In a chemical reaction, chemical equilibrium is the state in which both reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. Usually, this state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but equal. Thus, there are no net changes in the concentrations of the reactant(s) and product(s). Such a state is known as dynamic equilibrium.
In reliability theory and reliability engineering, the term availability has the following meanings:
Circuit reliability (CiR) is the percentage of time an electronic circuit was available for use in a specified period of scheduled availability. Circuit reliability is given by where To is the circuit total outage time, Ts is the circuit total scheduled time, and Ta is the circuit total available time.
In telecommunication, an equivalent noise resistance is a quantitative representation in resistance units of the spectral density of a noise-voltage generator, given by where is the spectral density, is the Boltzmann's constant, is the standard noise temperature, so .
In a system the mean time between outages (MTBO) is the mean time between equipment failures that result in loss of system continuity or unacceptable degradation.
Noise figure (NF) and noise factor (F) are measures of degradation of the signal-to-noise ratio (SNR), caused by components in a signal chain. It is a number by which the performance of an amplifier or a radio receiver can be specified, with lower values indicating better performance.
Mean time between failures (MTBF) is the predicted elapsed time between inherent failures of a mechanical or electronic system, during normal system operation. MTBF can be calculated as the arithmetic mean (average) time between failures of a system. The term is used for repairable systems, while mean time to failure (MTTF) denotes the expected time to failure for a non-repairable system.
In electrochemistry, the Nernst equation is an equation that relates the reduction potential of an electrochemical reaction to the standard electrode potential, temperature, and activities of the chemical species undergoing reduction and oxidation. It was named after Walther Nernst, a German physical chemist who formulated the equation.
Image response is a measure of performance of a radio receiver that operates on the super-heterodyne principle.
Alcohol by volume is a standard measure of how much alcohol (ethanol) is contained in a given volume of an alcoholic beverage. It is defined as the number of millilitres (mL) of pure ethanol present in 100 mL of solution at 20 °C (68 °F). The number of millilitres of pure ethanol is the mass of the ethanol divided by its density at 20 °C, which is 0.78924 g/mL. The ABV standard is used worldwide. The International Organization of Legal Metrology has tables of density of water–ethanol mixtures at different concentrations and temperatures.
In statistics, an effect size is a quantitative measure of the magnitude of a phenomenon. Examples of effect sizes are the correlation between two variables, the regression coefficient in a regression, the mean difference, or even the risk with which something happens, such as how many people survive after a heart attack for every one person that does not survive. For most types of effect size, a larger absolute value always indicates a stronger effect, with the main exception being if the effect size is an odds ratio. Effect sizes complement statistical hypothesis testing, and play an important role in power analyses, sample size planning, and in meta-analyses. They are the first item (magnitude) in the MAGIC criteria for evaluating the strength of a statistical claim. Especially in meta-analysis, where the purpose is to combine multiple effect sizes, the standard error (S.E.) of the effect size is of critical importance. The S.E. of the effect size is used to weigh effect sizes when combining studies, so that large studies are considered more important than small studies in the analysis. The S.E. of the effect size is calculated differently for each type of effect size, but generally only requires knowing the study's sample size (N), or the number of observations in each group.
Digital Signal 1 is a T-carrier signaling scheme devised by Bell Labs. DS1 is the primary digital telephone standard used in the United States, Canada and Japan and is able to transmit up to 24 multiplexed voice and data calls over telephone lines. E-carrier is used in place of T-carrier outside the United States, Canada, Japan, and South Korea. DS1 is the logical bit pattern used over a physical T1 line; in practice, the terms "DS1" and "T1" are often used interchangeably.
In thermodynamics, the exergy of a system is the maximum useful work possible during a process that brings the system into equilibrium with a heat reservoir. When the surroundings are the reservoir, exergy is the potential of a system to cause a change as it achieves equilibrium with its environment. Exergy is the energy that is available to be used. After the system and surroundings reach equilibrium, the exergy is zero. Determining exergy was also the first goal of thermodynamics. The term "exergy" was coined in 1956 by Zoran Rant (1904–1972) by using the Greek ex and ergon meaning "from work", but the concept was developed by J. Willard Gibbs in 1873.
The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is independent of the initial analytical concentrations of the reactant and product species in the mixture. Thus, given the initial composition of a system, known equilibrium constant values can be used to determine the composition of the system at equilibrium. However, reaction parameters like temperature, solvent, and ionic strength may all influence the value of the equilibrium constant.
Failure rate is the frequency with which an engineered system or component fails, expressed in failures per unit of time. It is often denoted by the Greek letter λ (lambda) and is highly used in reliability engineering.
The rate law or rate equation for a chemical reaction is an equation that links the reaction rate with the concentrations or pressures of the reactants and constant parameters. For many reactions the rate is given by a power law such as
Cohen's kappa coefficient (κ) is a statistic which measures inter-rater agreement for qualitative (categorical) items. It is generally thought to be a more robust measure than simple percent agreement calculation, as κ takes into account the possibility of the agreement occurring by chance. There is controversy surrounding Cohen's kappa due to the difficulty in interpreting indices of agreement. Some researchers have suggested that it is conceptually simpler to evaluate disagreement between items. See the Limitations section for more detail.
Availability is the probability that a system will work as required when required during the period of a mission. The mission could be the 18-hour span of an aircraft flight. The mission period could also be the 3 to 15-month span of a military deployment. Availability includes non-operational periods associated with reliability, maintenance, and logistics.
Operational availability in systems engineering is a measurement of how long a system has been available to use when compared with how long it should have been available to be used.
Time Slotted Channel Hopping or Time Synchronized Channel Hopping (TSCH) is a channel access method for shared medium networks.
