Alumina effect pigment

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An alumina effect pigment is a pearlescent pigment based on alumina (aluminium oxide). It is used for decorative purposes on paints and plastics, giving them a matte, metal-like appearance.

Contents

Production process

Fig. 1: Pure aluminium oxide flakes Alumina flake production.jpg
Fig. 1: Pure aluminium oxide flakes
Pure aluminium oxide flakes SEM of coated alumina flake.JPG
Pure aluminium oxide flakes

In the first step of the production process, Al2O3 (Aluminium oxide) flakes with a very smooth surface are formed. The flakes are produced using a crystal growth process. They are formed in the corundum structure (α-Al2O3). The desired flake shape is achieved by controlled crystal growth in the axial and equatorial directions. The color purity and transparency of the effect pigments obtained by coating the Al2O3 flakes with metal oxides can be attributed to the synthesis procedure yielding single-crystalline thin flakes [1] [2]

The coating of the alumina platelets with high-refractive metal oxides, such as with titanium dioxide and iron(III) oxide leads to strongly reflecting effect pigments. These pigments possess a strong glitter effect. The coating process is analogous to that used for metal oxide mica pigments except it starts from an aqueous suspension of Al2O3 flakes. The complete manufacturing process of pigments based on aluminum oxide platelets, consisting of the flake production and the coating with metal oxides is shown in Figure 1 [3]

For outdoor applications they are modified with an additional weather stabilizing surface treatment.

Products

Thickness of TiO2 determines the inference color TiO2 interference by thickness.jpg
Thickness of TiO2 determines the inference color

Silverwhite and interference pigments based on Al2O3flakes can be produced—analogous to similar pigments based on mica platelets—in different colors, e.g. gold, red, blue or green, by variation of the titanium dioxide layer thickness.

Depending on the layer thickness, the coating with iron oxide leads to bronze-, copper- or red-colored effect pigments. The pigments obtainable at the market possess a narrow particle size distribution of about 5 to 30 μm as well as a high aspect ratio. The sparkle effect referred to above has its origin in the optimized thickness of all layers in the pigment structure, including the Al2O3substrate. Analytical investigations show that the thickness range of the aluminum oxide platelets and the resultant pigments can be controlled very precisely. [4] [5]

Special effects

car dummy coated with iron oxide coated Alumina flake Car shape fireside copper Xirallic red.jpg
car dummy coated with iron oxide coated Alumina flake

The sparkle effect of the pigments in coating applications is controlled by the quantity of the added pigment. The effect is visible already at concentrations of 0.1% in the paint system. The intensity is steadily increased up to pigment concentrations of about 2%. The single light spots arising from the pigment structure and orientation in the paint system seem to spring back and forth when a painted metal plate is tilted. Also, the color of the other components of the paint has an influence in addition to the concentration of the pigment. A dark color, for example, forms a high contrast to the bright light spots and strengthens the effect. Favorable is also the use of a covering varnish in order to achieve an optimal effect. [4] [6]

The pigments can be applied with all painting techniques established for conventional pearlescent and interference pigments. Effect pigments based on alumina flakes may be applied in all substantial systems, i.e. in coatings, plastics, printing inks and cosmetic formulations. An additional surface treatment is applied to the pigment particles to adjust them to solvent-based and water-based coating systems. The pigments can be used in combination with many conventional pigments as well as with other effect pigments. Nearly unlimited styling possibilities are the result of these combinations. [4] [6]

See also

Literature

Related Research Articles

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The mica group of sheet silicate (phyllosilicate) minerals includes several closely related materials having nearly perfect basal cleavage. All are monoclinic, with a tendency towards pseudohexagonal crystals, and are similar in chemical composition. The nearly perfect cleavage, which is the most prominent characteristic of mica, is explained by the hexagonal sheet-like arrangement of its atoms.

Paint colored composition applied over a surface that dries as a solid film

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Aluminium oxide Chemical compound with formula Al2O3

Aluminium oxide (IUPAC name) or aluminum oxide (American English) is a chemical compound of aluminium and oxygen with the chemical formula Al2O3. It is the most commonly occurring of several aluminium oxides, and specifically identified as aluminium(III) oxide. It is commonly called alumina and may also be called aloxide, aloxite, or alundum depending on particular forms or applications. It occurs naturally in its crystalline polymorphic phase α-Al2O3 as the mineral corundum, varieties of which form the precious gemstones ruby and sapphire. Al2O3 is significant in its use to produce aluminium metal, as an abrasive owing to its hardness, and as a refractory material owing to its high melting point.

Ilmenite oxide mineral

Ilmenite, also known as manaccanite, is a titanium-iron oxide mineral with the idealized formula FeTiO
3
. It is a weakly magnetic black or steel-gray solid. From a commercial perspective, ilmenite is the most important ore of titanium. Ilmenite is the main source of titanium dioxide, which is used in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics.

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Titanium dioxide chemical compound

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2
. When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. Generally, it is sourced from ilmenite, rutile, and anatase. It has a wide range of applications, including paint, sunscreen, and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million tonnes. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide have been valued at $13.2 billion.

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Superalloy Alloy with higher durability than normal metals

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Thermal barrier coating Thermal barrier coating

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Xirallic

Xirallic is an alumina effect pigment pigment made of aluminum oxide platelets covered with titanium oxide that shows a strong glitter effect with a distinct shimmering behavior.

Titanium adhesive bonding is an engineering process used in the aerospace industry, medical-device manufacture and elsewhere. Titanium alloy is often used in medical and military applications because of its strength, weight, and corrosion resistance characteristics. In implantable medical devices, titanium is used because of its biocompatibility and its passive, stable oxide layer. Also, titanium allergies are rare and in those cases mitigations like Parylene coating are used. In the aerospace industry titanium is often bonded to save cost, touch times, and the need for mechanical fasteners. In the past, Russian submarines' hulls were completely made of titanium because the non-magnetic nature of the material went undetected by the defense technology at that time. Bonding adhesive to titanium requires preparing the surface beforehand, and there is not a single solution for all applications. For example, etchant and chemical methods are not biocompatible and cannot be employed when the device will come into contact with blood and tissue. Mechanical surface roughness techniques like sanding and laser roughening may make the surface brittle and create micro-hardness regions that would not be suitable for cyclic loading found in military applications. Air oxidation at high temperatures will produce a crystalline oxide layer at a lower investment cost, but the increased temperatures can deform precision parts. The type of adhesive, thermosetting or thermoplastic, and curing methods are also factors in titanium bonding because of the adhesive's interaction with the treated oxide layer. Surface treatments can also be combined. For example, a grit blast process can be followed by a chemical etch and a primer application.

References

  1. Nitta, K., Shau, T. M. Sugahara, J. EP 763 573
  2. Sharrock, S., Schül, N. "New Effect Pigments Based on SiO2 and Al2O3 Flakes", Eur. Coat. J. (1/2) (2000) 20
  3. Teaney, S., Pfaff, G., Nitta, K., "New Effect Pigments Using Innovative Substrates", Eur. Coat. J. (4) (1999) 90
  4. 1 2 3 Huber, A., Pfaff, G., "Spezielle Effektpigmente", Phänomen Farbe (3) (2005) 34
  5. Etzoldt, G., Kittel – Lehrbuch der Lacke und Beschichtungen (Pigmente, Füllstoffe und Farbmetrik), 2. Aufl., S. Hirzel Verlag Stuttgart-Leipzig, 2003, 160
  6. 1 2 Pfaff, G., Huber, A., “Spezielle Effektpigmente auf Basis von Aluminiumoxid-Plättchen”, Welt der Farben (9) (2005) 14]