Spurrite

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Spurrite
Spurrite Calcium silicate and carbonate Luna county New mexico 1873.jpg
Spurrite from New Mexico
General
Category Nesosilicate
Formula
(repeating unit)
Ca5(SiO4)2CO3
IMA symbol Spu [1]
Strunz classification 9.AH.15
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/a
Identification
ColorGray, gray white to lilac gray
Crystal habit Massive to granular
Twinning Polysynthetic twins on [001] and [101]
Cleavage Distinct on [100]
Fracture Uneven to splintery
Mohs scale hardness5
Luster vitreous to resinous
Streak White
Diaphaneity Transparent to translucent
Specific gravity 3
Optical propertiesBiaxial (−)
Refractive index nα = 1.640–1.641 nβ = 1.674–1.676 nγ = 1.679–1.681
Birefringence δ = 0.039–0.040
Other characteristicsGreen cathodoluminescence
References [2] [3] [4]

Spurrite is a white, yellow or light blue mineral with monoclinic crystals. Its chemical formula is Ca 5(Si O 4)2 CO3. [5]

Contents

Spurrite is generally formed in contact metamorphism zones as mafic magmas are intruded into carbonate rocks. [6] Spurrite's space group is P 2/a. It is biaxial with a birefringence of 0.0390–0.0400, giving second order red interference colors when viewed under crossed polarizers in a petrographic microscope. [7]

The calcium is in six-fold coordination with the oxygen, the silicon is in a four-fold coordination with the oxygen and the carbon is in two-fold coordination. One unique characteristic of spurrite is that it actually abides by two twin laws. Polysynthetic twinning can occur along its (001) and another type of twinning can occur parallel to its optical axes. [6]

Discovery and occurrence

Spurrite was first described in 1908 for an occurrence in the Terneras Mine, Velardeña District, Durango, Mexico. It was named for American economic geologist Josiah Edward Spurr (1870–1950). [3]

In addition to its type locality, spurrite has been reported from Riverside County, California; Luna County, New Mexico; and from the Little Belt Mountains, Lewis and Clark County, Montana. It is also found in Ireland, Scotland, New Zealand, Turkey, Israel, Japan and Siberia. [2]

Cement manufacture contaminant

Spurrite forms as contaminating spurrite rings on the walls of cement kilns during the production of Portland cement. [8]

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Sekaninaite</span> Mg, Fe, Al cyclosilicate mineral

Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.

<span class="mw-page-title-main">Zoisite</span> Sorosilicate mineral

Zoisite, first known as saualpite, after its type locality, is a calcium aluminum hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2Al3(SiO4)(Si2O7)O(OH).

<span class="mw-page-title-main">Staurolite</span> Reddish brown to black nesosilicate mineral

Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc and manganese substitute in the iron site and trivalent iron can substitute for aluminium.

<span class="mw-page-title-main">Forsterite</span> Magnesium end-member of olivine, a nesosilicate mineral

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

<span class="mw-page-title-main">Adamite</span> Zinc arsenate hydroxide mineral

Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.

<span class="mw-page-title-main">Esperite</span>

Esperite is a rare complex calcium lead zinc silicate (PbCa3Zn4(SiO4)4) related to beryllonite and trimerite that used to be called calcium larsenite. It was named in honor of Esper F. Larsen Jr. (1879–1961), petrologist of Harvard University.

<span class="mw-page-title-main">Hardystonite</span>

Hardystonite is a rare calcium zinc silicate mineral first described from the Franklin, New Jersey, U.S. zinc deposits. It often contains lead, which was detrimental to the zinc smelting process, so it was not a useful ore mineral. Like many of the famous Franklin minerals, hardystonite responds to short wave ultraviolet light, emitting a fluorescence from dark purple to bright violet blue. In daylight, it is white to gray to light pink in color, sometimes with a vitreous or greasy luster. It is very rarely found as well formed crystals, and these are usually rectangular in appearance and rock-locked.

<span class="mw-page-title-main">Afwillite</span> Nesosilicate alteration mineral also sometimes found in hydrated cement paste

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.

<span class="mw-page-title-main">Brownmillerite</span> Rare calcium aluminium oxide mineral

Brownmillerite is a rare oxide mineral with chemical formula Ca2(Al,Fe)2O5. It is named for Lorrin Thomas Brownmiller (1902–1990), chief chemist of the Alpha Portland Cement Company, Easton, Pennsylvania.

<span class="mw-page-title-main">Portlandite</span> Calcium hydroxide mineral

Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

<span class="mw-page-title-main">Thaumasite</span> Complex calcium silicate hydrate mineral

Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3Si(OH)6(CO3)(SO4)·12H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O.

