Chrozophora tinctoria

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Dyer's croton
ChrozophoraTinctoria.JPG
Scientific classification OOjs UI icon edit-ltr.svg
Kingdom: Plantae
Clade: Tracheophytes
Clade: Angiosperms
Clade: Eudicots
Clade: Rosids
Order: Malpighiales
Family: Euphorbiaceae
Genus: Chrozophora
Species:
C. tinctoria
Binomial name
Chrozophora tinctoria
Synonyms [1]
  • Croton tinctoriusL.
  • Ricinoides tinctoria(L.) Moench
  • Tournesol tinctoria(L.) Baill.
  • Croton argenteusForssk. 1775 not L. 1753
  • Croton obliquusVahl
  • Croton verbascifoliusWilld.
  • Croton patulusLag.
  • Chrozophora hierosolymitanaSpreng.
  • Chrozophora obliqua(Vahl) A.Juss. ex Spreng.
  • Chrozophora verbascifolia(Willd.) A.Juss. ex Spreng.
  • Croton oblongifoliusSieber ex Spreng.
  • Chrozophora villosaLindl.
  • Chrozophora sieberiC.Presl
  • Chrozophora integrifoliaBunge
  • Tournesol warionii(Coss. ex Batt. & Trab.) Baill.
  • Tournesol obliqua(Vahl) Franch.
  • Chrozophora warioniiCoss. ex Batt.
  • Tournesol verbascifolia(Willd.) Kuntze
  • Chrozophora glabrata(Heldr.) Pax & K.Hoffm.
  • Chrozophora subplicata(Müll.Arg.) Pax & K.Hoffm.
  • Chrozophora cordifoliaPazij
  • Chrozophora lepidocarpaPazij

Chrozophora tinctoria (commonly known as dyer's croton, [2] giradol, [2] turnsole [2] or dyer's litmus plant [3] ) is a plant species native to the Mediterranean, the Middle East, India, Pakistan, and Central Asia. [1] [4] [5] [6] It is also present as a weed in North America and Australia. [7]

Contents

Description

It is an annual, typically found in nutrient-poor ground. It develops a large taproot. [7] The plant is erect and covered with wool-like hairs. [8] The ash-green leaves are alternate. The tiny monecious flowers are grouped in a raceme. The lower, female flowers lack petals and the upper male flowers have five small yellow petals. Pollination is by ants. [7] The fruits are conspicuous and consist of three dark green conjoined spheres. Their surface is decorated with white scales and warty structures. Each sphere contains three seeds, which are propelled away from the plant by the mechanical force of the mature fruit twisting as it opens. [7] It is considered a poisonous plant. Its consumption may cause stomach upset, vomiting, nausea, and diarrhoea. [9]

Use for dye

Chrozophora tinctoria produced the blue-purple colorant "turnsole" (also known as katasol [10] or folium [8] ) used in medieval illuminated manuscripts and as a food colorant in Dutch cheese and certain liquors. [11] Its use was mostly as substitute of the more expensive Tyrian purple, the famous dye obtained from Murex molluscs. [12] The color comes from the plant's fruit, specifically its dry outer coat. [10] The colorant is also obtained from the translucent sap contained in the plant cells when the leaves of the plant are broken off and exposed to the air. [13] Different shades of blue and purple may also be obtained when the juice extracts are exposed to the vapors emitted from ammonia (NH3), and which in France, during the late 19th century, was produced by applying fresh horse manure and urine to the fabric that was soaked with the plant extract. [13] The plant has historically been used throughout the Levant to dye clothing. [13] 100 kilograms (220 lb) of the plant produces 50 kilograms (110 lb) of sap, and with this quantity one is able to dye 25 kilograms (55 lb) of fabric rolls. [13]

In 2020, an interdisciplinary team of researchers from FCT NOVA, University of Porto and University of Aveiro, identified the complex chemical structure of the medieval purple-blue dye extracted from the fruits of Chrozophora tinctoria. [8] The chemical structure of the medieval dye was a mystery until now. [8] The extracts obtained showed a novel blue chemical, chrozophoridine as the main chromophore. [8] [14]

Related Research Articles

<span class="mw-page-title-main">Indigo</span> Color

Indigo is a term used for a number of hues in the region of blue. The word comes from the ancient dye of the same name. The term "indigo" can refer to the color of the dye, various colors of fabric dyed with indigo dye, a spectral color, one of the seven colors of the rainbow as described by Newton, or a region on the color wheel, and can include various shades of blue, ultramarine, and green-blue. Since the web era, the term has also been used for various purple and violet hues identified as "indigo", based on use of the term "indigo" in HTML web page specifications.

