Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science.
In statistical mechanics, the virial theorem provides a general equation that relates the average over time of the total kinetic energy of a stable system of discrete particles, bound by a conservative force with that of the total potential energy of the system. Mathematically, the theorem states where T is the total kinetic energy of the N particles, Fk represents the force on the kth particle, which is located at position rk, and angle brackets represent the average over time of the enclosed quantity. The word virial for the right-hand side of the equation derives from vis, the Latin word for "force" or "energy", and was given its technical definition by Rudolf Clausius in 1870.
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by , , or and is measured in W·m−1·K−1.
In fluid mechanics, the Rayleigh number (Ra, after Lord Rayleigh) for a fluid is a dimensionless number associated with buoyancy-driven flow, also known as free (or natural) convection. It characterises the fluid's flow regime: a value in a certain lower range denotes laminar flow; a value in a higher range, turbulent flow. Below a certain critical value, there is no fluid motion and heat transfer is by conduction rather than convection. For most engineering purposes, the Rayleigh number is large, somewhere around 106 to 108.
In fluid dynamics, turbulence or turbulent flow is fluid motion characterized by chaotic changes in pressure and flow velocity. It is in contrast to laminar flow, which occurs when a fluid flows in parallel layers with no disruption between those layers.
In thermodynamics, the Helmholtz free energy is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature (isothermal). The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process in which temperature is held constant. At constant temperature, the Helmholtz free energy is minimized at equilibrium.
A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordance with Newton's third law. Most rocket engines use the combustion of reactive chemicals to supply the necessary energy, but non-combusting forms such as cold gas thrusters and nuclear thermal rockets also exist. Vehicles propelled by rocket engines are commonly used by ballistic missiles and rockets. Rocket vehicles carry their own oxidiser, unlike most combustion engines, so rocket engines can be used in a vacuum to propel spacecraft and ballistic missiles.
Thermoacoustic engines are thermoacoustic devices which use high-amplitude sound waves to pump heat from one place to another or use a heat difference to produce work in the form of sound waves.
The Rankine–Hugoniot conditions, also referred to as Rankine–Hugoniot jump conditions or Rankine–Hugoniot relations, describe the relationship between the states on both sides of a shock wave or a combustion wave in a one-dimensional flow in fluids or a one-dimensional deformation in solids. They are named in recognition of the work carried out by Scottish engineer and physicist William John Macquorn Rankine and French engineer Pierre Henri Hugoniot.
In thermodynamics, the Onsager reciprocal relations express the equality of certain ratios between flows and forces in thermodynamic systems out of equilibrium, but where a notion of local equilibrium exists.
In classical statistical mechanics, the equipartition theorem relates the temperature of a system to its average energies. The equipartition theorem is also known as the law of equipartition, equipartition of energy, or simply equipartition. The original idea of equipartition was that, in thermal equilibrium, energy is shared equally among all of its various forms; for example, the average kinetic energy per degree of freedom in translational motion of a molecule should equal that in rotational motion.
Thermoacoustics is the interaction between temperature, density and pressure variations of acoustic waves. Thermoacoustic heat engines can readily be driven using solar energy or waste heat and they can be controlled using proportional control. They can use heat available at low temperatures which makes it ideal for heat recovery and low power applications. The components included in thermoacoustic engines are usually very simple compared to conventional engines. The device can easily be controlled and maintained.
The Rijke tube is a cylindrical tube with both ends open, inside of which a heat source is placed that turns heat into sound, by creating a self-amplifying standing wave. It is an entertaining phenomenon in acoustics and is an excellent example of resonance.
The adiabatic theorem is a concept in quantum mechanics. Its original form, due to Max Born and Vladimir Fock (1928), was stated as follows:
Electrohydrodynamics (EHD), also known as electro-fluid-dynamics (EFD) or electrokinetics, is the study of the dynamics of electrically charged fluids. Electrohydrodynamics (EHD) is a joint domain of electrodynamics and fluid dynamics mainly focused on the fluid motion induced by electric fields. EHD, in its simplest form, involves the application of an electric field to a fluid medium, resulting in fluid flow, form, or properties manipulation. These mechanisms arise from the interaction between the electric fields and charged particles or polarization effects within the fluid. The generation and movement of charge carriers (ions) in a fluid subjected to an electric field are the underlying physics of all EHD-based technologies.
In fluid dynamics, an eddy is the swirling of a fluid and the reverse current created when the fluid is in a turbulent flow regime. The moving fluid creates a space devoid of downstream-flowing fluid on the downstream side of the object. Fluid behind the obstacle flows into the void creating a swirl of fluid on each edge of the obstacle, followed by a short reverse flow of fluid behind the obstacle flowing upstream, toward the back of the obstacle. This phenomenon is naturally observed behind large emergent rocks in swift-flowing rivers.
In fluid dynamics, a Tollmien–Schlichting wave is a streamwise unstable wave which arises in a bounded shear flow. It is one of the more common methods by which a laminar bounded shear flow transitions to turbulence. The waves are initiated when some disturbance interacts with leading edge roughness in a process known as receptivity. These waves are slowly amplified as they move downstream until they may eventually grow large enough that nonlinearities take over and the flow transitions to turbulence.
In fluid dynamics, the process of a laminar flow becoming turbulent is known as laminar–turbulent transition. The main parameter characterizing transition is the Reynolds number.
Combustion instabilities are physical phenomena occurring in a reacting flow in which some perturbations, even very small ones, grow and then become large enough to alter the features of the flow in some particular way.
In combustion, Michelson–Sivashinsky equation describes the evolution of a premixed flame front, subjected to the Darrieus–Landau instability, in the small heat release approximation. The equation was derived by Gregory Sivashinsky in 1977, who along the Daniel M. Michelson, presented the numerical solutions of the equation in the same year. Let the planar flame front, in a uitable frame of reference be on the -plane, then the evolution of this planar front is described by the amplitude function describing the deviation from the planar shape. The Michelson–Sivashinsky equation, reads as
