Chemical storage

Last updated
A chemical storage cabinet Chemical cabinet3.JPG
A chemical storage cabinet

Chemical storage is the storage of controlled substances or hazardous materials in chemical stores, chemical storage cabinets, or similar devices.

Contents

Chemical storage devices are usually present where a workplace requires the use of non-hazardous and/or hazardous chemicals. Proper storage is imperative for the safety of, and access by, laboratory workers. Improper chemical storage can result in the creation of workplace safety hazards, including the presence of heat, fire, explosion and leakage of toxic gas. [1]

Chemical storage cabinets are typically used to safely store small amounts of chemical substances within a workplace or laboratory for regular use. These cabinets are typically made from materials that are resistant to the chemicals stored in them and occasionally contain a bunded tray to capture spillage.

Chemical stores are warehouses commonly used by chemical or pharmaceutical companies to store bulk chemicals. In the US, the storage and handling of potentially hazardous materials must be disclosed to occupants under laws managed by the Occupational Safety and Health Administration (OSHA).

Principles

Proper labeling is important to ensure that chemicals are not misidentified, which is key to protecting health and safety. For example, organizing chemicals alphabetically is not generally recommended, because it may lead to incompatible chemicals placed near each other, risking a dangerous reaction.

Instead chemicals should be stored according to their reactivity and other properties. For example, acids and bases are incompatible and should be stored separately, whereas sodium and potassium can be kept together as they are both water-reactive but do not have any added hazard when placed with one another. [2] The United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) is an international system created by the United Nations to classify chemicals. [3] The Safety Data Sheet (SDS) or Material Safety Data sheet (MSDS) identifies and classifies the properties and hazards of chemicals. [3]

Unnecessary storage of large amounts of chemicals can pose a hazard if the amount exceeds the limits permitted by laboratory guidelines, and is avoided by accredited workplaces and laboratories. Chemicals are usually stored in cool areas, away from direct heat sources, moisture, or light and should be regularly checked for degradation or damage.

Types of facilities

Flammable cabinet The solvent flammable cabinet.png
Flammable cabinet

Due to chemicals' varying properties, many types of facilities are needed. Chemical storage facilities must be adequately maintained to prevent and mitigate their hazards. Accidental spillage or mixing of chemicals can be hazardous.

Shelving

Shelving must be stable, constructed of a material that is compatible with the chemicals stored on it, and not loaded beyond its rated capacity. [4] It is recommended not to store heavy containers on the highest shelves. Storing chemicals under a sink is not recommended, with the exception of compatible cleaning agents and non-hazardous chemicals.

Cabinetry

Chemical storage cabinets are usually suited for specific classes of chemicals. Acid cabinets, for example, consist of corrosion-resistant materials and sealing to prevent the leakage of fumes. Some institutions recommend a tray to contain any spillage and regular checks for any sign of corrosion. Flammable solvent cabinets are produced from specialized wood or metal able to resist fire for at least 30 minutes. [5] For example, a flammable liquid is any liquid that has a flash point lower than 93 °C (199 °F). Corrosive storage cabinets are designed for storing corrosive or oxidizing liquids. They contain a single-piece, leak-proof floor pan to contain spills, must be vented to the fume hood or the lab exhaust system, and their interior is constructed of corrosive-resistant materials. Wooden cabinets provide excellent strength for storing corrosives. Their laminate finish offers a high level of chemical durability.

Desiccation

Desiccation is a chemical storage technique used to maintain or to regulate humidity, usually to store moisture-sensitive chemicals. Desiccation is generally performed with a desiccator. Several types of desiccators are available, including standard, automatic, gas purge and vacuum desiccators.

Cold storage

Refrigerators and freezers can be used to store flammable and hazardous chemicals. In most situations, specialized laboratory refrigerators are used to ensure that the flash points of certain chemicals are not reached. For flammable chemicals, explosion-proof equipment must be used because conventional refrigerators have sources of ignition. [6]

Maintenance

Maintaining the proper condition of chemical storage areas reduces the likelihood of accidents or injuries in the workplace. For example, work areas should always be kept neat and clean and regularly inspected for any hazards such as improperly cleaned residue.