<i>Alkanna tinctoria</i> Species of flowering plant

Alkanna tinctoria, the dyer's alkanet or simply alkanet, is a herbaceous flowering plant in the borage family Boraginaceae. Its roots are used to produce a red dye. The plant is also known as dyers' bugloss, orchanet, Spanish bugloss, or Languedoc bugloss. It is native to the Mediterranean region. A. tinctoria has 30 chromosomes and is regarded as a dysploid at the tetraploid level.

<span class="mw-page-title-main">Purple</span> Range of colors with the hues between blue and red

Purple is a color similar in appearance to violet light. In the RYB color model historically used in the arts, purple is a secondary color created by combining red and blue pigments. In the CMYK color model used in modern printing, purple is made by combining magenta pigment with either cyan pigment, black pigment, or both. In the RGB color model used in computer and television screens, purple is created by mixing red and blue light in order to create colors that appear similar to violet light.

<span class="mw-page-title-main">Indigo dye</span> Chemical compound, food additive and dye

Indigo dye is an organic compound with a distinctive blue color. Indigo is a natural dye extracted from the leaves of some plants of the Indigofera genus, in particular Indigofera tinctoria. Dye-bearing Indigofera plants were commonly grown and used throughout the world, particularly in Asia, with the production of indigo dyestuff economically important due to the historical rarity of other blue dyestuffs.

<span class="mw-page-title-main">Tyrian purple</span> Natural dye extracted from Murex sea snails

Tyrian purple, also known as royal purple, imperial purple, or imperial dye, is a reddish-purple natural dye. The name Tyrian refers to Tyre, Lebanon, once Phoenicia. It is secreted by several species of predatory sea snails in the family Muricidae, rock snails originally known by the name Murex. In ancient times, extracting this dye involved tens of thousands of snails and substantial labour, and as a result, the dye was highly valued. The colored compound is 6,6'-dibromoindigo.

<i>Isatis tinctoria</i> Species of flowering plant

Isatis tinctoria, also called woad, dyer's woad, dyer's-weed, or glastum, is a flowering plant in the family Brassicaceae with a documented history of use as a blue dye and medicinal plant. Its genus name, Isatis, derives from the ancient Greek word for the plant, ἰσάτις. It is occasionally known as Asp of Jerusalem. Woad is also the name of a blue dye produced from the leaves of the plant. Woad is native to the steppe and desert zones of the Caucasus, Central Asia to Eastern Siberia and Western Asia but is now also found in South-Eastern and Central Europe and western North America.

<i>Hydrangea macrophylla</i> Species of flowering plant in the family Hydrangeaceae

Hydrangea macrophylla is a species of flowering plant in the family Hydrangeaceae, native to Japan. It is a deciduous shrub growing to 2 m (7 ft) tall by 2.5 m (8 ft) broad with large heads of pink or blue flowers in summer and autumn. Common names include bigleaf hydrangea, French hydrangea, lacecap hydrangea, mophead hydrangea, and hortensia. It is widely cultivated in many parts of the world in many climates. It is not to be confused with H. aspera 'Macrophylla'.

<i>Chrozophora</i> Genus of flowering plants

Chrozophora is a plant genus of the family Euphorbiaceae first described as a genus in 1824. It comprises monoecious herbs or undershrubs. The genus is widespread across Europe, Africa, and Asia.

<i>Indigofera tinctoria</i> Species of legume

Indigofera tinctoria, also called true indigo, is a species of plant from the bean family that was one of the original sources of indigo dye.

