass hydrocarbons (condensate) to produce pipeline quality dry natural gas for pipeline distribution and final use. Some of the substances which contaminate natural gas have economic value and are further processed or sold. Hydrocarbons that are liquid at ambient conditions: temperature and pressure (i.e., pentane and heavier) are called natural-gas condensate (sometimes also called natural gasoline or simply condensate).
The Everest gasfield is located in the Central North Sea, 233 kilometres (145 mi) east of Aberdeen, Scotland. It lies in the United Kingdom Continental Shelf blocks 22/9, 22/10a and 22/14a. The gasfield was discovered by Amoco in 1982 with first gas produced in 1993.
An oil production plant is a facility which processes production fluids from oil wells in order to separate out key components and prepare them for export. Typical oil well production fluids are a mixture of oil, gas and produced water. An oil production plant is distinct from an oil depot, which does not have processing facilities.
The term separator in oilfield terminology designates a pressure vessel used for separating well fluids produced from oil and gas wells into gaseous and liquid components. A separator for petroleum production is a large vessel designed to separate production fluids into their constituent components of oil, gas and water. A separating vessel may be referred to in the following ways: Oil and gas separator, Separator, Stage separator, Trap, Knockout vessel, Flash chamber, Expansion separator or expansion vessel, Scrubber, Filter. These separating vessels are normally used on a producing lease or platform near the wellhead, manifold, or tank battery to separate fluids produced from oil and gas wells into oil and gas or liquid and gas. An oil and gas separator generally includes the following essential components and features:
Onshore, when used in relation to hydrocarbons, refers to an oil, natural gas or condensate field that is under the land or to activities or operations carried out in relation to such a field.
In chemical engineering, a vapor–liquid separator is a device used to separate a vapor–liquid mixture into its constituent phases. It can be a vertical or horizontal vessel, and can act as a 2-phase or 3-phase separator.
Swirl valve technology has been developed by Twister BV of the Netherlands primarily for the gas processing market. This technology is similar to the swirl tube and can also be applied for liquid/liquid separation applications such as oil/water separation and for oil degassing. It is currently being used for optimising existing Joule–Thomson (JT-LTS) systems to minimise liquid carryover. The swirl valve is exactly the same as a Joule-Thomson (JT) choke valve, but it enhances the performance of downstream separators for the same pressure drop, by maximising droplet coalescence. The technology can be applied where a low temperature separator is undersized, or when a lower pressure drop over a JT valve is needed with a similar dew pointing performance. It can also be applied for reducing glycol/chemical inhibition liquid mist carry-over problems.
A separation process is a method that converts a mixture or a solution of chemical substances into two or more distinct product mixtures, a scientific process of separating two or more substance in order to obtain purity. At least one product mixture from the separation is enriched in one or more of the source mixture's constituents. In some cases, a separation may fully divide the mixture into pure constituents. Separations exploit differences in chemical properties or physical properties between the constituents of a mixture.
Continuous foam separation is a chemical process closely related to foam fractionation in which foam is used to separate components of a solution when they differ in surface activity. In any solution, surface active components tend to adsorb to gas-liquid interfaces while surface inactive components stay within the bulk solution. When a solution is foamed, the most surface active components collect in the foam and the foam can be easily extracted. This process is commonly used in large-scale projects such as water waste treatment due to a continuous gas flow in the solution.
The peeler centrifuge is a device that performs by rotating filtration basket in an axis. A centrifuge follows on the principle of centrifugal force to separate solids from liquids by density difference. High rotation speed provides high centrifugal force that allows the suspended solid in feed to settle on the inner surface of basket. There are three kinds of centrifuge, horizontal, vertical peeler centrifuge and siphon peeler centrifuge. These classes of instrument apply to various areas such as fertilisers, pharmaceutical, plastics and food including artificial sweetener and modified starch.
A centrifuge is a device that employs a high rotational speed to separate components of different densities. This becomes relevant in the majority of industrial jobs where solids, liquids and gases are merged into a single mixture and the separation of these different phases is necessary. A decanter centrifuge separates continuously solid materials from liquids in the slurry, and therefore plays an important role in the wastewater treatment, chemical, oil, and food processing industries. There are several factors that affect the performance of a decanter centrifuge, and some design heuristics are to be followed which are dependent upon given applications.
An oil water separator (OWS) is a piece of equipment used to separate oil and water mixtures into their separate components. There are many different types of oil-water separator. Each has different oil separation capability and are used in different industries. Oil water separators are designed and selected after consideration of oil separation performance parameters and life cycle cost considerations. "Oil" can be taken to mean mineral, vegetable and animal oils, and the many different hydrocarbons.