Related Research Articles

Chemical waste

Chemical waste is a waste that is made from harmful chemicals. Chemical waste may fall under regulations such as COSHH in the United Kingdom, or the Clean Water Act and Resource Conservation and Recovery Act in the United States. In the U.S., the Environmental Protection Agency (EPA) and the Occupational Safety and Health Administration (OSHA), as well as state and local regulations also regulate chemical use and disposal. Chemical waste may or may not be classed as hazardous waste.

Safety data sheet System for cataloging information, potential hazards and instructions for safe use associated with a material or product

A safety data sheet (SDS), material safety data sheet (MSDS), or product safety data sheet (PSDS) is a document that lists information relating to occupational safety and health for the use of various substances and products. SDSs are a widely used system for cataloguing information on chemicals, chemical compounds, and chemical mixtures. SDS information may include instructions for the safe use and potential hazards associated with a particular material or product, along with spill-handling procedures. The older MSDS formats could vary from source to source within a country depending on national requirements; however, the newer SDS format is internationally standardized.

Hazard symbol

Hazard symbols or warning symbols are recognisable symbols designed to warn about hazardous or dangerous materials, locations, or objects, including electric currents, poisons, and radioactivity. The use of hazard symbols is often regulated by law and directed by standards organizations. Hazard symbols may appear with different colors, backgrounds, borders, and supplemental information in order to specify the type of hazard and the level of threat. Warning symbols are used in many places in lieu of or addition to written warnings as they are quickly recognized and more commonly understood.

Fire safety Practices to reduce the results of fire

Fire safety is the set of practices intended to reduce the destruction caused by fire. Fire safety measures include those that are intended to prevent ignition of an uncontrolled fire, and those that are used to limit the development and effects of a fire after it starts.

"NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response" is a standard maintained by the U.S.-based National Fire Protection Association. First "tentatively adopted as a guide" in 1960, and revised several times since then, it defines the colloquial "Safety Square" or "Fire Diamond" used by emergency personnel to quickly and easily identify the risks posed by hazardous materials. This helps determine what, if any, special equipment should be used, procedures followed, or precautions taken during the initial stages of an emergency response.

Chemical hazard Non-biological substance that has the potential to cause harm to life or health

A chemical hazard is a (non-biological) substance that has the potential to cause harm to life or health. Chemicals are widely used in the home and in many other places. Exposure to chemicals can cause acute or long-term detrimental health effects. There are many types of hazardous chemicals, including neurotoxins, immune agents, dermatologic agents, carcinogens, reproductive toxins, systemic toxins, asthmagens, pneumoconiotic agents, and sensitizers. In the workplace, exposure to chemical hazards is a type of occupational hazard. The use of protective personal equipment(PPE) may substantially reduce the risk of damage from contact with hazardous materials.

Gas cylinder Cylindrical container for storing pressurised gas

A gas cylinder is a pressure vessel for storage and containment of gases at above atmospheric pressure. High-pressure gas cylinders are also called bottles. Inside the cylinder the stored contents may be in a state of compressed gas, vapor over liquid, supercritical fluid, or dissolved in a substrate material, depending on the physical characteristics of the contents. A typical gas cylinder design is elongated, standing upright on a flattened bottom end, with the valve and fitting at the top for connecting to the receiving apparatus.

Process safety management

Process safety managementsystem is a regulation promulgated by the U.S. Occupational Safety and Health Administration (OSHA). A process is any activity or combination of activities including any use, storage, manufacturing, handling or the on-site movement of highly hazardous chemicals (HHCs) as defined by OSHA and the Environmental Protection Agency.

Dangerous goods Solids, liquids, or gases harmful to people, other organisms, property or the environment

Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials.

Workplace Hazardous Materials Information System

The Workplace Hazardous Materials Information System is Canada's national workplace hazard communication standard. The key elements of the system, which came into effect on October 31, 1988, are cautionary labelling of containers of WHMIS controlled products, the provision of material safety data sheets (MSDSs) and worker education and site-specific training programs.

Electrical equipment in hazardous areas Electrical equipment in places where fire or explosion hazards may exist

In electrical and safety engineering, hazardous locations are places where fire or explosion hazards may exist. Sources of such hazards include gases, vapors, dust, fibers, and flyings, which are combustible or flammable. Electrical equipment installed in such locations could provide an ignition source, due to electrical arcing, or high temperature. Standards and regulations exist to identify such locations, classify the hazards, and design equipment for safe use in such locations.

