Sodium dichloroisocyanurate

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Sodium dichloroisocyanurate
Sodium dichloroisocyanurate structure.svg
Names
IUPAC name
Sodium 3,5-dichloro-2,4,6-trioxo-1,3,5-triazinan-1-ide
Other names
Sodium dichloroisocyanurate, Sodium troclosene, Sodic troclosene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.018.880 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
RTECS number
  • XZ1900000
UNII
  • InChI=1S/C3HCl2N3O3.Na/c4-7-1(9)6-2(10)8(5)3(7)11;/h(H,6,9,10);/q;+1/p-1 Yes check.svgY
    Key: MSFGZHUJTJBYFA-UHFFFAOYSA-M Yes check.svgY
  • InChI=1S/C3HCl2N3O3.Na/c4-7-1(9)6-2(10)8(5)3(7)11;/h(H,6,9,10);/q;+1/p-1
    Key: MSFGZHUJTJBYFA-REWHXWOFAV
  • Key: MSFGZHUJTJBYFA-UHFFFAOYSA-M
  • [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O
Properties
C3Cl2N3NaO3
Molar mass 219.95 g/mol (anhydrous)

255.98 g/mol (dihydrate)

Appearancewhite, crystalline powder
Odor chlorine-like
Density 0.7 g/cm3 (as granules)
Melting point 225 °C (437 °F; 498 K)
22.7 g/100 mL (25 °C)
Solubility in acetone 0.5 g/100 mL (30 °C)
Acidity (pKa)6.2-6.8
Hazards
Lethal dose or concentration (LD, LC):
(Rat oral) 1670 mg/kg
Related compounds
Other cations
Potassium dichloroisocyanurate
Calcium dichloroisocyanurate
Lithium dichloroisocyanurate
Barium dichloroisocyanurate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sodium dichloroisocyanurate (INN: sodium troclosene, troclosenum natricum or NaDCC or SDIC) is a chemical compound widely used as a cleansing agent and disinfectant. [1] It is a colorless, water-soluble solid, produced as a result of reaction of cyanuric acid with chlorine. The dihydrate is also known (51580-86-0 ) as is the potassium salt (2244-21-5 ).

Contents

Uses

It is mainly used as a disinfectant, biocide and industrial deodorant. It is found in some modern water purification tablets/filters. It is more efficient than the formerly used halazone water disinfectant. In these applications, it is a slow-release source of chlorine in low concentrations at a relatively constant rate. As a disinfectant, it is used to sterilize drinking water, swimming pools, tableware and air, and to fight against infectious diseases as a routine disinfection agent.

It can be used for disinfection and environmental sterilization, for example in livestock, poultry, fish and silkworm raising, for bleaching textiles, for cleaning industrial circulating water, and to prevent wool from shrinking.

The reaction between NaDCC and a dilute solution of copper (II) sulfate produces an intense lilac precipitate of the complex salt sodium copper dichloroisocyanurate. The reactions between dichloroisocyanurate salts (Na, K, Li, Ba, Ca) and transition metal salts (Ni, Cu, Cd) are described in patent US 3,055,889. The overall reaction is:

CuSO4 + 4 Na(C3N3O3Cl2) → Na2[Cu(C3N3O3Cl2)4] + Na2SO4

Sodium dichloroisocyanurate reacts with concentrated (130 vol, 35%) hydrogen peroxide to create singlet oxygen which emits red light upon decomposition . [2]

It is considered hazardous according to OSHA 29 CFR 1910.1200. High level exposure can cause reactive airways dysfunction syndrome (RADS) [3]

See also

Related Research Articles

<span class="mw-page-title-main">Chlorine</span> Chemical element, symbol Cl and atomic number 17

Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Pauling scale, behind only oxygen and fluorine.

<span class="mw-page-title-main">Sodium chloride</span> Chemical compound with formula NaCl

Sodium chloride, commonly known as table salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. Sodium chloride is the salt most responsible for the salinity of seawater and of the extracellular fluid of many multicellular organisms. In its edible form, salt is commonly used as a condiment and food preservative. Large quantities of sodium chloride are used in many industrial processes, and it is a major source of sodium and chlorine compounds used as feedstocks for further chemical syntheses. Another major application of sodium chloride is deicing of roadways in sub-freezing weather.

The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of ClO
2
. A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous acid.

<span class="mw-page-title-main">Sodium hypochlorite</span> Chemical compound (known in solution as bleach)

Sodium hypochlorite, commonly known in a dilute solution as (chlorine) bleach, is an inorganic chemical compound with the formula NaOCl, consisting of a sodium cation and a hypochlorite anion. It may also be viewed as the sodium salt of hypochlorous acid. The anhydrous compound is unstable and may decompose explosively. It can be crystallized as a pentahydrate NaOCl·5H
2
O
, a pale greenish-yellow solid which is not explosive and is stable if kept refrigerated.

<span class="mw-page-title-main">Water purification</span> Process of removing impurities from water

Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for human consumption, but water purification may also be carried out for a variety of other purposes, including medical, pharmacological, chemical, and industrial applications. The history of water purification includes a wide variety of methods. The methods used include physical processes such as filtration, sedimentation, and distillation; biological processes such as slow sand filters or biologically active carbon; chemical processes such as flocculation and chlorination; and the use of electromagnetic radiation such as ultraviolet light.

<span class="mw-page-title-main">Chlorine dioxide</span> Chemical compound

Chlorine dioxide is a chemical compound with the formula ClO2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is usually handled as an aqueous solution. It is commonly used as a bleach. More recent developments have extended its applications in food processing and as a disinfectant.

