Salammoniac

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Salammoniac
Salammoniac-456369.jpg
Salammoniac crystals from a mine in Eisden, Maasmechelen, Limburg, Belgium (field of vision: 1.5 cm)
General
Category Halide mineral
Formula
(repeating unit)
NH4Cl
IMA symbol Sam [1]
Strunz classification 3.AA.25
Crystal system Isometric
Crystal class Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group Pm3m
Unit cell a = 3.859 Å; Z = 1
Identification
Formula mass 53.49 g/mol
ColorColorless, white, pale gray; may be pale yellow to brown, if impure.
Crystal habit Crystals skeletal or dendritic; massive, encrustations
Twinning On {111}
Cleavage Imperfect on {111}
Fracture Conchoidal
Tenacity Sectile
Mohs scale hardness1–2
Luster Vitreous
Streak White
Diaphaneity Transparent
Specific gravity 1.535
Optical properties Isotropic
Refractive index n = 1.639
Birefringence Weak after deformation
Ultraviolet fluorescence No
Absorption spectra No
Solubility In water
References [2] [3] [4]
Salammoniac crystal from Ravat Village, Tajikistan. One of many unusual salammoniac crystal specimens found in the area of Ravat Village, near Yaghnob River, where the crystals have grown in a feather-like or three-dimensional arborescent. Size: miniature, 3.3 x 1.4 x 1.4 cm Salammoniac-4jg11a.jpg
Salammoniac crystal from Ravat Village, Tajikistan. One of many unusual salammoniac crystal specimens found in the area of Ravat Village, near Yaghnob River, where the crystals have grown in a feather-like or three-dimensional arborescent. Size: miniature, 3.3 × 1.4 × 1.4 cm

Salammoniac, [2] also salammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH4Cl. It forms colorless, white, or yellow-brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and is brittle to conchoidal fracture. It is quite soft, with a Mohs hardness of 1.5 to 2, and it has a low specific gravity of 1.5. It is water-soluble. Salammoniac is also the archaic name for the chemical compound ammonium chloride.

Contents

History

Pliny, in Book XXXI of his Natural History , refers to a salt produced in the Roman province of Cyrenaica named hammoniacum, so called because of its proximity to the nearby Temple of Jupiter Amun (Greek Ἄμμων Ammon). [5] [6] However, the description Pliny gives of the salt does not conform to the properties of ammonium chloride. According to Herbert Hoover's commentary in his English translation of Georgius Agricola's De re metallica , it is likely to have been common sea salt. [7] In any case, that salt ultimately gave ammonia and ammonium compounds their name.

The first attested reference to sal ammoniac as ammonium chloride is in the Pseudo-Geber work De inventione veritatis, where a preparation of sal ammoniac is given in the chapter De Salis armoniaci præparatione, salis armoniaci being a common name in the Middle Ages for sal ammoniac. [8]

It typically forms as encrustations formed by sublimation around volcanic vents and is found around volcanic fumaroles, guano deposits and burning coal seams. Associated minerals include sodium alum, native sulfur and other fumarole minerals. Notable occurrences include Tajikistan; Mount Vesuvius, Italy; and Parícutin, Michoacan, Mexico.

Uses

It is commonly used to clean the soldering iron in the soldering of stained-glass windows.

Metal refining

In jewellery-making and the refining of precious metals, potassium carbonate is added to gold and silver in a borax-coated crucible to purify iron or steel filings that may have contaminated the scrap. It is then air-cooled and remelted with a one-to-one mixture of powdered charcoal and sal ammoniac to yield a sturdy ingot of the respective metal or alloy in the case of sterling silver (7.5% copper) or karated gold.

Food

Salammoniac has also been used in the past in bakery products to give cookies or biscuits their crisp texture,[ citation needed ] but the application of food grade baking ammonia (ammonium carbonate or (NH4)2CO3) is generally being substituted with the creation of modern baking powder or baking soda (sodium bicarbonate).

Salammoniac is used in salmiac liquorice, for instance salty liquorice or salmiak pastilles.

Dyeing

In addition, the mineral or, better, its synthetic counterpart, also serves for the production of cooling baths as well as in dyeing and leather tanning. [9]

Salammoniac (as ammonium chloride) was the electrolyte in Leclanché cells, a forerunner of the dry battery; a carbon rod and a zinc rod or cylinder formed the electrodes.

