Turnsole

Last updated
Hvalov zbornik, 1404. Illustrated Slavic manuscript from medieval Bosnia. Turnsole was an essential ingredient in some of the pigments used in such illustrations Hvalov zbornik1.jpg
Hvalov zbornik, 1404. Illustrated Slavic manuscript from medieval Bosnia. Turnsole was an essential ingredient in some of the pigments used in such illustrations

Turnsole, katasol, or folium was a dyestuff prepared from the annual plant Chrozophora tinctoria .

Contents

History

Turnsole became a mainstay of medieval manuscript illuminators starting with the development of the technique for extracting it in the thirteenth century, [1] when it joined the vegetable-based woad and indigo in the illuminator's repertory. Its use was mostly as substitute of the more expensive Tyrian purple, the famous dye obtained from Murex molluscs. [2] However, the queen of blue colorants was always the expensive lapis lazuli or its substitute azurite, ground to the finest powders. Turnsole was downgraded to a shading glaze and fell out of use in the illuminator's palette by the turn of the seventeenth century, with the easier availability of less fugitive mineral-derived blue pigments. According to its method of preparation, turnsole produced a range of translucent colors from blue, through purple to red, depending on its reaction to the acidity or alkalinity of its environment, in a chemical reaction, not understood in the Middle Ages, that is most familiar in the litmus test.

Chrozophora tinctoria fruit ChrozophoraTinctoria.JPG
Chrozophora tinctoria fruit

Folium ("leaf"), was actually derived from the three-lobed fruit (illustration), not the leaves, and medieval recipes are explicit that the fruits must not be broken, or the seeds released, during production of the pigment. [3] The fruits were collected in autumn (August, September).

In the early fifteenth century, Cennino Cennini, in his Libro dell' Arte gives a recipe "XVIII: How you should tint paper turnsole color" and "LXXVI To paint a purple or turnsole drapery in fresco." (though neither of these recipes use or describe turnsole). Textiles soaked in the dye vat would be left in a close damp cellar in an atmosphere produced by pans of urine. It was not realized that the decomposition of urea in the urine was producing ammonia, but the technique reminds us how foul-smelling was the dyer's art.

It was sold impregnated into small pieces of linen and then extracted for use. The colour has been attributed to several different chemicals, including an anthocyanin. [4] Production of the pigment is described in a 15th century manuscript and this was used as the basis of producing the dye. [5] Although the plant extracts do contain several anthocyanins, the colour is due to chrozophoridine, a hermidin derivative. [3]

Turnsole was used as a food colorant, mentioned in Du Fait de Cuisine which suggests steeping it in milk. The French Cook by François Pierre La Varenne (London 1653) mentions turnsole grated in water with a little powder of Iris. It was also used to dye red the rind of a cheese from the Netherlands. [3]

Herbals indicated that the plant grows on sunny, well-drained Mediterranean slopes and called it solsequium ("sun-follower") from its habit of turning its flowers to face the sun; alternatively it might be called "Greater Verucaria"; [6] early botanical works gave it synonyms of Morella, Heliotropium tricoccum and Croton tinctorium.

Medicinal uses

Medicinal properties were ascribed to it in the first century AD by Dioscorides in De Materia Medica and also in medieval pharmacopoeia texts. [3] There have now been studies in the 21st century demonstrating that it did not have significant anti-inflammatory properties. [7]

Notes

  1. Thompson, Daniel V. Jr; Hamilton, G.H. (1933). De Arte Illuminandi: The Technique of Manuscript Illumination. New Haven: Yale University Press. p. 41.
  2. M. Aceto, E. Calà, A. Agostino, G. Fenoglio, A. Idone, C. Porte, M. Gulmini, On the identification of folium and orchil on illuminated manuscripts, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, http://dx.doi.org/10.1016/j.saa.2016.08.046.
  3. 1 2 3 4 Nabais, P; Oliviera, J; Pina, F; Teixeira, N; de Freitas, V; Brás, NF; Clemente, A; Rangel, M; Silva, AMS; Melo, MJ (2020). "A 1000-year-old mystery solved: Unlocking the molecular structure for the medieval blue from Chrozophora tinctoria, also known as folium". Science Advances. 6 (16): eaaz7772. doi: 10.1126/sciadv.aaz7772 . PMC   7164948 . PMID   32426456.
  4. Schultz, Isaac (17 April 2020). "The Mystery of a Medieval Blue Ink Has Been Solved". Atlas Obscura. Retrieved 20 April 2020.
  5. Melo, Maria J.; Castro, Rita; Nabais, Paula; Vitorino, Tatiana (2018). "The book on how to make all the colour paints for illuminating books: unravelling a Portuguese Hebrew illuminators' manual". Heritage Science. 6: 44. doi: 10.1186/s40494-018-0208-z .
  6. So named in a recipe for producing the colorant, Pro tornasolio faciendo, British Library, Sloane MS 1754, folio 235 verso, quoted in Daniel V. Thompson, Jr., "Medieval Color-Making: Tractatus Qualiter Quilibet Artificialis Color Fieri Possit from Paris, B. N., MS. latin 6749", Isis22.2 (February 1935, pp. 456–468) p 458 note.
  7. Abdallah, HM; Almowallad, FH; Esmat, A; Shehata, IA; Abdel-Sattar, EA (2015). "Anti-inflammatory activity of flavonoids from Chrozophora tinctoria". Phytochemistry Letters. 13: 74–80. doi:10.1016/j.phytol.2015.05.008 . Retrieved 20 April 2020.