<span class="mw-page-title-main">Orcein</span>

Orcein, also archil, orchil, lacmus and C.I. Natural Red 28, are names for dyes extracted from several species of lichen, commonly known as "orchella weeds", found in various parts of the world. A major source is the archil lichen, Roccella tinctoria. Orcinol is extracted from such lichens. It is then converted to orcein by ammonia and air. In traditional dye-making methods, urine was used as the ammonia source. If the conversion is carried out in the presence of potassium carbonate, calcium hydroxide, and calcium sulfate, the result is litmus, a more complex molecule. The manufacture was described by Cocq in 1812 and in the UK in 1874. Edmund Roberts noted orchilla as a principal export of the Cape Verde islands, superior to the same kind of "moss" found in Italy or the Canary Islands, that in 1832 was yielding an annual revenue of $200,000. Commercial archil is either a powder or a paste. It is red in acidic pH and blue in alkaline pH.

<span class="mw-page-title-main">H&E stain</span> Histological stain method

Hematoxylin and eosin stain is one of the principal tissue stains used in histology. It is the most widely used stain in medical diagnosis and is often the gold standard. For example, when a pathologist looks at a biopsy of a suspected cancer, the histological section is likely to be stained with H&E.

<span class="mw-page-title-main">Litmus</span> Substance to test chemical acidity

Litmus is a water-soluble mixture of different dyes extracted from lichens. It is often absorbed onto filter paper to produce one of the oldest forms of pH indicator, used to test materials for acidity. In an acidic medium, blue litmus paper turns red, while in a basic or alkaline medium, red litmus paper turns blue. In short, it is a dye and indicator which is used to place substances on a pH scale.

<span class="mw-page-title-main">Kermes (dye)</span> Red dye derived from scale insects in genus Kermes

Kermes is a red dye derived from the dried bodies of the females of a scale insect in the genus Kermes, primarily Kermes vermilio. The Kermes insects are native in the Mediterranean region and are parasites living on the sap of the host plant, the Kermes oak and the Palestine oak.

<span class="mw-page-title-main">Turnsole</span>

Turnsole, katasol, or folium was a dyestuff prepared from the annual plant Chrozophora tinctoria.

<span class="mw-page-title-main">Anthocyanin</span> Class of chemical compounds

Anthocyanins, also called anthocyans, are water-soluble vacuolar pigments that, depending on their pH, may appear red, purple, blue, or black. In 1835, the German pharmacist Ludwig Clamor Marquart named a chemical compound that gives flowers a blue color, Anthokyan, in his treatise "Die Farben der Blüthen". Food plants rich in anthocyanins include the blueberry, raspberry, black rice, and black soybean, among many others that are red, blue, purple, or black. Some of the colors of autumn leaves are derived from anthocyanins.

<span class="mw-page-title-main">Alkannin</span> Chemical compound

Alkannin is a natural dye that is obtained from the extracts of Alkanna tinctoria which is found in the south of France. The dye is used as a food coloring and in cosmetics; the European E number schedule, it is numbered E103. It is used as a red-brown food additive in regions such as Australia. Alkannin is deep red in an acid and blue in an alkaline environment. The chemical structure as a naphthoquinone derivative was first determined by Brockmann in 1936. The R-enantiomer of alkannin is known as shikonin, and the racemic mixture of the two is known as shikalkin.

<span class="mw-page-title-main">Natural dye</span> Dye extracted from plant or animal sources

Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, and wood—and other biological sources such as fungi.

<span class="mw-page-title-main">Glossary of dyeing terms</span>

Dyeing is the craft of imparting colors to textiles in loose fiber, yarn, cloth or garment form by treatment with a dye. Archaeologists have found evidence of textile dyeing with natural dyes dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years. Natural insect dyes such as Tyrian purple and kermes and plant-based dyes such as woad, indigo and madder were important elements of the economies of Asia and Europe until the discovery of man-made synthetic dyes in the mid-19th century. Synthetic dyes quickly superseded natural dyes for the large-scale commercial textile production enabled by the industrial revolution, but natural dyes remained in use by traditional cultures around the world.

