Vanadiocarpholite

Last updated
Vanadiocarpholite
General
Category Silicate mineral
Formula
(repeating unit)
Mn+2V+3AlSi2O6(OH)4
IMA symbol Vcar [1]
Strunz classification 9.DB.05
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Ccca
Unit cell a = 13.83  Å, b = 20.681 Å
c = 5.188 Å; Z = 8
Identification
ColorPale-straw yellow, honey-yellow to brown
Crystal habit Prismatic to acicular crystal clusters, vein fillings
Cleavage Perfect on {010}
Tenacity Flexible
Luster Vitreous, silky
Diaphaneity Transparent
Optical propertiesBiaxial (+)
Refractive index nα=1.684, nβ=1.691, nγ=1.7
Birefringence 0.0160
References [2] [3]

Vanadiocarpholite (Mn+2V+3AlSi2O6(OH)4) is straw yellow to brown silicate mineral. It crystallizes in the orthorhombic crystal system. It is the vanadium rich variety of carpholite (Mn+2Al2Si2O6(OH)4).

Contents

Discovery and occurrence

It was first described in 2005 for an occurrence in the Molinello Mine, Graveglia Valley, Genova Province, Liguria, Italy. [3] It occurs in chert in a manganese ore deposit as vein fillings in silicified wood. [2]

Chemical composition

It consists of: [2]

Manganese15.56%Mn20.09%MnO
Aluminium7.64%Al14.44%Al2O3
Vanadium14.43%V21.23%V2O3
Silicon15.91%Si34.04%SiO2
Hydrogen1.14%H10.21%H2O
Oxygen45.32%O

Related Research Articles

<span class="mw-page-title-main">Axinite</span>

Axinite is a brown to violet-brown, or reddish-brown bladed group of minerals composed of calcium aluminium boro-silicate, (Ca,Fe,Mn)3Al2BO3Si4O12OH. Axinite is pyroelectric and piezoelectric.

<span class="mw-page-title-main">Zinnwaldite</span>

Zinnwaldite, KLiFeAl(AlSi3)O10(OH,F)2, potassium lithium iron aluminium silicate hydroxide fluoride is a silicate mineral in the mica group. The IMA status is as a series between siderophyllite (KFe2Al(Al2Si2)O10(F,OH)2) and polylithionite (KLi2AlSi4O10(F,OH)2) and not considered a valid mineral species.

<span class="mw-page-title-main">Paragonite</span>

Paragonite is a mineral, related to muscovite. Its empirical formula is NaAl2(AlSi3O10)(OH)2. A wide solvus separates muscovite from paragonite, such that there is little solid solution along the vector Na+K+ and apparent micas of intermediate composition is most commonly a microscopic (or even sub-microscopic) intergrowth of two distinct micas, one rich in K, and the other in Na. Paragonite is a common mineral in rocks metamorphosed under blueschist facies conditions along with other sodic minerals such as albite, jadeite and glaucophane. During the transition from blueschist to greenschist facies, paragonite and glaucophane are transformed into chlorite and albite. Jadeite bearing pyroxene minerals have suggested Clinozoisite and paragonite are associated and derived from lawsonite releasing Quartz and water via the following reaction:

<span class="mw-page-title-main">Clinozoisite</span>

Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote.

<span class="mw-page-title-main">Chloritoid</span>

Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2
Al
4
Si
2
O
10
(OH)
4
. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.

<span class="mw-page-title-main">Zakharovite</span>

Zakharovite is a mineral, a silicate of sodium and manganese; formula Na4Mn5Si10O24(OH)6·6H2O. It has a yellow colour with a pearly lustre. Discovered in 1982 in the Kola peninsula of Northern Russia, it is named after Evgeny Evgenevich Zakharov (1902–1980), the director of the Moscow Institute of Geological Exploration.

<span class="mw-page-title-main">Pumpellyite</span> Pumpellyite series

Pumpellyite is a group of closely related sorosilicate minerals:

<span class="mw-page-title-main">Aliettite</span>

Aliettite is a complex phyllosilicate mineral of the smectite group with a formula of (Ca0.2Mg6(Si,Al)8O20(OH)4·4H2O) or [Mg3Si4O10(OH)2](Ca0.5,Na)0.33(Al,Mg,Fe2+)2-3(Si,Al)4O10(OH)2·n(H2O).

<span class="mw-page-title-main">Jerrygibbsite</span>

Jerrygibbsite is a rare silicate mineral with the chemical formula (Mn,Zn)9(SiO4)4(OH)2. Jerrygibbsite was originally discovered by Pete J. Dunn in 1984, who named it after mineralogist Gerald V. Gibbs. It has only been reported from the type locality of Franklin Furnace, New Jersey, United States, and in Namibia's Otjozondjupa region. Jerrygibbsite is member of the leucophoenite family of the humite group. It is always found with these two minerals. It is a dimorph of sonolite.

<span class="mw-page-title-main">Piemontite</span>

Piemontite is a sorosilicate mineral in the monoclinic crystal system with the chemical formula Ca2(Al,Mn3+,Fe3+)3(SiO4)(Si2O7)O(OH). It is a member of the epidote group.