Related Research Articles

<span class="mw-page-title-main">Ink</span> Liquid or paste that contains pigments or dyes

Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thicker inks, in paste form, are used extensively in letterpress and lithographic printing.

<i>Alkanna tinctoria</i> Species of flowering plant

Alkanna tinctoria, the dyer's alkanet or simply alkanet, is a herbaceous flowering plant in the borage family Boraginaceae. Its roots are used to produce a red dye. The plant is also known as dyers' bugloss, orchanet, Spanish bugloss, or Languedoc bugloss. It is native to the Mediterranean region. A. tinctoria has 30 chromosomes and is regarded as a dysploid at the tetraploid level.

<span class="mw-page-title-main">Violet (color)</span> Color between blue and ultraviolet on the electromagnetic spectrum

Violet is the color of light at the short wavelength end of the visible spectrum. It is one of the seven colors that Isaac Newton labeled when dividing the spectrum of visible light in 1672. Violet light has a wavelength between approximately 380 and 435 nanometers. The color's name is derived from the Viola genus of flowers.

<span class="mw-page-title-main">Purple</span> Range of colors with the hues between blue and red

Purple is a color similar in appearance to violet light. In the RYB color model historically used in the arts, purple is a secondary color created by combining red and blue pigments in different proportions. In the CMYK color model used in modern printing, purple is made by combining magenta pigment with either cyan pigment, black pigment, or both. In the RGB color model used in computer and television screens, purple is created by mixing red and blue light in order to create colors that appear similar to violet light.

<span class="mw-page-title-main">Pigment</span> Colored material

A pigment is a powder used to add color or change visual appearance. Pigments are completely or nearly insoluble and chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli.

<span class="mw-page-title-main">Indigo dye</span> Chemical compound, food additive and dye

Indigo dye is an organic compound with a distinctive blue color. Indigo is a natural dye extracted from the leaves of some plants of the Indigofera genus, in particular Indigofera tinctoria; dye-bearing Indigofera plants were commonly grown and used throughout the world, in Asia in particular, as an important crop, with the production of indigo dyestuff economically important due to the historical rarity of other blue dyestuffs.

<span class="mw-page-title-main">Illuminated manuscript</span> Manuscript in which the text is supplemented by the addition of decoration

An illuminated manuscript is a formally prepared document where the text is decorated with flourishes such as borders and miniature illustrations. Often used in the Roman Catholic Church for prayers, liturgical services and psalms, the practice continued into secular texts from the 13th century onward and typically include proclamations, enrolled bills, laws, charters, inventories and deeds.

<span class="mw-page-title-main">Tyrian purple</span> Natural dye extracted from Murex sea snails

Tyrian purple, also known as, royal purple, imperial purple, or imperial dye, is a reddish-purple natural dye. The name Tyrian refers to Tyre, Lebanon. It is secreted by several species of predatory sea snails in the family Muricidae, rock snails originally known by the name 'Murex'. In ancient times, extracting this dye involved tens of thousands of snails and substantial labor, and as a result, the dye was highly valued. The colored compound is 6,6′-dibromoindigo.

<span class="mw-page-title-main">Food coloring</span> Substance used to color to food or drink

Food coloring, or color additive, is any dye, pigment, or substance that imparts color when it is added to food or drink. They can be supplied as liquids, powders, gels, or pastes. Food coloring is used in both commercial food production and domestic cooking. Food colorants are also used in a variety of non-food applications, including cosmetics, pharmaceuticals, home craft projects, and medical devices. Colorings may be natural or artificial/synthetic.

<i>Isatis tinctoria</i> Species of flowering plant

Isatis tinctoria, also called woad, dyer's woad, or glastum, is a flowering plant in the family Brassicaceae with a documented history of use as a blue dye and medicinal plant. Its genus name, Isatis, derives from the ancient Greek word for the plant, ἰσάτις. It is occasionally known as Asp of Jerusalem. Woad is also the name of a blue dye produced from the leaves of the plant. Woad is native to the steppe and desert zones of the Caucasus, Central Asia to Eastern Siberia and Western Asia but is now also found in South-Eastern and Central Europe and western North America.

