Linoleum

Last updated
Linoleum from around 1950 Linoleum 003.jpg
Linoleum from around 1950
Application of liquid linoleum. Aanbrengen vloeibaar linoleum..jpg
Application of liquid linoleum.

Linoleum is a floor covering made from materials such as solidified linseed oil (linoxyn), pine resin, ground cork dust, sawdust, and mineral fillers such as calcium carbonate, most commonly on a burlap or canvas backing. Pigments are often added to the materials to create the desired colour finish. Commercially, the material has been largely replaced by sheet vinyl flooring, although in the UK and Australia this is often still referred to as "lino". [1]

Contents

The finest linoleum floors, known as "inlaid", are extremely durable, and are made by joining and inlaying solid pieces of linoleum. Cheaper patterned linoleum comes in different grades or gauges, and is printed with thinner layers which are more prone to wear and tear. High-quality linoleum is flexible and thus can be used in buildings where a more rigid material (such as ceramic tile) would crack.

Technology

Chemical reactions associated with crosslinking of drying oils, the process that produces linoleum. DryOilSteps.svg
Chemical reactions associated with crosslinking of drying oils, the process that produces linoleum.
Representative fat found in a drying oil. The triester is derived from three different unsaturated fatty acids, linoleic (top), alpha-linolenic (middle), and oleic acids (bottom). The order of drying rate is alpha-linolenic > linoleic > oleic acid, reflecting their degree of unsaturation. ModelDryingOil.png
Representative fat found in a drying oil. The triester is derived from three different unsaturated fatty acids, linoleic (top), alpha-linolenic (middle), and oleic acids (bottom). The order of drying rate is alpha-linolenic > linoleic > oleic acid, reflecting their degree of unsaturation.

Linoleum in essence consists of two components, a polymerizable organic compound and a collection of fillers, pigments, catalysts. The polymerizable precursors are rich in polyunsaturated fats, especially derivatives of linoleic acid and alpha-linolenic acid. Such fats are called drying oils because they "dry" (harden) upon exposure to the oxygen in air. [2] The drying process results in cross-linking of the fat molecules. This crosslinking process is often slow, thus catalysts and heat are applied to give a durable material. During this crosslinking, fillers and pigments are mixed with the resin.

History

Early linoleum at Tyntesfield Tyntesfield 2015 087.jpg
Early linoleum at Tyntesfield

Linoleum was invented by Englishman Frederick Walton. [3] In 1855, Walton happened to notice the rubbery, flexible skin of solidified linseed oil (linoxyn) that had formed on a can of oil-based paint and thought that it might form a substitute for India rubber. Raw linseed oil oxidizes very slowly, but Walton accelerated the process by heating it with lead acetate [ clarification needed ] and zinc sulfate. This made the oil form a resinous mass into which lengths of cheap cotton cloth were dipped until a thick coating formed. The coating was then scraped off and boiled with benzene or similar solvents to form a varnish. Walton initially planned to sell his varnish to the makers of water-repellent fabrics such as oilcloth, and received Patent No. 209 on 27 January 1860 [4] for the process. However, his method had problems: the cotton cloth soon fell apart, and it took months to produce enough of the linoxyn. Little interest was shown in Walton's varnish. In addition, his first factory burned down, and he suffered from persistent and painful rashes.

Walton soon came up with an easier way to transfer the oil to the cotton sheets, by hanging them vertically and sprinkling the oil from above, and he tried mixing the linoxyn with sawdust and cork dust to make it less tacky. In 1863 he applied for a further patent, which read: "For these purposes canvas or other suitable strong fabrics are coated over on their upper surfaces with a composition of oxidized oil, cork dust, and gum or resin ... such surfaces being afterward printed, embossed, or otherwise ornamented. The back or under surfaces of such fabrics are coated with a coating of such oxidized oils, or oxidized oils and gum or resin, and by preference without an admixture of cork."

At first Walton called his invention "Kampticon", which was deliberately close to Kamptulicon, the name of an existing floor covering, but he soon changed it to Linoleum, which he derived from the Latin words linum (flax) and oleum (oil). In 1864 he established the Linoleum Manufacturing Company Ltd., with a factory at Staines, near London. The new product did not prove immediately popular, mainly due to intense competition from the makers of Kamptulicon and oilcloth. The company operated at a loss for its first five years, until Walton began an intensive advertising campaign and opened two shops in London for the exclusive sale of Linoleum. Walton's friend Jerimiah Clarke designed the linoleum patterns, typically with a Grecian urn motif around the borders.[ citation needed ]

Other inventors began their own experiments after Walton took out his patent, and in 1871 William Parnacott took out a patent for a method of producing linoxyn by blowing hot air into a tank of linseed oil for several hours, then cooling the material in trays. Unlike Walton's process, which took weeks, Parnacott's method took only a day or two, although the quality of the linoxyn was not as good. Despite this, many manufacturers opted to use the less expensive Parnacott process.

