Tabular-grain film

Last updated

Tabular-grain film is a type of photographic film that includes nearly all color films, and many black and white films like T-MAX films from Kodak (with Kodak's T-grain emulsion), Delta films from Ilford Photo and the Fujifilm Neopan films. The silver halide crystals in the film emulsion are flatter and more tabular (hence T-Grain).

Contents

Tabular crystals

In panchromatic emulsions, the sensitivity of the silver halide crystal is enhanced by sensitizing dyes that adsorb on the crystal surface. Therefore, sensitivity can be increased by adsorbing more sensitizing dye. This requires increasing the surface area of the crystal, and also improving the dye molecules to form a dense assembly. Tabular grain emulsion solves the first part of this problem.

Tabular crystals tend to lie along the film's surface when coated and dried. This reduces scattering of light and increases resolution.

Tabular crystals usually have two twinned planes parallel to each other. They are formed at the very beginning of the crystallization. The crystal tends to grow at the edges and not on the main planes, forming very thin crystals of very large surface areas. Tabular crystals probably existed from very early days of silver-gelatin photography. However, it took until roughly 1970 for emulsion engineers to be able to make emulsions that consisted mainly of tabular crystals. Moreover, it was not until the 1980s that tabular crystals began to be used in production emulsions.

Tabular grain technology brought significant improvements to the image quality of the film, particularly in the improvement of resolution and granularity. However, several more key technologies were implemented into tabular grain products. Many of these concurrent improvements were applied to non-tabular grain products to improve image quality. Therefore, when tabular grain technology is described by uninformed writers, its advantage tends to be overemphasized. For example, excellent reciprocity law is not an inherent property of tabular crystals but rather the result of other techniques introduced at about the same time.

Fixing tabular crystals

Tabular crystals grow along the edges and not on the main planes. Similarly, tabular crystals dissolve mainly along the edges and this causes the crystals to be more difficult and slow to fix in the fixing stage. Users of tabular grain films are advised to ensure sufficient fixing time, at least twice the clearing time in rapid fixer.

Related Research Articles

Film stock Medium used for recording motion pictures

Film stock is an analog medium that is used for recording motion pictures or animation. It is recorded on by a movie camera, developed, edited, and projected onto a screen using a movie projector. It is a strip or sheet of transparent plastic film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast and resolution of the film. The emulsion will gradually darken if left exposed to light, but the process is too slow and incomplete to be of any practical use. Instead, a very short exposure to the image formed by a camera lens is used to produce only a very slight chemical change, proportional to the amount of light absorbed by each crystal. This creates an invisible latent image in the emulsion, which can be chemically developed into a visible photograph. In addition to visible light, all films are sensitive to X-rays and high-energy particles. Most are at least slightly sensitive to invisible ultraviolet (UV) light. Some special-purpose films are sensitive into the infrared (IR) region of the spectrum.

The following list comprises significant milestones in the development of photography technology.

Photographic processing or photographic development is the chemical means by which photographic film or paper is treated after photographic exposure to produce a negative or positive image. Photographic processing transforms the latent image into a visible image, makes this permanent and renders it insensitive to light.

Photographic paper Light-sensitive paper used to make photographic prints

Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on Silver halide but other alternatives have also been used.

Lippmann plate

Gabriel Lippmann conceived a two-step method to record and reproduce colours, variously known as direct photochromes, interference photochromes, Lippmann photochromes, Photography in natural colours by direct exposure in the camera or the Lippmann process of colour photography. Lippmann won the Nobel Prize in Physics for this work in 1908.

Photographic developer

In the processing of photographic films, plates or papers, the photographic developer is one or more chemicals that convert the latent image to a visible image. Developing agents achieve this conversion by reducing the silver halides, which are pale-colored, into silver metal, which is black. The conversion occurs within the gelatine matrix. The special feature of photography is that the developer acts more quickly on those particles of silver halides that have been exposed to light. Paper left in developer will eventually reduce all the silver halides and turn black. Generally, the longer a developer is allowed to work, the darker the image.

Color photography is photography that uses media capable of capturing and reproducing colors. By contrast, black-and-white or gray-monochrome photography records only a single channel of luminance (brightness) and uses media capable only of showing shades of gray.

Gelatin silver process Photographic process

The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. This was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.

Photographic printing is the process of producing a final image on paper for viewing, using chemically sensitized paper. The paper is exposed to a photographic negative, a positive transparency , or a digital image file projected using an enlarger or digital exposure unit such as a LightJet or Minilab printer. Alternatively, the negative or transparency may be placed atop the paper and directly exposed, creating a contact print. Digital photographs are commonly printed on plain paper, for example by a color printer, but this is not considered "photographic printing".

C-41 is a chromogenic color print film developing process introduced by Kodak in 1972, superseding the C-22 process. C-41, also known as CN-16 by Fuji, CNK-4 by Konica, and AP-70 by AGFA, is the most popular film process in use, with most photofinishing labs devoting at least one machine to this development process.

Silver bromide (AgBr) is a soft, pale-yellow, water-insoluble salt well known for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic materials. AgBr is widely used in photographic films and is believed by some to have been used for making the Shroud of Turin. The salt can be found naturally as the mineral bromargyrite.

Panchromatic emulsion is a type of black-and-white photographic emulsion that is sensitive to all wavelengths of visible light.

Latent image An invisible image produced by the exposure of a photosensitive material to light.

A latent image is an invisible image produced by the exposure to light of a photosensitive material such as photographic film. When photographic film is developed, the area that was exposed darkens and forms a visible image. In the early days of photography, the nature of the invisible change in the silver halide crystals of the film's emulsion coating was unknown, so the image was said to be "latent" until the film was treated with photographic developer.

Film grain

Film grain or granularity is the random optical texture of processed photographic film due to the presence of small particles of a metallic silver, or dye clouds, developed from silver halide that have received enough photons. While film grain is a function of such particles it is not the same thing as such. It is an optical effect, the magnitude of which depends on both the film stock and the definition at which it is observed. It can be objectionably noticeable in an over-enlarged film photograph.

Chromogenic photography is photography that works by a chromogen forming a conventional silver image and then replacing it with a dye image. Most films and papers used for color photography today are chromogenic, using three layers, each providing their own subtractive color. Some chromogenic films provide black-and-white negatives, and are processed in standard color developers. In this case, the dyes are a neutral color.

Color motion picture film Photographic film type

Color motion picture film refers both to unexposed color photographic film in a format suitable for use in a motion picture camera, and to finished motion picture film, ready for use in a projector, which bears images in color.

K-14 process

K-14 was the most recent version of the developing process for Kodak's Kodachrome transparency film before its discontinuation. It superseded previous versions of the Kodachrome process used with older films.

Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric.

Photographic film Film used by film (analog) cameras

Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and resolution of the film.

Photographic hypersensitization refers to a set of processes that can be applied to photographic film or plates before exposing. One or more of these processes is often needed to make photographic materials work better in long exposures.

References

    Further reading