<span class="mw-page-title-main">Majorite</span> Garnet mineral

Majorite is a type of garnet mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is distinguished from other garnets in having Si in octahedral as well as tetrahedral coordination. Majorite was first described in 1970 from the Coorara Meteorite of Western Australia and has been reported from various other meteorites in which majorite is thought to result from an extraterrestrial high pressure shock event. Mantle derived xenoliths containing majorite have been reported from potassic ultramafic magmas on Malaita Island on the Ontong Java Plateau Southwest Pacific.

<span class="mw-page-title-main">Pabstite</span>

Pabstite is a barium tin titanium silicate mineral that is found in contact metamorphosed limestone. It belongs to the benitoite group of minerals. The chemical formula of pabstite is Ba(Sn,Ti)Si3O9. It is found in Santa Cruz, California. The crystal system of the mineral is hexagonal.

<span class="mw-page-title-main">Hafnon</span>

Hafnon is a hafnium nesosilicate mineral, chemical formula (Hf,Zr)SiO4 or (Hf,Zr,Th,U,Y)SiO4. In natural zircon ZrSiO4 part of the zirconium is replaced by the very similar hafnium and so natural zircon is never pure ZrSiO4. A zircon with 100% hafnium substitution can be made synthetically and is hafnon.

<span class="mw-page-title-main">Hodgkinsonite</span>

Hodgkinsonite is a rare zinc manganese silicate mineral Zn2MnSiO4(OH)2. It crystallizes in the monoclinic system and typically forms radiating to acicular prismatic crystals with variable color from pink, yellow-red to deep red. Hodgkinsonite was discovered in 1913 by H. H. Hodgkinson, for whom it is named in Franklin, New Jersey, and it is only found in that area.

<span class="mw-page-title-main">Danalite</span> Iron beryllium silicate sulfide mineral

Danalite is an iron beryllium silicate sulfide mineral with formula: Fe2+4Be3(SiO4)3S.

<span class="mw-page-title-main">Warikahnite</span> Rare zinc arsenate mineral

Warikahnite is a rare zinc arsenate mineral of the triclinic crystal system with Hermann- Mauguin notation 1, belonging to the space group P1. It occurs in the Tsumeb mine in Namibia on corroded tennantite in the second oxidation zone under hydrothermal conditions in a dolomite-hosted polymetallic ore deposit. It is associated with adamite, stranskiite, koritnigite, claudetite, tsumcorite, and ludlockite. The origin of discovery was in a dolomite ore formation within an oxidized hydrothermal zone, in the E9 pillar, 31st level of the Tsumeb Mine in Namibia, Southwest Africa. It has also been found at Lavrion, Greece and Plaka, Greece as microscopic white needles.

Metarauchite is a member of the autunite group, found at the Jáchymov ore district, Czech Republic and in Schneeberg, Germany. The autunite group is a group of structured uranyl phosphates and arsenates; the other members of the group are autunite, bassetite, heinrichite, kahlerite, nováčekite-I, nováčekite-II, rauchite, sabugalite, saléeite, torbernite, uranocircite, uranospinite, and zeunerite. The mineral is named after Czech mineral collector Luděk Rauch, who died in the Jáchymov mines during mineral prospecting.

<span class="mw-page-title-main">Johnbaumite</span>

Johnbaumite is a calcium arsenate hydroxide mineral. It was first described in 1980, where it appeared in Franklin Township, Somerset County, New Jersey. Johnbaumite was discovered at Harstigen mine in Sweden in the 19th century, but it was described as svabite.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 http://rruff.geo.arizona.edu/doclib/hom/spurrite.pdf Mineral Handbook
  3. 1 2 http://www.mindat.org/min-3734.html Mindat
  4. http://webmineral.com/data/Spurrite.shtml Webmineral data
  5. Richard V. Gaines, H. Catherine W. Skinner, Eugene E. Foord, Brian Mason, and Abraham Rosenzweig: Dana's new mineralogy, p. 1106. John Wiley & Sons, 1997
  6. 1 2 Smith, J.V. (1960) "The Crystal structure of Spurrite, Ca5(SiO4)2CO3". Acta. Cryst. 13, 454
  7. Barthemy, D. (2000) Afwillite Mineral Data, (http://webmineral.com/data/Afwillite.shtml)
  8. Mosci, Ricardo, 1998, How To Eliminate Calcining Zone Rings, Cement America http://cementamericas.com/mag/cement_eliminate_calcining_zone/