"Magnesium silicate" redirects here. For the synthetic form, see synthetic magnesium silicate. For the chemical and mineral with the [SiO4]−4 anion, see forsterite.
The Mohs scale of mineral hardness, based on scratchhardness comparison, defines value 1 as the hardness of talc, the softest mineral. When scraped on a streak plate, talc produces a white streak, though this indicator is of little importance, because most silicate minerals produce a white streak. Talc is translucent to opaque, with colors ranging from whitish grey to green with a vitreous and pearly luster. Talc is not soluble in water, and is slightly soluble in dilute mineral acids.[7]
The word "talc" derives from Persian: تالکtālk. In ancient times, the word was used for various related minerals, including talc, mica, and selenite.[8]
Formation
A block of talc
Talc dominantly forms from the metamorphism of magnesian minerals such as serpentine, pyroxene, amphibole, and olivine, in the presence of carbon dioxide and water. This is known as "talc carbonation" or "steatization" and produces a suite of rocks known as talc carbonates.
Talc is primarily formed by hydration and carbonation by this reaction:
Talc can also be formed via a reaction between dolomite and silica, which is typical of skarnification of dolomites by silica-flooding in contact metamorphic aureoles:
Talc is also found as a diagenetic mineral in sedimentary rocks where it can form from the transformation of metastable hydrated magnesium-clay precursors such as kerolite, sepiolite, or stevensite that can precipitate from marine and lake water in certain conditions.[9]
In this reaction, the ratio of talc and kyanite depends on aluminium content, with more aluminous rocks favoring production of kyanite. This is typically associated with high-pressure, low-temperature minerals such as phengite, garnet, and glaucophane within the lower blueschist facies. Such rocks are typically white, friable, and fibrous, and are known as whiteschist.
Talc is a trioctahedral layered mineral; its structure is similar to pyrophyllite, but with magnesium in the octahedral sites of the composite layers.[2] The crystal structure of talc is described as TOT, meaning that it is composed of parallel TOT layers weakly bonded to each other by weak van der Waals forces. The TOT layers in turn consist of two tetrahedral sheets (T) strongly bonded to the two faces of a single trioctahedral sheet (O). It is the weak bonding between TOT layers that gives talc its perfect basal cleavage and softness.[10]
The tetrahedral sheets consist of silica tetrahedra, which are silicon ions surrounded by four oxygen ions. The tetrahedra each share three of their four oxygen ions with neighboring tetrahedra to produce a hexagonal sheet. The remaining oxygen ion (the apical oxygen ion) is available to bond with the trioctahedral sheet.[11]
The trioctahedral sheet has the structure of a sheet of the mineral brucite. Apical oxygens take the place of some of the hydroxyl ions that would be present in a brucite sheet, bonding the tetrahedral sheets tightly to the trioctahedral sheet.[12]
Tetrahedral sheets have a negative charge, since their bulk composition is Si4O104-. The trioctahedral sheet has an equal positive charge, since its bulk composition is Mg3(OH)24+ The combined TOT layer thus is electrically neutral.[13]
Because the hexagons in the T and O sheets are slightly different in size, the sheets are slightly distorted when they bond into a TOT layer. This breaks the hexagonal symmetry and reduces it to monoclinic or triclinic symmetry.[14] However, the original hexahedral symmetry is discernible in the pseudotrigonal character of talc crystals.[3]
View of tetrahedral sheet structure of talc. The apical oxygen ions are tinted pink.
View of trioctahedral sheet of talc. Yellow spheres are hydroxyl; blue are magnesium. Apical oxygen binding sites are white.
Talc crystal viewed along the [100] axis, looking along the layers of the crystal
Occurrence
Talc output in 2005
Talc is a common metamorphic mineral in metamorphic belts that contain ultramafic rocks, such as soapstone (a high-talc rock), and within whiteschist and blueschist metamorphic terranes. Prime examples of whiteschists include the Franciscan Metamorphic Belt of the western United States, the western European Alps especially in Italy, certain areas of the Musgrave Block, and some collisional orogens such as the Himalayas, which stretch along Pakistan, India, Nepal, and Bhutan.