Medicine

It was also brought into pharmacopeias by Islamic physicians for medicinal purposes. [10]

Related Research Articles

<span class="mw-page-title-main">Ammonia</span> Chemical compound

Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the formula NH3. A stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pungent smell. Biologically, it is a common nitrogenous waste, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to fertilisers. Around 70% of ammonia produced industrially is used to make fertilisers in various forms and composition, such as urea and diammonium phosphate. Ammonia in pure form is also applied directly into the soil.

<span class="mw-page-title-main">Georgius Agricola</span> German scholar, mineralogist and metallurgist (1494–1555)

Georgius Agricola was a German Humanist scholar, mineralogist and metallurgist. Born in the small town of Glauchau, in the Electorate of Saxony of the Holy Roman Empire, he was broadly educated, but took a particular interest in the mining and refining of metals. He was the first to drop the Arabic definite article al-, exclusively writing chymia and chymista in describing activity that we today would characterize as chemical or alchemical, giving chemistry its modern name. For his groundbreaking work De Natura Fossilium published in 1546, he is generally referred to as the Father of Mineralogy and the founder of geology as a scientific discipline.

<span class="mw-page-title-main">Kainite</span>

Kainite ( or ) (KMg(SO4)Cl·3H2O) is an evaporite mineral in the class of "Sulfates (selenates, etc.) with additional anions, with H2O" according to the Nickel–Strunz classification. It is a hydrated potassium-magnesium sulfate-chloride, naturally occurring in irregular granular masses or as crystalline coatings in cavities or fissures. This mineral is dull and soft, and is colored white, yellowish, grey, reddish, or blue to violet. Its name is derived from Greek καινος [kainos] ("(hitherto) unknown"), as it was the first mineral discovered that contained both sulfate and chloride as anions. Kainite forms monoclinic crystals.

<span class="mw-page-title-main">Ammonium</span> Chemical compound

The ammonium cation is a positively charged polyatomic ion with the chemical formula NH+4 or [NH4]+. It is formed by the protonation of ammonia. Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations, where one or more hydrogen atoms are replaced by organic or other groups.

<span class="mw-page-title-main">Natron</span> Carbonate mineral

Natron is a naturally occurring mixture of sodium carbonate decahydrate (Na2CO3·10H2O, a kind of soda ash) and around 17% sodium bicarbonate (also called baking soda, NaHCO3) along with small quantities of sodium chloride and sodium sulfate. Natron is white to colourless when pure, varying to gray or yellow with impurities. Natron deposits are sometimes found in saline lake beds which arose in arid environments. Throughout history natron has had many practical applications that continue today in the wide range of modern uses of its constituent mineral components.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

The compound hydrogen chloride has the chemical formula HCl and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry. Hydrochloric acid, the aqueous solution of hydrogen chloride, is also commonly given the formula HCl.

<span class="mw-page-title-main">Ammonium chloride</span> Chemical compound

Ammonium chloride is an inorganic chemical compound with the chemical formula NH4Cl, also written as [NH4]Cl. It is an ammonium salt of hydrogen chloride. It consists of ammonium cations [NH4]+ and chloride anions Cl. It is a white crystalline salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. In its naturally occurring mineralogic form, it is known as salammoniac. The mineral is commonly formed on burning coal dumps from condensation of coal-derived gases. It is also found around some types of volcanic vents. It is mainly used as fertilizer and a flavouring agent in some types of liquorice. It is a product of the reaction of hydrochloric acid and ammonia.

The Solvay process or ammonia–soda process is the major industrial process for the production of sodium carbonate (soda ash, Na2CO3). The ammonia–soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. The ingredients for this are readily available and inexpensive: salt brine (from inland sources or from the sea) and limestone (from quarries). The worldwide production of soda ash in 2005 was estimated at 42 million tonnes, which is more than six kilograms (13 lb) per year for each person on Earth. Solvay-based chemical plants now produce roughly three-quarters of this supply, with the remaining being mined from natural deposits. This method superseded the Leblanc process.

<span class="mw-page-title-main">Smelling salts</span> Ammonium carbonate used in the past to restore consciousness after fainting

Smelling salts, also known as ammonia inhalants, spirit of hartshorn or sal volatile, are chemical compounds used as stimulants to restore consciousness after fainting.

<span class="mw-page-title-main">Ammonium carbonate</span> Chemical used as leavening agent and smelling salt

Ammonium carbonate is a salt with the chemical formula (NH4)2CO3. Since it readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is a predecessor to the more modern leavening agents baking soda and baking powder. It is a component of what was formerly known as sal volatile and salt of hartshorn, and produces a pungent smell when baked. It comes in the form of a white powder or block, with a molar mass of 96.09 g/mol and a density of 1.50 g/cm3. It is a strong electrolyte.

