A climbing/falling film plate evaporator is a specialized type of evaporator in which a thin film of liquid is passed over a rising and falling plate to allow the evaporation process to occur. It is an extension of the falling film evaporator, and has application in any field where the liquid to be evaporated cannot withstand extended exposure to high temperatures, such as the concentration of fruit juices.
The basic design of the climbing/falling film plate evaporator consists of two phases. In the climbing phase, the liquid feed is heated by a flow of steam as it rises through a corrugated plate. In the subsequent falling phase, the liquid flows downward at high velocity under gravitational force. Evaporation and cooling occurs rapidly in the falling phase.
There are several design variations that are commonly used in industrial field. These include single-effect and multiple-effect evaporators. The choice of evaporator design is dictated by constraints of the process. Fundamentally, there are four factors involved in designing this evaporator:
The main advantage of climbing/falling film plate evaporator is its short residence time. Since the liquid feed does not remain in the evaporator for long, this evaporator is suitable for heat/temperature sensitive material. Thus, this evaporator is used widely in food, beverages and pharmaceutical industries. Besides that, the colour, texture, nutritional content and taste of the liquid feed can be preserved too. Despite its functionality, this evaporator has a few drawbacks such as large energy consumption. Future development compromises installing large number of steam effects and recycle the steam where possible for better energy efficiency.
Climbing/falling film plate evaporator designs can be group into single-effect and multiple-effect film plate designs. [1]
The operations for single-effect evaporator can be carried out in a batch, semi-batch, or continuous- batch or continuously. Single-effect evaporators are indicated in any of the following conditions:
Thermocompression is useful whenever evaporator energy requirements need to be reduced. This could be achieved by compressing and recycling the vapor from a single-effects evaporator into the same evaporator as the heating medium. Thermocompression of vapor can be achieved by applying the steam-jet or by using mechanical means such as compressors
The best way to reduce energy consumption is by using multiple-effect evaporators. For multiple-effect evaporators, the steam from outside is condensed by the heating element of the first effect and the vapors produced from the first effect are then recycled back to the second effect, where the feed will be partially concentrated product of the first effect. The process expands until the last effect when the final desired concentration is achieved. [1] [2]
There are several process characteristics that should be taken into account in order for the evaporator to operate at its best performance.
Evaporation of liquid film in film evaporators is very important in order to cool the flowing liquid and the surface on which the liquid flows. It can also increase the concentration of the components in the liquid. The climbing/falling film plate evaporator is specifically designed to produce a thin film during both the climbing and falling phases. [3] For the climbing film evaporators, the feed is introduced at the bottom of the tubes. Evaporation causes the vapor to expand thus causing a thin film of liquid to rise along the tubes. The vapor shear will push the thin film to climb up the wall of the tubes. The feed for the falling film evaporator on the other hand is introduced at the top of the tubes. The liquid flows down the tubes and it will get evaporated as it descends. [3] The flow of the liquid down the tubes is driven by the vapor shear stress and the gravitational forces. The effect of the vapor shear and the gravity will lead to a higher flow rates and shorter residence time. The flow of the thin liquid film in the falling film evaporator is possible in two ways: cocurrent and countercurrent. [4] It is cocurrent if the vapor is drawn from the top to the bottom of the tubes and vice versa for the countercurrent flow. The cocurrent flow will increase the flow rates resulting in a shorter residence time. [4] The type of flow can be described in figure 2.
The heat transfer performance of the climbing and falling film plate evaporator is affected by several factors, including the height of the feed inside the tube and the temperature difference. The height of the feed water is inversely related to the climbing film height. [5] The low height of feed water will lead to the high height of climbing film. Higher height of the climbing film will increase the percentage of saturated flow boiling region therefore it will lead to an increase in the local heat transfer coefficient. The optimum height ratio of feed water is found to be Rh = 0.3. [5] Any height ratio less than 0.3 will cause the local heat transfer coefficient to decrease. Besides that, small liquid content in the tube can minimize the foaming problem.
The combination of climbing and falling film evaporator allows the evaporator to operate within a wide temperature range. The evaporators can operate in a small temperature difference between the heating medium and the liquid. This is due to the lack of hydrostatic pressure drop in the evaporator. The lack of hydrostatic pressure drop will eliminate the temperature drop thus causing the temperature to be relatively uniform. [4] Besides that, the local heat transfer coefficient inside the tube is depending on the change in temperature. A minimum threshold of change in temperature (ΔT) of 5 °C was found by Luopeng Yang in one of his experiments. [5] If the change in temperature is less than 5 °C, the liquid film will not be able to travel up the tubes which resulting in a drop of local heat transfer coefficient in the tube.
Since the evaporator is mainly used in processes dealing with heat-sensitive materials, the residence time should be kept as low as possible. [6] Residence time is the time taken for the product to be in contact with heat. To improve the product quality, short heat contact period from single pass operation can minimize product deterioration. The climbing and falling film plate evaporator is capable of satisfying this requirement. Short residence time can be achieved by higher liquid flow rates down the tube in the falling film evaporator. [4] The effect of gravitational force will increase the flow rate of the liquid resulting in the short residence time.