China is the key world talc and steatite-producing country with an output of about 2.2M tonnes(2016), which accounts for 30% of total global output. The other major producers are Brazil (12%), India (11%), the U.S. (9%), France (6%), Finland (4%), Italy, Russia, Canada, and Austria (2%, each).[15]
Notable economic talc occurrences include the Mount Seabrook talc mine, Western Australia, formed upon a polydeformed, layered ultramafic intrusion. The France-based Luzenac Group is the world's largest supplier of mined talc. Its largest talc mine at Trimouns near Luzenac in southern France produces 400,000tonnes of talc per year.
Talcum powderThe structure of talc is composed of Si2O5 sheets with magnesium sandwiched between sheets in octahedral sites.
Talc is used in many industries, including paper making, plastic, paint and coatings (e.g. for metal casting molds), rubber, food, electric cable, pharmaceuticals, cosmetics, and ceramics. A coarse grayish-green high-talc rock is soapstone or steatite, used for stoves, sinks, electrical switchboards, etc. It is often used for surfaces of laboratory table tops and electrical switchboards because of its resistance to heat, electricity, and acids.
In finely ground form, talc finds use as a cosmetic (talcum powder), as a lubricant, and as a filler in paper manufacture. It is used to coat the insides of inner tubes and rubber gloves during manufacture to keep the surfaces from sticking. Talcum powder, with heavy refinement, has been used in baby powder, an astringent powder used to prevent diaper rash (nappy rash). The American Academy of Pediatrics recommends that parents avoid using baby powder because it poses a risk of respiratory problems, including breathing trouble and serious lung damage if inhaled. The small size of the particles makes it difficult to keep them out of the air while applying the powder. Zinc oxide-based ointments are a much safer alternative.[17]
Due to its low shear strength, talc is one of the oldest known solid lubricants. Also, limited use is made of talc as a friction-reducing additive in lubricating oils.[20]
Talc is widely used in the ceramics industry in both bodies and glazes. In low-fire art-ware bodies, it imparts whiteness and increases thermal expansion to resist crazing. In stonewares, small percentages of talc are used to flux the body and therefore improve strength and vitrification. It is a source of MgO flux in high-temperature glazes (to control melting temperature). It is also employed as a matting agent in earthenware glazes and can be used to produce magnesia mattes at high temperatures.
ISO standard for quality (ISO 3262)
Type
Talc content min. wt%
Loss on ignition at 1000°C, wt%
Solubility in HCl, max. wt%
A
95
4 – 6.5
5
B
90
4–9
10
C
70
4–18
30
D
50
4–27
30
Patents are pending on the use of magnesium silicate as a cement substitute. Its production requirements are less energy-intensive than ordinary Portland cement (at a heating requirement of around 650°C for talc compared to 1500°C for limestone to produce Portland cement), while it absorbs far more carbon dioxide as it hardens. This results in a negative carbon footprint overall, as the cement substitute removes 0.6 tonnes of CO2 per tonne used. This contrasts with a positive carbon footprint of 0.4 tonnes per tonne of conventional cement.[21]
Talc is used in the production of the materials that are widely used in the building interiors such as base content paints in wall coatings. Other areas that use talc to a great extent are organic agriculture, the food industry, cosmetics, and hygiene products such as baby powder and detergent powder.
Sterile talc powder (NDC 63256-200-05) is a sclerosing agent used in the procedure of pleurodesis. This can be helpful as a cancer treatment to prevent pleural effusions (an abnormal collection of fluid in the space between the lungs and the thoracic wall). It is inserted into the space via a chest tube, causing it to close up, so fluid cannot collect there. The product can be sterilized by dry heat, ethylene oxide, or gamma irradiation.[22]
Safety
Suspicions have been raised that talc use contributes to certain types of disease, mainly cancers of the ovaries and lungs. According to the IARC, talc containing asbestos is classified as a group 1 agent (carcinogenic to humans), talc use in the perineum is classified as group 2B (possibly carcinogenic to humans), and talc not containing asbestos is classified as group 3 (unclassifiable as to carcinogenicity in humans).[23] Reviews by Cancer Research UK and the American Cancer Society conclude that some studies have found a link, but other studies have not.[24][25]
The studies discuss pulmonary issues,[26]lung cancer,[27][28] and ovarian cancer.[29] One of these, published in 1993, was a US National Toxicology Program report, which found that cosmetic grade talc containing no asbestos-like fibres was correlated with tumor formation in rats forced to inhale talc for 6 hours a day, five days a week over at least 113 weeks.[27] A 1971 paper found particles of talc embedded in 75% of the ovarian tumors studied.[30] Research published in 1995 and 2000 concluded that it was plausible that talc could cause ovarian cancer, but no conclusive evidence was shown.[31][32] The Cosmetic Ingredient Review Expert Panel concluded in 2015 that talc, in the concentrations currently used in cosmetics, is safe.[33] In 2018, Health Canada issued a warning, advising against inhaling talcum powder or using it in the female perineal area.[34]