Classical qualitative inorganic analysis is a method of analytical chemistry which seeks to find the elemental composition of inorganic compounds. It is mainly focused on detecting ions in an aqueous solution, therefore materials in other forms may need to be brought to this state before using standard methods. The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes.

<span class="mw-page-title-main">Salty liquorice</span> Variety of liquorice

Salty liquorice, salmiak liquorice or salmiac liquorice, is a variety of liquorice flavoured with salmiak salt, and is a common confection found in the Nordic countries, Benelux, and northern Germany. Salmiak salt gives salty liquorice an astringent, salty taste, akin to that of tannins—a characteristic of red wines, which adds bitterness and astringency to the flavour. Consuming salmiak liquorice can stimulate either a savoury or non-savoury palate and response. Anise oil can also be an additional main ingredient in salty liquorice. Extra-salty liquorice is additionally coated with salmiak salt or salmiak powder, or sometimes table salt.

<span class="mw-page-title-main">Hexafluorosilicic acid</span> Octahedric silicon compound

Hexafluorosilicic acid is an inorganic compound with the chemical formula H
2
SiF
6
. Aqueous solutions of hexafluorosilicic acid consist of salts of the cation and hexafluorosilicate anion. These salts and their aqueous solutions are colorless.

<i>De re metallica</i> 1556 book on mining and metallurgy by Georgius Agricola

De re metallica is a book in Latin cataloguing the state of the art of mining, refining, and smelting metals, published a year posthumously in 1556 due to a delay in preparing woodcuts for the text. The author was Georg Bauer, whose pen name was the Latinized Georgius Agricola. The book remained the authoritative text on mining for 180 years after its publication. It was also an important chemistry text for the period and is significant in the history of chemistry.

<span class="mw-page-title-main">Hydrochloric acid</span> Aqueous solution of hydrogen chloride

Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid. It is a component of the gastric acid in the digestive systems of most animal species, including humans. Hydrochloric acid is an important laboratory reagent and industrial chemical.

<span class="mw-page-title-main">Bararite</span> Halide mineral

Bararite is a natural form of ammonium fluorosilicate (also known as hexafluorosilicate or fluosilicate). It has chemical formula (NH4)2SiF6 and trigonal crystal structure. This mineral was once classified as part of cryptohalite. Bararite is named after the place where it was first described, Barari, India. It is found at the fumaroles of volcanoes (Vesuvius, Italy), over burning coal seams (Barari, India), and in burning piles of anthracite (Pennsylvania, U.S.). It is a sublimation product that forms with cryptohalite, sal ammoniac, and native sulfur.

Gold parting is the separating of gold from silver. Gold and silver are often extracted from the same ores and are chemically similar and therefore difficult to separate. The alloy of gold and silver is called electrum.

Calcium nitrite is an inorganic compound with the chemical formula Ca(NO
2
)
2
. In this compound, as in all nitrites, nitrogen is in a +3 oxidation state. It has many applications such as antifreeze, rust inhibitor of steel and wash heavy oil.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 "Salammoniac". mindat.org and the Hudson Institute of Mineralogy.
  3. "Redirect for Sal-ammoniac". webmineral.com.
  4. "Handbook of Mineralogy" (PDF).
  5. "Pliny the Elder, The Natural History, Book XXXI, Chapter 39. (7.) - The various kinds of salt; the methods of preparing it, and the remedies derived from it".
  6. Stapleton, H. E. (1905). "Sal-Ammoniac: A Study in Primitive Chemistry". Memoirs of the Asiatic Society of Bengal. 1 (4): 25--42, i--iii via Archive.org.
  7. Hoover, Herbert (1950). Georgius Agricola De Re Metallica - Translated from the first Latin edition of 1556. New York: Dover Publications. p. 560. ISBN   978-0486600062.
  8. "Geberis philosophi perspicacissimi, summa perfectionis magisterii in sua natur ex bibliothecae Vaticanae exemplari". 1542.
  9. "In Salmiak Territory - Opinion - The Harvard Crimson". www.thecrimson.com.
  10. Pormann, Peter E.; Savage-Smith, Emilie (2007). Medieval Islamic Medicine. Washington D.C.: Georgetown University Press. p. 120. ISBN   978-1-58901-161-8.