A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals, are coordination complexes.
In geometry, the gyroelongated square bipyramid is a polyhedron with 16 triangular faces. it can be constructed from a square antiprism by attaching two equilateral square pyramids to each of its square faces. The same shape is also called heccaidecadeltahedron, or tetrakis square antiprism; these last names mean a polyhedron with 16 triangular faces. It is an example of deltahedron, and of a Johnson solid.
The triaugmented triangular prism, in geometry, is a convex polyhedron with 14 equilateral triangles as its faces. It can be constructed from a triangular prism by attaching equilateral square pyramids to each of its three square faces. The same shape is also called the tetrakis triangular prism, tricapped trigonal prism, tetracaidecadeltahedron, or tetrakaidecadeltahedron; these last names mean a polyhedron with 14 triangular faces. It is an example of a deltahedron and of a Johnson solid.
Valence shell electron pair repulsion (VSEPR) theory is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. It is also named the Gillespie-Nyholm theory after its two main developers, Ronald Gillespie and Ronald Nyholm.
In geometry, the gyroelongated square pyramid is the Johnson solid that can be constructed by attaching an equilateral square pyramid to a square antiprism. It occurs in the chemistry such as square antiprismatic molecular geometry.
In chemistry, a trigonal pyramid is a molecular geometry with one atom at the apex and three atoms at the corners of a trigonal base, resembling a tetrahedron (not to be confused with the tetrahedral geometry). When all three atoms at the corners are identical, the molecule belongs to point group C3v. Some molecules and ions with trigonal pyramidal geometry are the pnictogen hydrides (XH3), xenon trioxide (XeO3), the chlorate ion, ClO−
3, and the sulfite ion, SO2−
3. In organic chemistry, molecules which have a trigonal pyramidal geometry are sometimes described as sp3 hybridized. The AXE method for VSEPR theory states that the classification is AX3E1.
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The octahedron has eight faces, hence the prefix octa. The octahedron is one of the Platonic solids, although octahedral molecules typically have an atom in their centre and no bonds between the ligand atoms. A perfect octahedron belongs to the point group Oh. Examples of octahedral compounds are sulfur hexafluoride SF6 and molybdenum hexacarbonyl Mo(CO)6. The term "octahedral" is used somewhat loosely by chemists, focusing on the geometry of the bonds to the central atom and not considering differences among the ligands themselves. For example, [Co(NH3)6]3+, which is not octahedral in the mathematical sense due to the orientation of the N−H bonds, is referred to as octahedral.
In geometry, the square antiprism is the second in an infinite family of antiprisms formed by an even-numbered sequence of triangle sides closed by two polygon caps. It is also known as an anticube.
In geometry, a near-miss Johnson solid is a strictly convex polyhedron whose faces are close to being regular polygons but some or all of which are not precisely regular. Thus, it fails to meet the definition of a Johnson solid, a polyhedron whose faces are all regular, though it "can often be physically constructed without noticing the discrepancy" between its regular and irregular faces. The precise number of near-misses depends on how closely the faces of such a polyhedron are required to approximate regular polygons.
In geometry, the gyroelongated bipyramids are an infinite set of polyhedra, constructed by elongating an n-gonal bipyramid by inserting an n-gonal antiprism between its congruent halves.
In 4-dimensional geometry, a uniform antiprismatic prism or antiduoprism is a uniform 4-polytope with two uniform antiprism cells in two parallel 3-space hyperplanes, connected by uniform prisms cells between pairs of faces. The symmetry of a p-gonal antiprismatic prism is [2p,2+,2], order 8p.
Square pyramidal geometry describes the shape of certain chemical compounds with the formula ML5 where L is a ligand. If the ligand atoms were connected, the resulting shape would be that of a pyramid with a square base. The point group symmetry involved is of type C4v. The geometry is common for certain main group compounds that have a stereochemically-active lone pair, as described by VSEPR theory. Certain compounds crystallize in both the trigonal bipyramidal and the square pyramidal structures, notably [Ni(CN)5]3−.
In chemistry, the square antiprismatic molecular geometry describes the shape of compounds where eight atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a square antiprism. This shape has D4d symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the dodecahedron and the bicapped trigonal prism.
In chemistry, the tricapped trigonal prismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triaugmented triangular prism.
In chemistry, the capped octahedral molecular geometry describes the shape of compounds where seven atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a gyroelongated triangular pyramid. This shape has C3v symmetry and is one of the three common shapes for heptacoordinate transition metal complexes, along with the pentagonal bipyramid and the capped trigonal prism.
In geometry, a diminished trapezohedron is a polyhedron in an infinite set of polyhedra, constructed by removing one of the polar vertices of a trapezohedron and replacing it by a new face (diminishment). It has one regular n-gonal base face, n triangle faces around the base, and n kites meeting on top. The kites can also be replaced by rhombi with specific proportions.
In chemistry, the capped trigonal prismatic molecular geometry describes the shape of compounds where seven atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of an augmented triangular prism. This shape has C2v symmetry and is one of the three common shapes for heptacoordinate transition metal complexes, along with the pentagonal bipyramid and the capped octahedron.
In chemistry, the dodecahedral molecular geometry describes the shape of compounds where eight atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a snub disphenoid. This shape has D2d symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the square antiprism and the bicapped trigonal prism.
In chemistry, the bicapped trigonal prismatic molecular geometry describes the shape of compounds where eight atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a biaugmented triangular prism. This shape has C2v symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the square antiprism and the dodecahedron.