<span class="mw-page-title-main">Disinfectant</span> Antimicrobial agent that inactivates or destroys microbes

A disinfectant is a chemical substance or compound used to inactivate or destroy microorganisms on inert surfaces. Disinfection does not necessarily kill all microorganisms, especially resistant bacterial spores; it is less effective than sterilization, which is an extreme physical or chemical process that kills all types of life. Disinfectants are generally distinguished from other antimicrobial agents such as antibiotics, which destroy microorganisms within the body, and antiseptics, which destroy microorganisms on living tissue. Disinfectants are also different from biocides—the latter are intended to destroy all forms of life, not just microorganisms. Disinfectants work by destroying the cell wall of microbes or interfering with their metabolism. It is also a form of decontamination, and can be defined as the process whereby physical or chemical methods are used to reduce the amount of pathogenic microorganisms on a surface.

<span class="mw-page-title-main">Hypochlorous acid</span> Chemical compound

Hypochlorous acid is a weak acid that forms when chlorine dissolves in water, and itself partially dissociates, forming hypochlorite, ClO. HClO and ClO are oxidizers, and the primary disinfection agents of chlorine solutions. HClO cannot be isolated from these solutions due to rapid equilibration with its precursor, chlorine.

<span class="mw-page-title-main">Hypochlorite</span> Ion

In chemistry, hypochlorite, or chloroxide is an anion with the chemical formula ClO. It combines with a number of cations to form hypochlorite salts. Common examples include sodium hypochlorite and calcium hypochlorite. The Cl-O distance in ClO is 1.69 Å.

<span class="mw-page-title-main">Cyanuric acid</span> Chemical compound belonging to the class of triazine

Cyanuric acid or 1,3,5-triazine-2,4,6-triol is a chemical compound with the formula (CNOH)3. Like many industrially useful chemicals, this triazine has many synonyms. This white, odorless solid finds use as a precursor or a component of bleaches, disinfectants, and herbicides. In 1997, worldwide production was 160 000 tonnes.

<span class="mw-page-title-main">Sodium chlorite</span> Chemical compound

Sodium chlorite (NaClO2) is a chemical compound used in the manufacturing of paper and as a disinfectant.

<span class="mw-page-title-main">Trichloroisocyanuric acid</span> Chemical compound

Trichloroisocyanuric acid is an organic compound with the formula (C3Cl3N3O3). It is used as an industrial disinfectant, bleaching agent and a reagent in organic synthesis. This white crystalline powder, which has a strong "chlorine odour," is sometimes sold in tablet or granule form for domestic and industrial use.

<span class="mw-page-title-main">Portable water purification</span> Self-contained, easily transported units used to purify water from untreated sources

Portable water purification devices are self-contained, easily transported units used to purify water from untreated sources for drinking purposes. Their main function is to eliminate pathogens, and often also of suspended solids and some unpalatable or toxic compounds.

<span class="mw-page-title-main">Electrolysed water</span> Chemical mixture in water solution

Electrolysed water is produced by the electrolysis of ordinary tap water containing dissolved sodium chloride. The electrolysis of such salt solutions produces a solution of hypochlorous acid and sodium hydroxide. The resulting water can be used as a disinfectant.

<span class="mw-page-title-main">Dichloroisocyanuric acid</span> Chemical compound

Dichloroisocyanuric acid, also known as dichlor or dichloro-s-triazinetrione and is marketed under many names (e.g. troclosene), is a chemical compound with the formula (C(O)NCl)2(C(O)NH).

<span class="mw-page-title-main">Bleach</span> Chemicals used to whiten or disinfect

Bleach is the generic name for any chemical product that is used industrially or domestically to remove colour (whitening) from fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".

<span class="mw-page-title-main">Water chlorination</span> Chorination of water

Water chlorination is the process of adding chlorine or chlorine compounds such as sodium hypochlorite to water. This method is used to kill bacteria, viruses and other microbes in water. In particular, chlorination is used to prevent the spread of waterborne diseases such as cholera, dysentery, and typhoid.

Potassium hypochlorite is the potassium salt of hypochlorous acid. It is used in variable concentrations, often diluted in water solution. It has a light grey color and a strong chlorine smell. It can be used as a disinfectant.

Mixed oxidant solution is a type of disinfectant which is used for disinfecting, sterilization and eliminating pathogenic microorganisms in water and in many other applications. Using a mixed oxidant solution for water disinfection, compared to other methods, may have various benefits such as higher disinfecting power, stable residual chlorine in water, improved taste and smell, elimination of biofilm, and safety. A mixed-oxidant solution is produced by electrolysis of sodium chloride and is a mixture of disinfecting compounds. The main component of this product is chlorine and its derivatives (ClO, HClO and Cl2 solution). It may also contain high amounts of chlorine dioxide solution, dissolved ozone, hydrogen peroxide, and oxygen, from which the name "mixed oxidant" is derived.

<span class="mw-page-title-main">Chlorine-releasing compounds</span>

Chlorine-releasing compounds, also known as chlorine base compounds, is jargon to describe certain chlorine-containing substances that are used as disinfectants and bleaches. They include the following chemicals: sodium hypochlorite, chloramine, halazone, and sodium dichloroisocyanurate. They are widely used to disinfect water and medical equipment, and surface areas as well as bleaching materials such as cloth. The presence of organic matter can make them less effective as disinfectants. They come as a liquid solution, or as a powder that is mixed with water before use.

References

  1. Huthmacher, Klaus; Most, Dieter (2000). "Cyanuric Acid and Cyanuric Chloride". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a08_191. ISBN   3-527-30673-0..
  2. [Acc. Chem. Res. 2006, 39, 11, 797–804]
  3. "Sodium dichloroisocyanurate - Material Safety Data Sheet" (PDF). September 30, 2009.