<span class="mw-page-title-main">Gedrite</span>

Gedrite is a crystal belonging to the orthorhombic ferromagnesian subgroup of the amphibole supergroup of the double chain inosilicate minerals with the ideal chemical formula Mg2(Mg3Al2)(Si6Al2)O22(OH)2.

Alluaivite is a rare mineral of the eudialyte group, with complex formula written as Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl·2H2O. It is unique among the eudialyte group as the only titanosilicate (other representatives of the group are usually zirconosilicates). The two dual-nature minerals of the group, being both titano- and zirconosilicates, are labyrinthite and dualite. They both contain alluaivite module in their structures. Alluaivite is named after Mt. Alluaiv in Lovozero Tundry massif, Kola Peninsula, Russia, where it is found in ultra-agpaitic, hyperalkaline pegmatites.

<span class="mw-page-title-main">Carpholite</span>

Carpholite is a manganese silicate mineral with formula Mn2+Al2Si2O6(OH)4. It occurs as yellow clusters of slender prisms or needles. It crystallizes in the orthorhombic system.

Eveslogite is a complex inosilicate mineral with a chemical formula (Ca,K,Na,Sr,Ba)
48
[(Ti,Nb,Fe,Mn)
12
(OH)
12
Si
48
O
144
](F,OH,Cl)
14
found on Mt. Eveslogchorr in Khibiny Mountains, on the Kola peninsula, Russia. It was named after the place it was found. This silicate mineral occurs as an anchimonomineral veinlet that cross-cuts poikilitic nepheline syenite. This mineral appears to resemble yuksporite, as it forms similar placated fine fibrous of approximately 0.05 to 0.005mm that aggregates outwardly. The color of eveslogite is yellow or rather light brown. In addition, it is a semitransparent mineral that has a white streak and a vitreous luster. Its crystal system is monoclinic and possesses a hardness (Mohs) of 5. This newly discovered mineral belongs to the astrophyllite group of minerals and contains structures that are composed of titanosilicate layers. Limited information about this mineral exists due to the few research studies carried out since its recent discovery.

Franklinphilite is a phyllosilicate of the stilpnomelane group. Known from only two localities It was found exclusively from the Franklin and Sterling Hill mines in Franklin, Sussex County, New Jersey. until 2013, when a locality in Wales was confirmed

<span class="mw-page-title-main">Hubeite</span>

The mineral hubeite, Ca
2
Mn2+
Fe3+
[Si
4
O
12
(OH)]·(H
2
O)
2
, is a sorosilicate of the Si
4
O
13
group. Structurally it also belongs to the Akatoreite group. It was found and named after the province of Hubei, China. It is common to iron ores in a mine of that region. It occurs mainly as aggregates of fan like crystals. It is dark to pale brown, has orange-brown streak and is vitreous. Hubeite has a hardness of 5.5 in the Mohs scale, one good cleavage and conchoidal fracture. It is triclinic with a space group of P1*. The structure of hubeite is very uncommon, and in fact there is only one other mineral that fits the Si
4
O
13
group, which is ruizite.

Carbokentbrooksite is a very rare mineral of the eudialyte group, with formula (Na,□)12(Na,Ce)3Ca6Mn3Zr3NbSiO(Si9O27)2(Si3O9)2(OH)3(CO3).H2O. The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group. Carbokenbrooksite characterizes in being carbonate-rich (the other eudialyte-group species with essential carbonate are zirsilite-(Ce), golyshevite, and mogovidite). It is also sodium rich, being sodium equivalent of zirsilite-(Ce), with which it is intimately associated.

<span class="mw-page-title-main">Zirsilite-(Ce)</span>

Zirsilite-(Ce) is a very rare mineral of the eudialyte group, with formula (Na,□)12(Ce,Na)3Ca6Mn3Zr3NbSi(Si9O27)2(Si3O9)2O(OH)3(CO3)·H2O. The original formula was extended to show the presence of cyclic silicate groups and the presence of silicon at the M4 site, according to the nomenclature of the eudialyte group.according to the nomenclature of eudialyte group. Zirsilite-(Ce) differs from carbokentbrooksite in cerium-dominance over sodium only. Both minerals are intimately associated. The only other currently known representative of the eudialyte group having rare earth elements (in particular cerium, as suggested by the "-Ce)" Levinson suffix in the name) in dominance is johnsenite-(Ce).

Oneillite is a rare mineral of the eudialyte group with the chemical formula Na15Ca3Mn3Fe2+3Zr3NbSiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2. The formula is based on the original one but extended to show the presence of cyclic silicate groups and domination of Si at the M4 site. The mineral has lowered symmetry (space group R3, instead of more specific for the group R3m one) due to Ca-Mn ordering. Similar feature is displayed by some other eudialyte-group members: aqualite, labyrinthite, raslakite, and voronkovite. Oneillite is strongly enriched in rare earth elements (REE, mainly cerium), but REE do not dominate any of its sites.

<span class="mw-page-title-main">Alpeite</span>

Alpeite (IMA symbol: Apt) is a calcium manganese magnesium silicate mineral with the chemical formula Ca4Mn3+2Al2(Mn3+Mg)(SiO4)2(Si3O10)(V5+O4)(OH)6. It is named for its type locality, the Monte Alpe mine in Italy.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Vanadiocarpholite data on Webmineral.com
  3. 1 2 Vanadiocarpholite on Mindat.org