Chromium(II) sulfide

Last updated
Chromium(II) sulfide
CrS.png
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/Cr.S/q+2;-2
    Key: LXEAUGDQDABWTN-UHFFFAOYSA-N
  • [S-2].[Cr+2]
Properties
CrS
Molar mass 84.061 g/mol
Appearanceblack crystals
Melting point 1,550 °C (2,820 °F; 1,820 K)
insoluble
Related compounds
Related compounds
Chromium(III) sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Chromium(II) sulfide is an inorganic compound of chromium and sulfur with the chemical formula CrS. [1] [2] [3] The compound forms black hexagonal crystals, insoluble in water. [4]

Contents

Synthesis

Chromium(II) sulfide may be formed by reaction of chromium metal with sulfur or hydrogen sulfide at high temperature. It may also be formed by reacting chromium(III) chloride with H2S, reducing chromium(III) sulfide with hydrogen, or by double replacement reaction of lithium sulfide with chromium(II) chloride. [5]

Physical properties

Chromium(II) sulfide forms black paramagnetic crystals of two crystalline modifications: [6]

Chromium(II) sulfide is a semiconductor, [7] [8] and is also used as a catalyst. [9]

Chemical properties

Chromium(II) sulfide slowly oxidizes in air:[ citation needed ]

Related Research Articles

<span class="mw-page-title-main">Potassium oxide</span> Chemical compound

Potassium oxide (K2O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertilizers and cements, are assayed assuming the percent composition that would be equivalent to K2O.

<span class="mw-page-title-main">Cadmium sulfide</span> Chemical compound

Cadmium sulfide is the inorganic compound with the formula CdS. Cadmium sulfide is a yellow salt. It occurs in nature with two different crystal structures as the rare minerals greenockite and hawleyite, but is more prevalent as an impurity substituent in the similarly structured zinc ores sphalerite and wurtzite, which are the major economic sources of cadmium. As a compound that is easy to isolate and purify, it is the principal source of cadmium for all commercial applications. Its vivid yellow color led to its adoption as a pigment for the yellow paint "cadmium yellow" in the 18th century.

In chemistry, disproportionation, sometimes called dismutation, is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states. The reverse of disproportionation, such as when a compound in an intermediate oxidation state is formed from precursors of lower and higher oxidation states, is called comproportionation, also known as synproportionation.

<span class="mw-page-title-main">Chromium(III) oxide</span> Chemical compound

Chromium(III) oxide is an inorganic compound with the formula Cr
2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

<span class="mw-page-title-main">Chromium(II) chloride</span> Chemical compound

Chromium(II) chloride describes inorganic compounds with the formula CrCl2(H2O)n. The anhydrous solid is white when pure, however commercial samples are often grey or green; it is hygroscopic and readily dissolves in water to give bright blue air-sensitive solutions of the tetrahydrate Cr(H2O)4Cl2. Chromium(II) chloride has no commercial uses but is used on a laboratory-scale for the synthesis of other chromium complexes.

<span class="mw-page-title-main">Aluminium sulfide</span> Chemical compound

Aluminium sulfide is a chemical compound with the formula Al2S3. This colorless species has an interesting structural chemistry, existing in several forms. The material is sensitive to moisture, hydrolyzing to hydrated aluminum oxides/hydroxides. This can begin when the sulfide is exposed to the atmosphere. The hydrolysis reaction generates gaseous hydrogen sulfide (H2S).

<span class="mw-page-title-main">Silicon disulfide</span> Chemical compound

Silicon disulfide is the inorganic compound with the formula SiS2. Like silicon dioxide, this material is polymeric, but it adopts a 1-dimensional structure quite different from the usual forms of SiO2.

<span class="mw-page-title-main">Gold compounds</span>

Gold compounds are compounds by the element gold (Au). Although gold is the most noble of the noble metals, it still forms many diverse compounds. The oxidation state of gold in its compounds ranges from −1 to +5, but Au(I) and Au(III) dominate its chemistry. Au(I), referred to as the aurous ion, is the most common oxidation state with soft ligands such as thioethers, thiolates, and organophosphines. Au(I) compounds are typically linear. A good example is Au(CN)−2, which is the soluble form of gold encountered in mining. The binary gold halides, such as AuCl, form zigzag polymeric chains, again featuring linear coordination at Au. Most drugs based on gold are Au(I) derivatives.