<span class="mw-page-title-main">Synthetic colorant</span>


A colorant is any substance that changes the spectral transmittance or reflectance of a material. Synthetic colorants are those created in a laboratory or industrial setting. The production and improvement of colorants was a driver of the early synthetic chemical industry, in fact many of today's largest chemical producers started as dye-works in the late 19th or early 20th centuries, including Bayer AG(1863). Synthetics are extremely attractive for industrial and aesthetic purposes as they have they often achieve higher intensity and color fastness than comparable natural pigments and dyes used since ancient times. Market viable large scale production of dyes occurred nearly simultaneously in the early major producing countries Britain (1857), France (1858), Germany (1858), and Switzerland (1859), and expansion of associated chemical industries followed. The mid-nineteenth century through WWII saw an incredible expansion of the variety and scale of manufacture of synthetic colorants. Synthetic colorants quickly became ubiquitous in everyday life, from clothing to food. This stems from the invention of industrial research and development laboratories in the 1870s, and the new awareness of empirical chemical formulas as targets for synthesis by academic chemists. The dye industry became one of the first instances where directed scientific research lead to new products, and the first where this occurred regularly.

<span class="mw-page-title-main">Chrozophoridin</span> Chemical compound

Chrozophoridin is a chemical used as a dye.

References

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  2. 1 2 3 "Chrozophora tinctoria". Germplasm Resources Information Network . Agricultural Research Service, United States Department of Agriculture . Retrieved 3 December 2012.
  3. Shmida, Avi (2005). MAPA's Dictionary of Plants and Flowers in Israel (in Hebrew). Tel-Aviv: MAPA Publishers. p. 250. OCLC   716569354., s.v. Chrozophora tinctoria
  4. Altervista Flora Italiana, Tornasole comune, Turn Sole, tournesol, tornasol, Lackmuskraut, Chrozophora tinctoria (L.) A. Juss.
  5. Zervous, S., Raus, T. & Yannitsaros, A. (2009). Additions to the flora of the island of Kalimnos (SE Aegean, Greece). Willdenowia 39: 165-177.
  6. Dobignard, A. & Chatelain, C. (2011). Index synonymique de la flore d'Afrique du nord 3: 1-449. Éditions des conservatoire et jardin botaniques, Genève.
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  9. Abid, Mushtaq Ahmad, Muhammad Zafar, Sadia Zafar, Mohamed Fawzy Ramadan, Ashwaq T. Althobaiti, Shazia Sultana, Omer Kilic, Trobjon Makhkamov, Akramjon Yuldashev, Oybek Mamarakhimov, Khislat Khaydarov, Afat O. Mammadova, Komiljon Komilov and Salman Majeed, Aqsa (December 2023). "Foliar epidermal and trichome micromorphological diversity among poisonous plants and their taxonomic significance". Folia Horticulturae . 35 (2): 243–274. doi: 10.2478/fhort-2023-0019 . ISSN   2083-5965.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  10. 1 2 Melo, Maria J.; Castro, Rita; Nabais, Paula; Vitorino, Tatiana (2018). "The book on how to make all the colour paints for illuminating books: unravelling a Portuguese Hebrew illuminators' manual". Heritage Science. 6: 44. doi: 10.1186/s40494-018-0208-z .
  11. Chrozophora, Folium cloth
  12. M. Aceto, E. Calà, A. Agostino, G. Fenoglio, A. Idone, C. Porte, M. Gulmini, On the identification of folium and orchil on illuminated manuscripts, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, http://dx.doi.org/10.1016/j.saa.2016.08.046
  13. 1 2 3 4 Ḳrispil, Nissim (1985). A Bag of Plants (The Useful Plants of Israel) (in Hebrew). Vol. 3 (Ṭ.-M.). Jerusalem: Cana Publishing House Ltd. pp. 627–629, 632–633. ISBN   965-264-011-5. OCLC   959573975., s.v. Chrozophora tinctoria
  14. "1000-Year-Old Mistery Unfolded With The Discovery Of Medieval Blue Dye Structure". Universidade Nova de Lisboa. 20 April 2020. Retrieved 22 April 2020.