Walton soon faced competition from other manufacturers, including a company which bought the rights to Parnacott's process, and launched its own floor covering, which it named Corticine, from the Latin cortex (bark or rind). Corticine was mainly made of cork dust and linoxyn without a cloth backing, and became popular because it was cheaper than linoleum.

By 1869 Walton's factory in Staines, England was exporting to Europe and the United States. In 1877, the Scottish town of Kirkcaldy, in Fife, became the largest producer of linoleum in the world, with no fewer than six floorcloth manufacturers in the town, most notably Michael Nairn & Co., which had been producing floor cloth since 1847.

Walton opened the American Linoleum Manufacturing Company in 1872 on Staten Island, in partnership with Joseph Wild, the company's town being named Linoleumville (renamed Travis in 1930). [5] It was the first U.S. linoleum manufacturer, but was soon followed by the American Nairn Linoleum Company, established by Sir Michael Nairn in 1887 (later the Congoleum-Nairn Company, and then the Congoleum Corporation of America), in Kearny, New Jersey. Congoleum now manufactures sheet vinyl and no longer has a linoleum line.[ citation needed ]

Loss of trademark protection

Walton was unhappy with Michael Nairn & Co's use of the name Linoleum and brought a lawsuit against them for trademark infringement. However, the term had not been trademarked, and he lost the suit, the court opining that even if the name had been registered as a trademark, it was by now so widely used that it had become generic, [6] only 14 years after its invention. It is considered to be the first product name to become a generic term. [5]

Use

Between the time of its invention in 1860 and its being largely superseded by other hard floor coverings in the 1950s, linoleum was considered to be an excellent, inexpensive material for high-use areas. In the late nineteenth and early twentieth centuries, it was favoured in hallways and passages, and as a surround for carpet squares. However, most people associate linoleum with its common twentieth century use on kitchen floors. Its water resistance enabled easy maintenance of sanitary conditions and its resilience made standing easier and reduced breakage of dropped china.

Other products devised by Walton included Linoleum Muralis in 1877, which became better known as Lincrusta. Essentially a highly durable linoleum wall covering, Lincrusta could be manufactured to resemble carved plaster or wood, or even leather. It was very successful, and inspired a much cheaper imitation, Anaglypta, originally devised by one of Walton's showroom managers.

Walton also tried integrating designs into linoleum during the manufacturing stage, coming up with granite, marbled, and jaspé (striped) linoleum. For the granite variety, granules of various colours of linoleum cement were mixed together, before being hot-rolled. If the granules were not completely mixed before rolling, the result was marbled or jaspé patterns.

1928 advertisement for Armstrong Linoleum Armstrong Linoleum - 1928 advertisement.jpg
1928 advertisement for Armstrong Linoleum

Walton's next product was inlaid linoleum, which resembled encaustic tiles, in 1882. Previously, linoleum had been produced in solid colours, with patterns printed on the surface if required. In inlaid linoleum, the colours extend all the way through to the backing cloth. Inlaid linoleum was made using a stencil type method where different-coloured granules were placed in shaped metal trays, after which the sheets were run through heated rollers to fuse them to the backing cloth. In 1898 Walton devised a process for making straight-line inlaid linoleum that allowed for crisp, sharp geometric designs. This involved strips of uncured linoleum being cut and pieced together patchwork-fashion before being hot-rolled. Embossed inlaid linoleum was not introduced until 1926.

The heavier gauges of linoleum are known as "battleship linoleum", and are mainly used in high-traffic situations like offices and public buildings. It was originally manufactured to meet the specifications of the U.S. Navy for warship deck covering on enclosed decks instead of wood, hence the name. Most U.S. Navy warships removed their linoleum deck coverings following the attack on Pearl Harbor, as they were considered too flammable. (Use of linoleum persisted in U.S. Navy submarines.[ citation needed ]) Royal Navy warships used the similar product "Corticine".

Early in the twentieth century, a group of Dresden artists used easy-to-cut linoleum instead of wood for printmaking, creating the linocut printmaking technique – similar to woodcuts [ citation needed ]. Prominent artists who created linocut prints included Picasso and Henri Matisse.

