Lead(II) phosphate

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Lead(II) phosphate
Names
Systematic IUPAC name
Lead(II) phosphate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.028.368 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 231-205-5
PubChem CID
RTECS number
  • OG3675000
UNII
UN number 3288 2291
  • InChI=1S/2H3O4P.3Pb/c2*1-5(2,3)4;;;/h2*(H3,1,2,3,4);;;/q;;3*+2/p-6 X mark.svgN
    Key: HUTDDBSSHVOYJR-UHFFFAOYSA-H X mark.svgN
  • [O-]P(=O)([O-])[O-].[O-]P(=O)([O-])[O-].[Pb+2].[Pb+2].[Pb+2]
Properties
Pb3(PO4)2
Molar mass 811.54272 g/mol
Appearancewhite powder
Density 6.9 g/cm3
Melting point 1,014 °C (1,857 °F; 1,287 K)
0.000014 g/100 mL
Solubility insoluble in alcohol
soluble in nitric acid
182.0·10−6 cm3/mol
2.048
Hazards
GHS labelling: [1]
GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Warning
H360Df, H373, H410
P203, P260, P273, P280, P318, P319, P391, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lead(II) phosphate is an ionic compound with chemical formula Pb 3(P O 4)2. Lead(II) phosphate is a long-lived electronically neutral reagent chemical. [2] Despite limited tests on humans, it has been identified as a carcinogen based on tests on animals conducted by the EPA. [3] Lead(II) phosphate appears as hexagonal, colorless crystals or as a white powder. Lead(II) phosphate is insoluble in water and alcohol but soluble in nitric acid (HNO3) and fused alkali metal hydroxides. When lead(II) phosphate is heated for decomposition it emits very toxic fumes containing Lead (Pb) and POx. [4]

Preparation

It is prepared by reacting lead(II) hydroxide with orthophosphoric acid.

3Pb(OH)2 + 2H3PO4 → Pb3(PO4)2 + 6H2O

Related Research Articles

<span class="mw-page-title-main">Monazite</span> Mineral containing rare-earth elements

Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium-dominant member of the group. It occurs usually in small isolated crystals. It has a hardness of 5.0 to 5.5 on the Mohs scale of mineral hardness and is relatively dense, about 4.6 to 5.7 g/cm3. There are five different most common species of monazite, depending on the relative amounts of the rare earth elements in the mineral:

<span class="mw-page-title-main">Calcium phosphate</span> Chemical compound

The term calcium phosphate refers to a family of materials and minerals containing calcium ions (Ca2+) together with inorganic phosphate anions. Some so-called calcium phosphates contain oxide and hydroxide as well. Calcium phosphates are white solids of nutritional value and are found in many living organisms, e.g., bone mineral and tooth enamel. In milk, it exists in a colloidal form in micelles bound to casein protein with magnesium, zinc, and citrate–collectively referred to as colloidal calcium phosphate (CCP). Various calcium phosphate minerals are used in the production of phosphoric acid and fertilizers. Overuse of certain forms of calcium phosphate can lead to nutrient-containing surface runoff and subsequent adverse effects upon receiving waters such as algal blooms and eutrophication (over-enrichment with nutrients and minerals).

Acid salts are a class of salts that produce an acidic solution after being dissolved in a solvent. Its formation as a substance has a greater electrical conductivity than that of the pure solvent. An acidic solution formed by acid salt is made during partial neutralization of diprotic or polyprotic acids. A half-neutralization occurs due to the remaining of replaceable hydrogen atoms from the partial dissociation of weak acids that have not been reacted with hydroxide ions to create water molecules.

<span class="mw-page-title-main">Triphylite</span>

Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.

Lead(II) hydroxide, Pb(OH)2, is a hydroxide of lead, with lead in oxidation state +2.

<span class="mw-page-title-main">Tricalcium phosphate</span> Chemical compound

Tricalcium phosphate (sometimes abbreviated TCP), more commonly known as Calcium phosphate, is a calcium salt of phosphoric acid with the chemical formula Ca3(PO4)2. It is also known as tribasic calcium phosphate and bone phosphate of lime (BPL). It is a white solid of low solubility. Most commercial samples of "tricalcium phosphate" are in fact hydroxyapatite.