One particular issue with commercial use of talc is its frequent co-location in underground deposits with asbestos ore. Asbestos is a general term for different types of fibrous silicate minerals, desirable in construction for their heat resistant properties.[37] There are six varieties of asbestos; the most common variety in manufacturing, white asbestos, is in the serpentine family.[38] Serpentine minerals are sheet silicates; although not in the serpentine family, talc is also a sheet silicate, with two sheets connected by magnesium cations. The frequent co-location of talc deposits with asbestos may result in contamination of mined talc with white asbestos, which poses serious health risks when dispersed into the air and inhaled. Stringent quality control since 1976, including separating cosmetic- and food-grade talc from "industrial"-grade talc, has largely eliminated this issue, but it remains a potential hazard requiring mitigation in the mining and processing of talc.[39] A 2010 US FDA survey failed to find asbestos in a variety of talc-containing products.[40] A 2018 Reuters investigation asserted that pharmaceuticals company Johnson & Johnson knew for decades that there was asbestos in its baby powder,[41] and in 2020 the company stopped selling its baby powder in the US and Canada.[42] There were calls for Johnson & Johnson's largest shareholders to force the company to end global sales of baby powder, and hire an independent firm to conduct a racial justice audit as it had been marketed to African American and overweight women.[43] On August 11, 2022, the company announced it would stop making talc-based powder by 2023 and replace it with cornstarch-based powders. The company said the talc-based powder is safe to use and does not contain asbestos.[44]
Litigation
In 2006 the International Agency for Research on Cancer classified talcum powder as a possible human carcinogen if used in the female genital area. Despite this, no federal agency in the US acted to remove talcum powder from the market or add warnings.[45]
In February 2016, as the result of a lawsuit against Johnson & Johnson (J&J), a St. Louis jury awarded $72 million to the family of an Alabama woman who died from ovarian cancer. The family claimed that the use of talcum powder was responsible for her cancer.
In May 2016, a South Dakota woman was awarded $55 million as the result of another lawsuit against J&J.[46] The woman had used Johnson & Johnson's Baby Powder for more than 35 years before being diagnosed with ovarian cancer in 2011.[47]
In October 2016, a St. Louis jury awarded $70.1 million to a Californian woman with ovarian cancer who had used Johnson's Baby Powder for 45 years.[48]
In August 2017, a Los Angeles jury awarded $417 million to a Californian woman, Eva Echeverria, who developed ovarian cancer as a "proximate result of the unreasonably dangerous and defective nature of talcum powder", her lawsuit against Johnson & Johnson stated.[49] On 20 October 2017, Los Angeles Superior Court judge Maren Nelson dismissed the verdict. The judge stated that Echeverria proved there is "an ongoing debate in the scientific and medical community about whether talc more probably than not causes ovarian cancer and thus (gives) rise to a duty to warn", but not enough to sustain the jury's imposition of liability against Johnson & Johnson stated, and concluded that Echeverria did not adequately establish that talc causes ovarian cancer.[50][51]
In July 2018, a court in St. Louis awarded a $4.7bn claim ($4.14bn in punitive damages and $550m in compensatory damages) against J&J to 22 claimant women, concluding that the company had suppressed evidence of asbestos in its products for more than four decades.[52]
At least 1,200 to 2,000 other talcum powder-related lawsuits were pending as of 2016[update].[48][53]
In July 2023 J&J sued researchers who linked talc to cancer alleging they used junk science to disparage company's products, while defendants say the lawsuits are meant to silence scientists.[54]
See also
Pyrophyllite– Aluminium silicate hydroxide phyllosilicate mineral
Serpentinite– Rock formed by hydration and metamorphic transformation of olivine
Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula K(Mg,Fe)3AlSi3O10(F,OH)2. It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more aluminous end-members include siderophyllite and eastonite. Biotite was regarded as a mineral species by the International Mineralogical Association until 1998, when its status was changed to a mineral group. The term biotite is still used to describe unanalysed dark micas in the field. Biotite was named by J.F.L. Hausmann in 1847 in honor of the French physicist Jean-Baptiste Biot, who performed early research into the many optical properties of mica.
