Tripuhyite

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Tripuhyite
Tripuhyite.jpg
Tripuhyite from the Tafone Mine, Grosseto Province, Tuscany, Italy
General
Category Antimonate mineral
Formula
(repeating unit)
FeSbO4
IMA symbol Tpy [1]
Strunz classification 4.DB.05
Crystal system Tetragonal
Crystal class Ditetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Space group P41/mnm
Unit cell a = 4.63, c = 9.14 [Å]; Z = 2
Identification
ColorYellowish brown, lemon-yellow, brown-black
Crystal habit Fibrous to fine-grained aggregates
Mohs scale hardness6 - 7
Luster Dull to earthy
Streak Canary-yellow to dark brown with a greenish tinge
Diaphaneity Translucent
Specific gravity 5.82
Optical propertiesUniaxial (+), canary-yellow color (transmitted light)
Refractive index nω = 2.190 nε = 2.330
Birefringence δ = 0.140
Pleochroism None
Solubility Insoluble in acids
Other characteristics Antiferromagnetic
References [2] [3] [4]

Tripuhyite is an iron antimonate mineral with composition FeSbO4.

Contents

Nomenclature

The name of the mineral comes from the locality of Tripuhy, Ouro Preto, Minas Gerais, Brazil, where it was discovered. Hussak and Prior [5] first described the mineral tripuhyite as an oxide of iron and antimony, and assigned it the composition Fe2Sb2O7. When a mineral with composition FeSbO4 was later discovered in Squaw Creek, New Mexico (US), it was considered erroneously as a new mineral and it was given the name squawcreekite. [6] However, other studies had shown that the original tripuhyite was also FeSbO4. [7] In 2002, the Commission on New Minerals and Mineral Names (CNMMN) of the International Mineralogical Association (IMA), approved the redefinition of tripuhyite as FeSbO4 and the discreditation of squawcreekite. [8]

Crystal Structure

FeSbO4 exhibits the rutile structure, with a tetragonal unit cell. The cations are octahedrally coordinated to oxygen anions, with the octahedra sharing edges along the c-direction. Fe(III) and Sb(V) cations are distributed in a disordered way over the octahedral sites.

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2
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<span class="mw-page-title-main">Zemannite</span>

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<span class="mw-page-title-main">Sarkinite</span>

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<span class="mw-page-title-main">Hidalgoite</span> Mineral of the beudantite group

Hidalgoite, PbAl3(AsO4)(SO4)(OH)4, is a rare member of the beudantite group and is usually classified as part of the alunite family. It was named after the place where it was first discovered, the Zimapán mining district, Hidalgo, Mexico. At Hidalgo where it was initially discovered, it was found as dense white masses in alternating dikes of quartz latite and quartz monzonite alongside other secondary minerals such as sphalerite, arsenopyrite, cerussite and trace amounts of angelsite and alamosite, it was then rediscovered at other locations such as Australia where it occurs on oxidized shear zones above greywacke shales especially on the anticline prospects of the area, and on fine grained quartz-spessartine rocks in Broken Hill, Australia. Hidalgoite specimens are usually associated with copper minerals, clay minerals, iron oxides and polymetallic sulfides in occurrence.

Filipstadite is a very rare mineral of the spinel group, with the formula (Mn,Mg)(Sb5+0.5Fe3+0.5)O4. It is isometric, although it was previously thought to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. Filipstadite is chemically close to melanostibite. The mineral comes from Långban, Sweden, a manganese skarn deposit famous for many rare minerals.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Mindat.org
  3. Handbook of Mineralogy
  4. Webmineral data
  5. Hussak, E.; Prior, G. T. (1897). "On Tripuhyite, a New Antimonate of Iron, from Tripuhy, Brazil". Mineralogical Magazine. 11 (53): 302–303. Bibcode:1897MinM...11..302H. doi:10.1180/minmag.1897.011.53.04.
  6. Foord, E. E.; P. F. Hlava; J. J. Fitzpatrick; R. C. Erd; R. W. Hinton (1991). Neues Jahrbuch für Mineralogie - Monatshefte. 8: 363–384.{{cite journal}}: Missing or empty |title= (help)
  7. Tavora, E. (1955). "X-ray diffraction powder data for some minerals from Brazilian localities". Anais da Academia Brasileira de Ciências. 27: 7–27.
  8. Berlepsch, P.; T. Armbruster; J. Brugger; A. J. Criddle; S. Graeser (2003). "Tripuhyite, FeSbO4, revisited". Mineralogical Magazine. 67 (1): 31–46. Bibcode:2003MinM...67...31B. doi:10.1180/0026461036710082. S2CID   54551345.

Bibliography