<span class="mw-page-title-main">Monocalcium phosphate</span> Chemical compound

Monocalcium phosphate is an inorganic compound with the chemical formula Ca(H2PO4)2 ("AMCP" or "CMP-A" for anhydrous monocalcium phosphate). It is commonly found as the monohydrate ("MCP" or "MCP-M"), Ca(H2PO4)2·H2O. Both salts are colourless solids. They are used mainly as superphosphate fertilizers and are also popular leavening agents.

<span class="mw-page-title-main">Iron(II) phosphate</span> Chemical compound

Iron(II) phosphate, also ferrous phosphate, Fe3(PO4)2, is an iron salt of phosphoric acid.

<span class="mw-page-title-main">Sodium monofluorophosphate</span> Chemical compound

Sodium monofluorophosphate, commonly abbreviated SMFP, is an inorganic compound with the chemical formula Na2PO3F. Typical for a salt, MFP is odourless, colourless, and water-soluble. This salt is an ingredient in some toothpastes.

Aluminium phosphate is a chemical compound. In nature it occurs as the mineral berlinite. Many synthetic forms of aluminium phosphate are known. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers or molecular sieves. Commercial aluminium phosphate gel is available.

<span class="mw-page-title-main">Lithium iron phosphate</span> Chemical compound

Lithium iron phosphate or lithium ferro-phosphate (LFP) is an inorganic compound with the formula LiFePO
4
. It is a gray, red-grey, brown or black solid that is insoluble in water. The material has attracted attention as a component of lithium iron phosphate batteries, a type of Li-ion battery. This battery chemistry is targeted for use in power tools, electric vehicles, solar energy installations and more recently large grid-scale energy storage.

<span class="mw-page-title-main">Trimagnesium phosphate</span> Chemical compound

Trimagnesium phosphate describes inorganic compounds with formula Mg3(PO4)2.xH2O. They are magnesium acid salts of phosphoric acid, with varying amounts of water of crystallization: x = 0, 5, 8, 22.

<span class="mw-page-title-main">Copper(II) phosphate</span> Chemical compound

Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.

Sodium aluminium phosphate (SAlP) describes the inorganic compounds consisting of sodium salts of aluminium phosphates. The most common SAlP has the formulas NaH14Al3(PO4)8·4H2O and Na3H15Al2(PO4)8. These materials are prepared by combining alumina, phosphoric acid, and sodium hydroxide.

Manganese(II) phosphate is an inorganic compound with the chemical formula Mn3(PO4)2. It has industrial importance as a constituent of manganese based phosphate conversion coatings.

<span class="mw-page-title-main">Chromium(III) phosphate</span> Chemical compound

Chromium(III) phosphate describes inorganic compounds with the chemical formula CrPO4·(H2O)n, where n = 0, 4, or 6. All are deeply colored solids. Anhydrous CrPO4 is green. The hexahydrate CrPO4·6H2O is violet.

Copper phosphate may refer to :

Actinium compounds are compounds containing the element actinium (Ac). Due to actinium's intense radioactivity, only a limited number of actinium compounds are known. These include: AcF3, AcCl3, AcBr3, AcOF, AcOCl, AcOBr, Ac2S3, Ac2O3, AcPO4 and Ac(NO3)3. Except for AcPO4, they are all similar to the corresponding lanthanum compounds. They all contain actinium in the oxidation state +3. In particular, the lattice constants of the analogous lanthanum and actinium compounds differ by only a few percent.

Gold(III) phosphate is a chemical compound with the formula AuPO4. It is a pale yellow solid that is insoluble in water and acetone. It decomposes at 450 °C into gold metal, phosphorus pentoxide, and oxygen.

References

  1. "Lead phosphate". pubchem.ncbi.nlm.nih.gov. Retrieved 27 April 2023.
  2. "Lead(II) phosphate". The Chemical Thesaurus. Retrieved 11 October 2010.
  3. Wright, John, (2003). Environmental Chemistry pg 211. New York (NY): Routledge.
  4. Lewis, Richard J., Lewis, Richard J. Sr., (2008). Hazardous chemicals desk reference (sixth ed.) pg 831. Hoboken (NJ): John Wiley & Sons, Inc.