Present day

As a floor covering, linoleum has often been replaced by polyvinyl chloride (PVC), referred to sometimes as vinyl. PVC has many properties that are superior to linoleum, including fire-resistance. [1] Linoleum is still used in art for linocut prints. Linoleum is also considered an environmentally friendly alternative to PVC as it is derived from renewable, natural, biodegradable material. [7]

Related Research Articles

<span class="mw-page-title-main">Oil painting</span> Process of painting with pigments that are bound with a medium of drying oil

Oil painting is a painting method involving the procedure of painting with pigments with a medium of drying oil as the binder. It has been the most common technique for artistic painting on canvas, wood panel or copper for several centuries, spreading from Europe to the rest of the world. The advantages of oil for painting images include "greater flexibility, richer and denser colour, the use of layers, and a wider range from light to dark". But the process is slower, especially when one layer of paint needs to be allowed to dry before another is applied.

Flooring is the general term for a permanent covering of a floor, or for the work of installing such a floor covering. Floor covering is a term to generically describe any finish material applied over a floor structure to provide a walking surface. Both terms are used interchangeably but floor covering refers more to loose-laid materials.

<span class="mw-page-title-main">Varnish</span> Transparent hard protective finish or film

Varnish is a clear transparent hard protective coating or film. It is not to be confused with wood stain. It usually has a yellowish shade due to the manufacturing process and materials used, but it may also be pigmented as desired. It is sold commercially in various shades.

<span class="mw-page-title-main">Linseed oil</span> Oil obtained from the dried, ripened seeds of the flax plant

Linseed oil, also known as flaxseed oil or flax oil, is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant. The oil is obtained by pressing, sometimes followed by solvent extraction.

<span class="mw-page-title-main">Patent leather</span> Type of coated leather

Patent leather is a type of coated leather that has a high-gloss finish.

<span class="mw-page-title-main">Drying oil</span> Oil that hardens after exposure to air

A drying oil is an oil that hardens to a tough, solid film after a period of exposure to air, at room temperature. The oil hardens through a chemical reaction in which the components crosslink by the action of oxygen. Drying oils are a key component of oil paint and some varnishes. Some commonly used drying oils include linseed oil, tung oil, poppy seed oil, perilla oil, and walnut oil. Their use has declined over the past several decades, as they have been replaced by alkyd resins and other binders.

<span class="mw-page-title-main">Vinyl composition tile</span> Flooring material

Vinyl composition tile (VCT) is a finished flooring material used primarily in commercial and institutional applications. Modern vinyl floor tiles and sheet flooring and versions of those products sold since the early 1980s are composed of colored polyvinyl chloride (PVC) chips formed into solid sheets of varying thicknesses by heat and pressure. Floor tiles are cut into modular shapes such 12-by-12-inch squares or 12-by-24-inch rectangles. In installation the floor tiles or sheet flooring are applied to a smooth, leveled sub-floor using a specially formulated vinyl adhesive or tile mastic that remains pliable. In commercial applications some tiles are typically waxed and buffed using special materials and equipment.

Kamptulicon, whose name was derived from the Greek kamptos ("flexible") + oulos ("thick"), was a floor covering made from powdered cork and natural rubber.

<span class="mw-page-title-main">Lincrusta</span>

Lincrusta is a deeply embossed wallcovering, invented by Frederick Walton. Walton was already known for patenting linoleum floor covering in 1860. Lincrusta was launched in 1877 and was used in a host of applications from royal homes to railway carriages. Many examples over a hundred years old can still be found throughout the world.

<span class="mw-page-title-main">Alkyd</span> Polyester resin modified by the addition of fatty acids and other components

An alkyd is a polyester resin modified by the addition of fatty acids and other components. Alkyds are derived from polyols and organic acids including dicarboxylic acids or carboxylic acid anhydride and triglyceride oils. The term alkyd is a modification of the original name "alcid", reflecting the fact that they are derived from alcohol and organic acids. The inclusion of a fatty acid confers a tendency to form flexible coatings. Alkyds are used in paints, varnishes and in moulds for casting. They are the dominant resin or binder in most commercial oil-based coatings. Approximately 200,000 tons of alkyd resins are produced each year. The original alkyds were compounds of glycerol and phthalic acid sold under the name Glyptal. These were sold as substitutes for the darker-colored copal resins, thus creating alkyd varnishes that were much paler in colour. From these, the alkyds that are known today were developed.

