| Singles | |
|---|---|
| 2012 Valencia Open 500 | |
| Champion |  David Ferrer |
| Runner-up |  Alexandr Dolgopolov |
| Final score | 6–1, 3–6, 6–4 |
| Draw | 32 |
| Seeds | 8 |
Marcel Granollers was the defending champion, but lost to Alexandr Dolgopolov in the quarterfinals.
David Ferrer won the title, defeating Dolgopolov in the final, 6–1, 3–6, 6–4.
Former world No. 1 Juan Carlos Ferrero played his last match at the tournament losing to 6th seed Nicolás Almagro in the first round in straight sets.
David Ferrer (champion)
Jo-Wilfried Tsonga (first round, retired because of a back injury)
Janko Tipsarević (first round, retired because of a right shoulder injury)
Juan Mónaco (first round)
John Isner (second round) Nicolás Almagro (quarterfinals)
Marin Čilić (quarterfinals)
Milos Raonic (first round)| Semifinals | Final | ||||||||||||
| 1 | David Ferrer | 6 | 65 | 6 | |||||||||
| Q | Ivan Dodig | 4 | 77 | 1 | |||||||||
| 1 | David Ferrer | 6 | 3 | 6 | |||||||||
| Alexandr Dolgopolov | 1 | 6 | 4 | ||||||||||
| Alexandr Dolgopolov | 6 | 6 | |||||||||||
 Jürgen Melzer | 4 | 2 | |||||||||||
| First round | Second round | Quarterfinals | Semifinals | ||||||||||||||||||||||||
| 1 | D Ferrer | 7 | 7 | ||||||||||||||||||||||||
| Q |  O Rochus | 5 | 5 | 1 | D Ferrer | 6 | 6 | ||||||||||||||||||||
| A Ramos | 6 | 6 | A Ramos | 4 | 2 | ||||||||||||||||||||||
| Q | R Ram | 3 | 3 | 1 | D Ferrer | 6 | 7 | ||||||||||||||||||||
| S Querrey | 6 | 77 | 6 | N Almagro | 3 | 5 | |||||||||||||||||||||
| F López | 3 | 64 | S Querrey | 4 | 77 | 0 | |||||||||||||||||||||
| WC | JC Ferrero | 5 | 3 | 6 | N Almagro | 6 | 64 | 6 | |||||||||||||||||||
| 6 | N Almagro | 7 | 6 | 1 | D Ferrer | 6 | 65 | 6 | |||||||||||||||||||
| 4 | J Mónaco | 3 | 4 | Q | I Dodig | 4 | 77 | 1 | |||||||||||||||||||
| WC |  L Hewitt | 6 | 6 | WC | L Hewitt | 1 | 6 | 2 | |||||||||||||||||||
| Q | I Dodig | 6 | 78 | Q | I Dodig | 6 | 3 | 6 | |||||||||||||||||||
 P Kohlschreiber | 2 | 66 | Q | I Dodig | 6 | 78 | |||||||||||||||||||||
| F Verdasco | 6 | 6 | 7 | M Čilić | 2 | 66 | |||||||||||||||||||||
| WC | T Robredo | 3 | 4 | F Verdasco | 1 | 4 | |||||||||||||||||||||
 M Kližan | 6 | 0 | 3 | 7 | M Čilić | 6 | 6 | ||||||||||||||||||||
| 7 | M Čilić | 1 | 6 | 6 | |||||||||||||||||||||||
| First round | Second round | Quarterfinals | Semifinals | ||||||||||||||||||||||||
| 8 | M Raonic | 5 | 61 | ||||||||||||||||||||||||
 G Müller | 7 | 77 | G Müller | 4 | 4 | ||||||||||||||||||||||
| A Dolgopolov | 6 | 77 | A Dolgopolov | 6 | 6 | ||||||||||||||||||||||
 F Volandri | 3 | 65 | A Dolgopolov | 6 | 6 | ||||||||||||||||||||||
| M Granollers | 7 | 6 | M Granollers | 0 | 2 | ||||||||||||||||||||||
| Q |  J Hájek | 5 | 4 | M Granollers | 64 | 6 | 6 | ||||||||||||||||||||
| G Simon | 5 | G Simon | 77 | 3 | 2 | ||||||||||||||||||||||
| 3 | J Tipsarević | 4r | A Dolgopolov | 6 | 6 | ||||||||||||||||||||||
| 5 | J Isner | 6 | 64 | 7 | J Melzer | 4 | 2 | ||||||||||||||||||||
| F Fognini | 3 | 77 | 5 | 5 | J Isner | 62 | 6 | 4 | |||||||||||||||||||
| D Goffin | 6 | 6 | D Goffin | 77 | 4 | 6 | |||||||||||||||||||||
| P Andújar | 2 | 2 | D Goffin | 67 | 4 | ||||||||||||||||||||||
| J Melzer | 6 | 6 | J Melzer | 79 | 6 | ||||||||||||||||||||||
| C Berlocq | 3 | 3 | J Melzer | 7 | 6 | ||||||||||||||||||||||
| X Malisse | 3 | X Malisse | 5 | 2 | |||||||||||||||||||||||
| 2 | J-W Tsonga | 1r | |||||||||||||||||||||||||
Daniel Gimeno Traver (qualifying competition) Roberto Bautista Agut (qualifying competition) Flavio Cipolla (first round) Philipp Petzschner (qualifying competition) Rajeev Ram (qualified)
Ričardas Berankis (first round) Olivier Rochus (qualified) Ivan Dodig (qualified)| First round | Qualifying competition | ||||||||||||
| 1 | Daniel Gimeno Traver | 77 | 4 | 77 | |||||||||
| Vasek Pospisil | 64 | 6 | 62 | ||||||||||
| 1 | Daniel Gimeno Traver | 4 | 64 | ||||||||||
| Jan Hájek | 6 | 77 | |||||||||||
| Jan Hájek | 77 | 6 | |||||||||||
| 6 | Ričardas Berankis | 65 | 2 | ||||||||||
| First round | Qualifying competition | ||||||||||||
| 2 | Roberto Bautista Agut | 6 | 6 | ||||||||||
| Albert Montañés | 2 | 2 | |||||||||||
| 2 | Roberto Bautista Agut | 2 | 5 | ||||||||||
| 7 | Olivier Rochus | 6 | 7 | ||||||||||
| Ruben Bemelmans | 4 | 2 | |||||||||||
| 7 | Olivier Rochus | 6 | 6 | ||||||||||
| First round | Qualifying competition | ||||||||||||
| 3 | Flavio Cipolla | 65 | 4 | ||||||||||
| Daniel Brands | 77 | 6 | |||||||||||
| Daniel Brands | 1 | 4 | |||||||||||
| 8 | Ivan Dodig | 6 | 6 | ||||||||||
| WC | Dominic Thiem | 2 | 0 | ||||||||||
| 8 | Ivan Dodig | 6 | 6 | ||||||||||
| First round | Qualifying competition | ||||||||||||
| 4 | Philipp Petzschner | 6 | 6 | ||||||||||
| WC | Mario Vilella Martínez | 2 | 2 | ||||||||||
| 4 | Philipp Petzschner | 6 | 4 | 4 | |||||||||
| 5 | Rajeev Ram | 3 | 6 | 6 | |||||||||
| WC | Sergio Gutiérrez Ferrol | 3 | 3 | ||||||||||
| 5 | Rajeev Ram | 6 | 6 | ||||||||||
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