Globally Harmonized System of Classification and Labelling of Chemicals

The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Core elements of the GHS include standardized hazard testing criteria, universal warning pictograms, and harmonized safety data sheets which provide users of dangerous goods with a host of information. The system acts as a complement to the UN Numbered system of regulated hazardous material transport. Implementation is managed through the UN Secretariat. Although adoption has taken time, as of 2017, the system has been enacted to significant extents in most major countries of the world. This includes the European Union, which has implemented the United Nations' GHS into EU law as the CLP Regulation, and United States Occupational Safety and Health Administration standards.

Hazardous Materials Identification System Numerical hazard rating using colour coded labels

The Hazardous Materials Identification System (HMIS) is a numerical hazard rating that incorporates the use of labels with color developed by the American Coatings Association as a compliance aid for the OSHA Hazard Communication (HazCom) Standard.

Combustibility and flammability Ability to easily ignite in air at ambient temperatures

A combustible material is something that can combust (burn) in air. Flammable materials are combustible materials that ignite easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.

Hazard statements form part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). They are intended to form a set of standardized phrases about the hazards of chemical substances and mixtures that can be translated into different languages. As such, they serve the same purpose as the well-known R-phrases, which they are intended to replace.

The safe handling of carcinogens is the handling of cancer causing substances in a safe and responsible manner. Carcinogens are defined as 'a substance or agent that can cause cells to become cancerous by altering their genetic structure so that they multiply continuously and become malignant'. The Australian NOHSC Definitions divides carcinogens into three categories. Category 1 carcinogens are substances known to be carcinogenic to humans. Category 2 carcinogens are substances that should be regarded as if they were carcinogenic to humans. Category 3 carcinogens are defined as substances that have possible carcinogenic effects in humans but about which there is insufficient information to make an assessment. Substances are most often categorised as category 1 carcinogens by epidemiological data and as category 2 or 3 carcinogens through the results of animal testing. Mixtures containing more than 0.1% of a category 1 or 2 carcinogen or more than 1% of a category 3 carcinogen must also be considered carcinogenic and be appropriately labelled. Many carcinogens are used in industry and everyday life, making the safe handling of carcinogens an important consideration.

Many laboratories contain significant risks, and the prevention of laboratory accidents requires great care and constant vigilance. Examples of risk factors include high voltages, high and low pressures and temperatures, corrosive and toxic chemicals and chemical vapours, radiation, fire, explosions, and biohazards including infective organisms and their toxins.

Engineering controls are strategies designed to protect workers from hazardous conditions by placing a barrier between the worker and the hazard or by removing a hazardous substance through air ventilation. Engineering controls involve a physical change to the workplace itself, rather than relying on workers' behavior or requiring workers to wear protective clothing.

Chemicals as elements, compounds, mixtures, solutions and emulsions are very widely used and transported in the modern industrial society. Of necessity, they are also used in schools, Universities and other training facilities to educate pupils in their safe use and handling and also are commonly used in domestic situations for cleaning, garden maintenance and DIY.

Safety cabinet

A safety cabinet is used for the safe storage of flammable chemical substance or compressed gas cylinders.

References

  1. "Safe Storage of Hazardous Chemicals in Stockrooms, Workshops and Laboratories" (PDF). Archived from the original (PDF) on 2017-08-29.
  2. "STORING CHEMICALS IN THE LABORATORY". chemistry.umeche.maine.edu. Archived from the original on 2018-04-09. Retrieved 2018-02-23.
  3. 1 2 Chemical Inspection & Regulation Service. "The UN Globally Harmonized System of Classification and Labeling of Chemicals (GHS)" . Retrieved 22 February 2018.
  4. "Chemical storage".
  5. "Guidance on Safe Storage of Chemicals in Laboratories" (PDF).
  6. Occupational Health and Safety Service. "Safe storage of hazardous chemicals in stockrooms, workshops and laboratories" (PDF). Safety Office. University of Cambridge. Archived from the original (PDF) on 29 August 2017. Retrieved 22 February 2018.