<span class="mw-page-title-main">Floorcloth</span>

A floorcloth, or floor-cloth, is a household furnishing used for warmth, decoration, or to protect expensive carpets. They were primarily produced and used from the early 18th to the early 20th century and were also referred to as oilcloth, wax cloths, and painted canvas. Some still use floorcloths as a customizable alternative to rugs, and some artists have elected to use floorcloths as a medium of expression. Most modern floorcloths are made of heavy, unstretched canvas with two or more coats of gesso. They are then painted and varnished to make them waterproof.

<span class="mw-page-title-main">Perilla oil</span> Vegetable oil derived from perilla seeds

Perilla oil is an edible vegetable oil derived from perilla seeds. Having a distinct nutty aroma and taste, the oil pressed from the toasted perilla seeds is used as a flavor enhancer, condiment, and cooking oil in Korean cuisine. The oil pressed from untoasted perilla seeds is used for non-culinary purposes.

<span class="mw-page-title-main">Frederick Walton</span>

Frederick Edward Walton, was an English manufacturer and inventor whose invention of Linoleum in Chiswick was patented in 1863. He also invented Lincrusta in 1877.

<span class="mw-page-title-main">History of Kirkcaldy</span>

Kirkcaldy is a former royal burgh and town. Known as one of Scotland's "most ancient burghs", the area surrounding the modern town has a history dating as far back as between 2500 BC and 500 BC as a possible funerary landscape.

<span class="mw-page-title-main">Sustainable flooring</span>

Sustainable flooring is produced from sustainable materials that reduces demands on ecosystems during its life-cycle. This includes harvest, production, use and disposal. It is thought that sustainable flooring creates safer and healthier buildings and guarantees a future for traditional producers of renewable resources that many communities depend on. Several initiatives have led the charge to bring awareness of sustainable flooring as well as healthy buildings. Below are examples of available, though sometimes less well-known, eco-friendly flooring options. The Asthma and Allergy Foundation of America recommends those with allergies to dust or other particulates choose flooring with smooth surfaces – such as hardwood, vinyl, linoleum tile or slate.

<span class="mw-page-title-main">Tung oil</span> Chemical compound

Tung oil or China wood oil is a drying oil obtained by pressing the seed from the nut of the tung tree. Tung oil hardens upon exposure to air, and the resulting coating is transparent and has a deep, almost wet look. Used mostly for finishing and protecting wood, after numerous coats, the finish can even look plastic-like. Related drying oils include linseed, safflower, poppy, and soybean oils. Raw tung oil tends to dry to a fine, wrinkled finish ; this property was used to make wrinkle finishes, usually by adding excess cobalt drier. To prevent wrinkling, the oil is heated to gas-proof it.

A finishing oil is a vegetable oil used for wood finishing.

<span class="mw-page-title-main">Oilcloth</span> Type of cloth with a waterproof coating

Oilcloth, also known as enameled cloth or American cloth, is close-woven cotton duck or linen cloth with a coating of boiled linseed oil to make it waterproof.

<span class="mw-page-title-main">Sheet vinyl flooring</span> Type of vinyl flooring

Sheet vinyl flooring is vinyl flooring that comes in large, continuous, flexible sheets. A vinyl sheet floor is completely impermeable to water, unlike vinyl floor tile, which comes in stiff tiles, and vinyl planks, which come in interlocking strips. It is sometimes called linoleum after a visually similar product of different chemical composition.

References

  1. 1 2 Heisterberg‐Moutsis, Gudrun; Heinz, Rainer; Wolf, Thomas F.; Harper, Dominic J.; James, David; Mazzur, Richard P.; Kettler, Volker; Soiné, Hansgert (2001). "Floor Coverings". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a11_263. ISBN   9783527303854.
  2. Ulrich Poth (2002). "Drying Oils and Related Products". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a09_055. ISBN   978-3527306732.
  3. Jones, M.W. (21 Nov 1918). The history and manufacture of floorcloth and linoleum. Society of Chemical Industry.
  4. "F. BRIDGE, STOPPER FOR BOTTLEs, &C., No. 418,549. Patented Dec. 31, 1889" (PDF). Patentimages.storage.googleapis.com. Retrieved 2022-07-24.
  5. 1 2 Powell and Svendsen, p. 23
  6. "Has linoleum become a generic trademark?". genericides.org. Retrieved February 17, 2021.
  7. Fofana, Bourlaye; Ragupathy, Raja; Cloutier, Sylvie (2010). "Flax Lipids: Classes, Biosynthesis, Genetics and the Promise of Applied Genomics for Understanding and Altering of Fatty Acids". In Gilmore, Paige L. (ed.). Lipids. pp. 71–98.

Sources