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Sphalerite is a sulfide mineral with the chemical formula (Zn,Fe)S. It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in sedimentary exhalative, Mississippi-Valley type, and volcanogenic massive sulfide deposits. It is found in association with galena, chalcopyrite, pyrite, calcite, dolomite, quartz, rhodochrosite, and fluorite.
Hemimorphite is the chemical compound Zn4(Si2O7)(OH)2·H2O, a component of mineral calamine. It is a silicate mineral which, together with smithsonite (ZnCO3), has been historically mined from the upper parts of zinc and lead ores. Both compounds were originally believed to be the same mineral and classified as calamine. In the second half of the 18th century, it was discovered that these two different compounds were both present in calamine. They closely resemble one another.
Zoisite, first known as saualpite, after its type locality, is a calcium aluminum hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2Al3(SiO4)(Si2O7)O(OH).
Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2. It forms hydrates. Zinc chloride, anhydrous and its hydrates are colorless or white crystalline solids, and are highly soluble in water. Five hydrates of zinc chloride are known, as well as four forms of anhydrous zinc chloride. This salt is hygroscopic and even deliquescent. Zinc chloride finds wide application in textile processing, metallurgical fluxes, and chemical synthesis. No mineral with this chemical composition is known aside from the very rare mineral simonkolleite, Zn5(OH)8Cl2·H2O.
Wurtzite is a zinc and iron sulfide mineral with the chemical formula (Zn,Fe)S, a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent. It is trimorphous with matraite and sphalerite.
Zincobotryogen is a hydrous sulfate mineral with the chemical formula (Zn,Mg,Mn)Fe3+(SO4)2(OH)·7H2O. It forms bright orange red monoclinic prismatic crystals that exhibit a vitreous to greasy luster. Its specific gravity is 2.201 and it has a Mohs hardness of 2.5.
Zinc hydroxide Zn(OH)2 is an inorganic chemical compound. It also occurs naturally as 3 rare minerals: wülfingite (orthorhombic), ashoverite and sweetite (both tetragonal).
Jerrygibbsite is a rare silicate mineral with the chemical formula (Mn,Zn)9(SiO4)4(OH)2. Jerrygibbsite was originally discovered by Pete J. Dunn in 1984, who named it after mineralogist Gerald V. Gibbs. It has only been reported from the type locality of Franklin Furnace, New Jersey, United States, and in Namibia's Otjozondjupa region. Jerrygibbsite is member of the leucophoenite family of the humite group. It is always found with these two minerals. It is a dimorph of sonolite.
Duftite is a relatively common arsenate mineral with the formula CuPb(AsO4)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite-descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO4 )(OH), austinite, CaZn(AsO4)(OH) and duftite PbCu(AsO4)(OH), all of them belonging to the adelite group of arsenates. It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia. The type locality is the Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia.
Alsakharovite-Zn (IMA symbol: Ask-Zn) is an extremely rare alkaline strontium zinc titanium silicate mineral from the cyclosilicates class, with the chemical formula NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4·7H2O, from alkaline pegmatites. It belongs to the labuntsovite group.
Cleusonite is a member of the crichtonite group of minerals with the chemical formula (Pb,Sr)(U4+
,U6+
)(Fe2+
,Zn)
2(Ti,Fe2+
,Fe3+
)
18(O,OH)
38. This group of minerals contains approximately thirteen complex metal titanates. The structures of minerals of this group is complicated by frequent fine-scale twinning and metamictization due to radioactive elements. The crichtonite group consists of members of related mineral species of the type A{BC2D6E12}O38 which are characterized by their predominant cations (as seen in crichtonite (Sr), senaite (Pb), davidite (REE + U), landauite (Na), loveringite (Ca), lindsleyite (Ba), and mathiasite (K).
Sweetite has a general formula of Zn(OH)2. The name is given after a curator of mineral department of The British Museum, Jessie May Sweet (1901–1979). It occurs in an oxidized vein in limestone bedrock with galena, ashoverite, wülfingite, anglesite, cerussite, hydrocerussite, litharge, fluorite, palygorskite and calcite.
Matlockite is a rare lead halide mineral, named after the town of Matlock in Derbyshire, England, where it was first discovered in a nearby mine. Matlockite gives its name to the matlockite group which consists of rare minerals of a similar structure.
Zinclipscombite is a dark-green to brown zinc iron phosphate mineral with the formula Zn(Fe3+)2(PO4)2(OH)2. It occurs as fibrous spheres and exhibits tetragonal crystal structure.
Ferronigerite-2N1S is an iron, tin, alumino-hydroxide mineral that naturally occurs around sillimanite-quartz veins. Ferronigerite-2N1S belongs to the nigerite group, högbomite supergroup. The other constituents of the nigerite group are ferronigerite-6N6S, magnesionigerite-2N1S, magnesionigerite-6N6S, zinconigerite-2N1S and zinconigerite-6N6S. The 2N1S ending stands for the nolanite and spinel structural layers.
Gordaite is a sulfate mineral composed primarily of hydrous zinc sodium sulfate chloride hydroxide with formula: NaZn4(SO4)(OH)6Cl·6H2O. It was named for the discovery location in the Sierra Gorda district of Chile. Gordaite forms as tabular trigonal crystals.
Serpierite (Ca(Cu,Zn)4(SO4)2(OH)6·3H2O) is a rare, sky-blue coloured hydrated sulfate mineral, often found as a post-mining product. It is a member of the devilline group, which has members aldridgeite (Cd,Ca)(Cu,Zn)4(SO4)2(OH)6·3H2O, campigliaite Cu4Mn2+(SO4)2(OH)6·4H2O, devilline CaCu4(SO4)2(OH)6·3H2O, kobyashevite Cu5(SO4)2(OH)6·4H2O, lautenthalite PbCu4(SO4)2(OH)6·3H2O and an unnamed dimorph of devilline. It is the calcium analogue of aldridgeite and it is dimorphous with orthoserpierite CaCu4(SO4)2(OH)6·3H2O.
Antigorite is a lamellated, monoclinic mineral in the phyllosilicate serpentine subgroup with the ideal chemical formula of (Mg,Fe2+)3Si2O5(OH)4. It is the high-pressure polymorph of serpentine and is commonly found in metamorphosed serpentinites. Antigorite, and its serpentine polymorphs, play an important role in subduction zone dynamics due to their relative weakness and high weight percent of water (up to 13 weight % H2O). It is named after its type locality, the Geisspfad serpentinite, Valle Antigorio in the border region of Italy/Switzerland and is commonly used as a gemstone in jewelry and carvings.
References
- ↑ Clark, A. M.; Fejer, E. F.; Creesy, G; Tandy, P. C. (1988). "Ashoverite, a new mineral, and other polymorphs of Zn(OH)2 from Milltown, Ashover, Derbyshire" (PDF). Mineralogical Magazine. 52 (368): 699–702. Bibcode:1988MinM...52..699C. doi:10.1180/minmag.1988.052.368.14.
- Handbook of Mineralogy
- Ashoverite Mineral Data, webmineral.com
- Mindat.org
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