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Chromogenic photography is photography that works by a chromogen forming a conventional silver image and then replacing it with a dye image. Most films and papers used for color photography today are chromogenic, using three layers, each providing their own subtractive color. Some chromogenic films provide black-and-white negatives, and are processed in standard color developers (such as the C-41 process). In this case, the dyes are a neutral color.
Chromogenic film or paper contains one or many layers of silver halide (AgX) emulsion, along with dye couplers that, in combination with processing chemistry, form visible dyes. In processing, the silver image of each layer is first developed. In concert with the dye couplers in each layer, the process subsequently forms dyes only in those areas where silver is present.
In full-color chromogenic materials, multiple layers of emulsion are sensitized to different wavelengths of light. Three layers are usually present, generally sensitive to red, green, and blue colored light. Cyan-colored dye is formed on the red-sensitive layer, magenta-colored dye is formed on the green-sensitive layer, and yellow-colored dye is formed on the blue-sensitive layer, following generally the CMY color model.
Some chromogenic black-and-white negative films also exist, mainly to exploit the wide availability of C-41 processing. These films have softer grain and less contrast than traditional silver halide films. In these films, a single emulsion layer has panchromatic sensitivity. The dye image is typically slightly blue because of the choice of dye couplers. Examples of black-and-white chromogenic negative films are Ilford XP2 Super and Fujifilm Neopan 400CN, produced in partnership with Ilford. Kodak have ceased production of their Kodak BW400CN film.
It is also possible to develop a standard black and white silver gelatine film or print using specially formulated chromogenic developers so that a colored dye image only remains after processing, the silver image being totally or partially bleached away during processing. [1]
Each microscopic point of chromogenic dye formation is called a dye cloud. After the formation of dyes is complete, the silver image is removed in processing by a specialty photographic fixer called bleach fix or blix. A processing variation called skip bleach , most popular in motion picture negative processing, leaves the silver image partially or completely intact, yielding a type of contrast enhancement.
The most common chromogenic processes are C-41 for color (and chromogenic black-and-white) negative film, RA-4 for color negative paper (see Type C print), and E-6 for slide film.
A great deal of research effort has been placed by manufacturers, most notably Fujifilm, Ilford Photo, and Kodak, into controlling the color and tonal characteristics of their chromogenic film and paper. The sensitization of the silver halide emulsions, the composition and mixture of the dye couplers, and the chemical interactions of layers upon one another during processing (called interlayer effects), are the subjects of numerous patents. Fujifilm is apparently unique in its use of a fourth (cyan-sensitive) color layer in certain of its negative films.
Like the traditional silver halide process, the main hazardous waste product of chromogenic processing consists of silver compounds dissolved in the used fixer. This waste is usually processed to recover the valuable dissolved silver in metallic form, and to allow safe disposal of the remaining substance. A history of improper handling of waste fixer has led to environmental contamination. For example, the disposal of untreated waste fixer into the sanitary sewers and storm drains of New York City has led to high levels of dissolved silver in the Hudson River.
Film stock is an analog medium that is used for recording motion pictures or animation. It is recorded on by a movie camera, developed, edited, and projected onto a screen using a movie projector. It is a strip or sheet of transparent plastic film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast and resolution of the film. The emulsion will gradually darken if left exposed to light, but the process is too slow and incomplete to be of any practical use. Instead, a very short exposure to the image formed by a camera lens is used to produce only a very slight chemical change, proportional to the amount of light absorbed by each crystal. This creates an invisible latent image in the emulsion, which can be chemically developed into a visible photograph. In addition to visible light, all films are sensitive to X-rays and high-energy particles. Most are at least slightly sensitive to invisible ultraviolet (UV) light. Some special-purpose films are sensitive into the infrared (IR) region of the spectrum.
The Land Camera is a model of self-developing film camera manufactured by Polaroid between 1948 and 1983. It is named after their inventor, Edwin Land, who developed a process for self-developing photography between 1943 and 1947. After Edwin Land's retirement from Polaroid, the name 'Land' was dropped from the camera name. The first commercially available model was the Model 95, which produced sepia-colored prints in about 1 minute. It was first sold to the public on November 26, 1948.
Photographic processing or photographic development is the chemical means by which photographic film or paper is treated after photographic exposure to produce a negative or positive image. Photographic processing transforms the latent image into a visible image, makes this permanent and renders it insensitive to light.
Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on Silver halide but other alternatives have also been used.
In photography, reversal film or slide film is a type of photographic film that produces a positive image on a transparent base. Instead of negatives and prints, reversal film is processed to produce transparencies or diapositives (abbreviated as "diafilm" in many countries). Reversal film is produced in various sizes, from 35 mm to roll film to 8×10 inch sheet film.
The E-6 process is a chromogenic photographic process for developing Ektachrome, Fujichrome and other color reversal photographic film.
In the processing of photographic films, plates or papers, the photographic developer is one or more chemicals that convert the latent image to a visible image. Developing agents achieve this conversion by reducing the silver halides, which are pale-colored, into silver metal, which is black. The conversion occurs within the gelatine matrix. The special feature of photography is that the developer acts more quickly on those particles of silver halides that have been exposed to light. Paper left in developer will eventually reduce all the silver halides and turn black. Generally, the longer a developer is allowed to work, the darker the image.
Color photography is photography that uses media capable of capturing and reproducing colors. By contrast, black-and-white (monochrome) photography records only a single channel of luminance (brightness) and uses media capable only of showing shades of gray.
The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. This was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.
Photographic printing is the process of producing a final image on paper for viewing, using chemically sensitized paper. The paper is exposed to a photographic negative, a positive transparency , or a digital image file projected using an enlarger or digital exposure unit such as a LightJet printer. Alternatively, the negative or transparency may be placed atop the paper and directly exposed, creating a contact print. Digital photographs are commonly printed on plain paper, for example by a color printer, but this is not considered "photographic printing".
C-41 is a chromogenic color print film developing process introduced by Kodak in 1972, superseding the C-22 process. C-41, also known as CN-16 by Fuji, CNK-4 by Konica, and AP-70 by AGFA, is the most popular film process in use, with most photofinishing labs devoting at least one machine to this development process.
Instant film is a type of photographic film that was introduced by Polaroid Corporation to produce a visible image within minutes or seconds of the photograph's exposure. The film contains the chemicals needed for developing and fixing the photograph, and the camera exposes and initiates the developing process after a photo has been taken.
Leopold Godowsky Jr. was an American violinist and chemist, who together with Leopold Mannes created the first practical color transparency film, Kodachrome.
Tabular-grain film is a type of photographic film that includes nearly all color films, T-MAX films from Kodak, Delta films from Ilford Photo and the Fujifilm Neopan films. The silver halide crystals in the film emulsion are flatter and more tabular.
A chromogenic print, also known as a C-print or C-type print, a silver halide print, or a dye coupler print, is a photographic print made from a color negative, transparency or digital image, and developed using a chromogenic process. They are composed of three layers of gelatin, each containing an emulsion of silver halide, which is used as a light-sensitive material, and a different dye coupler of subtractive color which together, when developed, form a full-color image.
Color motion picture film refers both to unexposed color photographic film in a format suitable for use in a motion picture camera, and to finished motion picture film, ready for use in a projector, which bears images in color.
K-14 was the most recent version of the developing process for Kodak's Kodachrome transparency film before its discontinuation. It superseded previous versions of the Kodachrome process used with older films.
Leopold Damrosch Mannes was an American musician, who, together with Leopold Godowsky Jr., created the first practical color transparency film, Kodachrome.
Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric.
Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and resolution of the film.