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.
Micas are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is common in igneous and metamorphic rock and is occasionally found as small flakes in sedimentary rock. It is particularly prominent in many granites, pegmatites, and schists, and "books" of mica several feet across have been found in some pegmatites.
Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(AlSi3O10)(F,OH)2, or (KF)2(Al2O3)3(SiO2)6(H2O). It has a highly perfect basal cleavage yielding remarkably thin laminae (sheets) which are often highly elastic. Sheets of muscovite 5 meters × 3 meters (16.5 feet × 10 feet) have been found in Nellore, India.
Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO 4 tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.
The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.
Serpentine subgroup are greenish, brownish, or spotted minerals commonly found in serpentinite. They are used as a source of magnesium and asbestos, and as decorative stone. The name comes from the greenish color and smooth or scaly appearance from the Latin serpentinus, meaning "serpent rock".
Wollastonite is a calcium inosilicate mineral (CaSiO3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns or in contact with metamorphic rocks. Associated minerals include garnets, vesuvianite, diopside, tremolite, epidote, plagioclase feldspar, pyroxene and calcite. It is named after the English chemist and mineralogist William Hyde Wollaston (1766–1828).
Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals known as the gemstone jade, is a green variety of tremolite.
Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2Si2O5(OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Anthophyllite is an orthorhombic amphibole mineral: ☐Mg2Mg5Si8O22(OH)2 (☐ is for a vacancy, a point defect in the crystal structure), magnesium iron inosilicate hydroxide. Anthophyllite is polymorphic with cummingtonite. Some forms of anthophyllite are lamellar or fibrous and are classed as asbestos. The name is derived from the Latin word anthophyllum, meaning clove, an allusion to the most common color of the mineral. The Anthophyllite crystal is characterized by its perfect cleavage along directions 126 degrees and 54 degrees.
An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption. Caking mechanisms depend on the nature of the material. Crystalline solids often cake by formation of liquid bridge and subsequent fusion of microcrystals. Amorphous materials can cake by glass transitions and changes in viscosity. Polymorphic phase transitions can also induce caking.
Baby powder is an astringent powder used for preventing diaper rash and for cosmetic uses. It may be composed of talc, corn starch or potato starch. It may also contain additional ingredients like fragrances. Baby powder can also be used as a dry shampoo, cleaning agent, and freshener.
"Chasing the dragon" (CTD), or "foily" in Australian English, refers to inhaling the vapor of a powdered psychoactive drug off a heated sheet of aluminium foil. The moving vapor is chased after with a tube through which the user inhales. The "chasing" occurs as the user gingerly keeps the liquid moving in order to keep it from overheating and burning up too quickly, on a heat conducting material such as aluminium foil.
Nontronite is the iron(III) rich member of the smectite group of clay minerals. Nontronites typically have a chemical composition consisting of more than ~30% Fe2O3 and less than ~12% Al2O3 (ignited basis). Nontronite has very few economic deposits like montmorillonite. Like montmorillonite, nontronite can have variable amounts of adsorbed water associated with the interlayer surfaces and the exchange cations.
Talc carbonates are a suite of rock and mineral compositions found in metamorphosed ultramafic rocks.
Asbestos is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere by abrasion and other processes. Inhalation of asbestos fibres can lead to various dangerous lung conditions, including mesothelioma, asbestosis, and lung cancer. As a result of these health effects, asbestos is considered a serious health and safety hazard.
Pimelite was discredited as a mineral species by the International Mineralogical Association (IMA) in 2006, in an article which suggests that "pimelite" specimens are probably willemseite, or kerolite. This was a mass discreditation, and not based on any re-examination of the type material. Nevertheless, a considerable number of papers have been written, verifying that pimelite is a nickel-dominant smectite. It is always possible to redefine a mineral wrongly discredited.
Johnson's Baby is an American brand of baby cosmetics and skin care products owned by Kenvue. The brand was introduced in 1893 with Johnson's Baby Powder. The product line consists of baby powder, shampoos, body lotions, massage oil, shower gels and baby wipes.
↑ Gruber, James (November–December 2019). "Do Cosmetic Consumers Really Know What Ingredients They Are Using? An Inquiry into the Search for the 'Truth'". Skeptical Inquirer. 43 (6): 54.
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