<span class="mw-page-title-main">Selenium compounds</span> Chemical compounds containing selenium

Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states, the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite, guanajuatite, tiemannite, crookesite etc., and can also coexist with sulfide minerals such as pyrite and chalcopyrite. For many mammals, selenium compounds are essential. For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins. The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine, making some proteins have antioxidant activity. Selenium compounds have important applications in semiconductors, glass and ceramic industries, medicine, metallurgy and other fields.

<span class="mw-page-title-main">Chromium compounds</span> Chemical compounds containing chromium

Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals. The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist.

A polysulfane is a chemical compound of formula H2Sn, where n > 1. Compounds containing 2 – 8 sulfur atoms have been isolated, longer chain compounds have been detected, but only in solution. H2S2 is colourless, higher members are yellow with the colour increasing with the sulfur content. In the chemical literature the term polysulfanes is sometimes used for compounds containing −(S)n, e.g. organic polysulfanes R1−(S)n−R2.

Antimony pentasulfide is an inorganic compound of antimony and sulfur, also known as antimony red. It is a nonstoichiometric compound with a variable composition. Its structure is unknown. Commercial samples are contaminated with sulfur, which may be removed by washing with carbon disulfide in a Soxhlet extractor.

Iron(III) sulfide, also known as ferric sulfide or sesquisulfide, is one of the several binary iron sulfides. It is a solid, black powder that degrades at ambient temperature.

Chromium(III) hydroxide is a gelatinous green inorganic compound with the chemical formula Cr(OH)3. It is a polymer with an undefined structure and low solubility. It is amphoteric, dissolving in both strong alkalis and strong acids.

Chromium(II) hydride, systematically named chromium dihydride and poly­(dihydridochromium) is pale brown solid inorganic compound with the chemical formula (CrH2)n. Although it is thermodynamically unstable toward decomposition at ambient temperatures, it is kinetically metastable.

<span class="mw-page-title-main">Chromium(IV) fluoride</span> Chemical compound

Chromium(IV) fluoride is an inorganic compound with the chemical formula CrF4. It has a dark greenish-black color when solid. It rapidly hydrolysizes in presence of moisture in air or directly in water.

<span class="mw-page-title-main">Metal peroxide</span>

Metal peroxides are metal-containing compounds with ionically- or covalently-bonded peroxide (O2−
2
) groups. This large family of compounds can be divided into ionic and covalent peroxide. The first class mostly contains the peroxides of the alkali and alkaline earth metals whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid (H2SO5). In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metals have a more covalent character.

<span class="mw-page-title-main">Neptunium(III) chloride</span> Chemical compound

Neptunium(III) chloride or neptunium trichloride is an inorganic compound with a chemical formula NpCl3. This salt is strongly radioactive.

Tungsten trisulfide is an inorganic compound of tungsten and sulfur with the chemical formula WS3. The compound looks like chocolate-brown powder.

Polonium sulfide is an inorganic compound of polonium and sulfur with the chemical formula PoS. The compound is radioactive and forms black crystals.

References

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  2. Wiberg, Egon; Holleman, A. F.; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 1372. ISBN   978-0-12-352651-9 . Retrieved 1 November 2021.
  3. Sr, Richard J. Lewis (13 June 2008). Hazardous Chemicals Desk Reference. John Wiley & Sons. p. 670. ISBN   978-0-470-18024-2 . Retrieved 1 November 2021.
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  5. Wadhawan, Amar R.; Livi, Kenneth J.; Stone, Alan T.; Bouwer, Edward J. (2015-03-17). "Influence of oxygenation on chromium redox reactions with manganese sulfide (MnS(s))". Environmental Science & Technology. 49 (6): 3523–3531. doi:10.1021/es5057165. ISSN   1520-5851. PMID   25688449.
  6. PubChem (2002). "Chromium sulfide (CrS)". PubChem . National Library of Medicine. 40 (1): 24–26. PMID   11955372. Archived from the original on 2022-09-04. Retrieved 2022-09-04.
  7. Riedel, Erwin; Janiak, Christoph (2011). Anorganische Chemie (in German). Walter de Gruyter. p. 732. ISBN   978-3-11-022566-2.
  8. Holleman, A. F.; Wiberg, E.; Wiberg, N. (1995). Lehrbuch der Anorganischen Chemie. 101. Auflage (in German). Walter de Gruyter. p. 1451. ISBN   3-11-012641-9.
  9. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3082. ISBN   978-0-412-30120-9 . Retrieved 1 November 2021.