In the visual arts, color theory is the body of practical guidance for color mixing and the visual effects of a specific color combination. Color terminology based on the color wheel and its geometry separates colors into primary color, secondary color, and tertiary color. The understanding of color theory dates to antiquity. Aristotle and Claudius Ptolemy already discussed which and how colors can be produced by mixing other colors. The influence of light on color was investigated and revealed further by al-Kindi and Ibn al-Haytham (d.1039). Ibn Sina, Nasir al-Din al-Tusi, and Robert Grosseteste discovered that contrary to the teachings of Aristotle, there are multiple color paths to get from black to white. More modern approaches to color theory principles can be found in the writings of Leone Battista Alberti and the notebooks of Leonardo da Vinci. A formalization of "color theory" began in the 18th century, initially within a partisan controversy over Isaac Newton's theory of color and the nature of primary colors. From there it developed as an independent artistic tradition with only superficial reference to colorimetry and vision science.

<i>Chrozophora</i> Genus of flowering plants

Chrozophora is a plant genus of the family Euphorbiaceae first described as a genus in 1824. It comprises monoecious herbs or undershrubs. The genus is widespread across Europe, Africa, and Asia.

<span class="mw-page-title-main">Rose madder</span> Red paint made from the madder plant

Rose madder is a red paint made from the pigment madder lake, a traditional lake pigment extracted from the common madder plant Rubia tinctorum.

<span class="mw-page-title-main">Brazilin</span> Chemical compound

Brazilin is a naturally occurring, a homoisoflavonoid, red dye obtained from the wood of Paubrasilia echinata, Biancaea sappan, Caesalpinia violacea, and Haematoxylum brasiletto. Brazilin has been used since at least the Middle Ages to dye fabric, and has been used to make paints and inks as well. The specific color produced by the pigment depends on its manner of preparation: in an acidic solution brazilin will appear yellow, but in an alkaline preparation it will appear red. Brazilin is closely related to the blue-black dye precursor hematoxylin, having one fewer hydroxyl group. Brazilein, the active dye agent, is an oxidized form of brazilin.

<span class="mw-page-title-main">Anthocyanin</span> Class of chemical compounds

Anthocyanins, also called anthocyans, are water-soluble vacuolar pigments that, depending on their pH, may appear red, purple, blue, or black. In 1835, the German pharmacist Ludwig Clamor Marquart gave the name Anthokyan to a chemical compound that gives flowers a blue color for the first time in his treatise "Die Farben der Blüthen". Food plants rich in anthocyanins include the blueberry, raspberry, black rice, and black soybean, among many others that are red, blue, purple, or black. Some of the colors of autumn leaves are derived from anthocyanins.

<span class="mw-page-title-main">Cochineal</span> Species of insect producing the crimson dye carmine

The cochineal is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessile parasite native to tropical and subtropical South America through North America, this insect lives on cacti in the genus Opuntia, feeding on plant moisture and nutrients. The insects are found on the pads of prickly pear cacti, collected by brushing them off the plants, and dried.

<i>Chrozophora tinctoria</i> Species of flowering plant

Chrozophora tinctoria is a plant species native to the Mediterranean, the Middle East, India, Pakistan, and Central Asia. It is also present as a weed in North America and Australia.

<span class="mw-page-title-main">Natural dye</span> Dye extracted from plant or animal sources

Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, and wood—and other biological sources such as fungi.

<span class="mw-page-title-main">Synthetic colorant</span>


A colorant is any substance that changes the spectral transmittance or reflectance of a material. Synthetic colorants are those created in a laboratory or industrial setting. The production and improvement of colorants was a driver of the early synthetic chemical industry, in fact many of today's largest chemical producers started as dye-works in the late 19th or early 20th centuries, including Bayer AG(1863). Synthetics are extremely attractive for industrial and aesthetic purposes as they have they often achieve higher intensity and color fastness than comparable natural pigments and dyes used since ancient times. Market viable large scale production of dyes occurred nearly simultaneously in the early major producing countries Britain (1857), France (1858), Germany (1858), and Switzerland (1859), and expansion of associated chemical industries followed. The mid-nineteenth century through WWII saw an incredible expansion of the variety and scale of manufacture of synthetic colorants. Synthetic colorants quickly became ubiquitous in everyday life, from clothing to food. This stems from the invention of industrial research and development laboratories in the 1870s, and the new awareness of empirical chemical formulas as targets for synthesis by academic chemists. The dye industry became one of the first instances where directed scientific research lead to new products, and the first where this occurred regularly.

<span class="mw-page-title-main">Chrozophoridin</span> Chemical compound

Chrozophoridin is a chemical used as a dye.