In designing a film plate evaporator, the use of superheated liquid needs to be controlled in order to prevent nucleate boiling. Nucleate boiling will cause product deterioration resulting from increases in chemical reaction rates that come from the raise in temperature. Nucleate boiling will cause fouling to occur, thus affecting the rate of heat transfer of the process. In order to avoid nucleate boiling, the liquid superheat should be in the range of 3 to 40 K depending on the liquid used. [4]
Minimizing residence time is important in order to minimize the occurrence of chemical reactions between the feed and the evaporator materials, thus reducing fouling within the evaporator. This guideline is especially important in the food processing industry, where purity of output product is paramount. [4] In this application, residence time bears directly on product quality, thus it is important for the climbing and falling film plate evaporator to have low residence time. [7]
This section may be confusing or unclear to readers.(October 2013) |
Condensate is the waste that had been discharged through waste stream in climbing and falling-film evaporator. This evaporator will discharge vapor as the condensate as vapor pass through more rapidly than the liquid flows in the tube.
In each evaporation unit, the feed enter from the bottom of tubesheet of pass through the climbing and falling film segment. When the liquid rises throughout the tube, boiling and vaporization process occurred as it is contact with the steam heated plates. Then the mixture that contains liquid and vapour are discharged and it is reallocated at the top of falling film pass tubes. The vapour that produced by climbing film is used to increase the velocity of liquid in the distribution liquid tubes in order to rise up the heat transfer. External separator is used to separate the mixture of both liquid and water that produced at the down-flow.
This section may be confusing or unclear to readers.(October 2013) |
In a multi-effect evaporator, the vapor output of one phase of the evaporator is recycled as the heating medium for the next phase, reducing the overall consumption of steam for the evaporator.
A surface condenser is used to condense the vapor that produced in the second effect process. In order to recover the heat that had been used in this evaporator, both of the vapor condensate is pumped to the pre-heater feed so that it can produce heat to this process. [7] [8] [9]
Climbing/falling film plate evaporators are used in a range of applications:
Fruit juices are condensed by evaporation for storage, transport and commercial use. [10] If fruit juices are exposed to heat, the nutrient content such as vitamin C may be affected. [11] Furthermore, these nutrients are easily oxidized at high temperature. The evaporator can overcome this constraint as it operates at high feed flow rate and small temperature difference. In addition, the change in color and texture of the juices can be prevented via the operation of this evaporator type.
Other protein-rich products such as whey powder in dietary supplement and milk (including both skim and whole milk) are concentrated to remove most liquid components for further processes. [12] Protein is easily denatured at high temperature because its tertiary structure is degraded upon exposure to heat. Evaporation via climbing and falling film plate design can minimize the effect of protein denaturation and thus, optimizing the product quality.
Instant and concentrated cooking ingredients such as pasta sauce, chicken broth, vegetable purees etc. undergo evaporation through the same evaporating equipment. Although they are relatively less sensitive to heat, evaporating them at low temperature and short residence time is crucial to maintain the quality taste, texture appearance and nutritional value. [13]
Antibiotics, supplementary pills and drugs containing organic and inorganic compounds are evaporated to remove as much moisture as possible for crystallization. This is because in crystallized form, antibiotics and enzyme compounds will be well preserved and improved in stability. [14] Moreover, exposure to high temperature will lead to decomposition of inorganic compounds. Although most pharmaceutical products are extremely sensitive in temperature, this type of evaporator is still practical to be used since several design of this evaporators are able to operate at low pressure since the boiling point of water is low as pressure decreases.
There are few limitations of this evaporator that makes it not applicable for all range of industrial processes. The evaporator needs to be operated within the range of 26–100 °C and is able to remove water in a range of 450–16,000 kg/h. In order to provide the proper rising/falling characteristics, most evaporators are quite tall and can only be installed in a space that is 4 metres (13 ft) high. The suspended solid in the liquid feed need to be low and can pass through 50 mesh screen.
There are several problems related to climbing and falling film plate evaporators. One of them is the energy intensive system. In order to improve the productivity of the plant, the energy consumption needs to be reduced with the intention of reducing the use of steam. New strategies had been proposed by investigator to reduce the utilization of steam to improve the system of economic steam. The examples of operating strategies are flashing of feed, product and condensate, splitting of feed and steam and use of optimum feed flow series. [9]
Several techniques have been suggested to minimize energy consumption: [8]
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heating of solid materials to produce gaseous products ; this may involve chemical changes such as destructive distillation or cracking. Distillation may result in essentially complete separation, or it may be a partial separation that increases the concentration of selected components; in either case, the process exploits differences in the relative volatility of the mixture's components. In industrial applications, distillation is a unit operation of practically universal importance, but is a physical separation process, not a chemical reaction. An installation used for distillation, especially of distilled beverages, is a distillery. Distillation includes the following applications:
Boiling is the rapid phase transition from liquid to gas or vapor; the reverse of boiling is condensation. Boiling occurs when a liquid is heated to its boiling point, so that the vapour pressure of the liquid is equal to the pressure exerted on the liquid by the surrounding atmosphere. Boiling and evaporation are the two main forms of liquid vapourization.
The Leidenfrost effect is a physical phenomenon in which a liquid, close to a surface that is significantly hotter than the liquid's boiling point, produces an insulating vapor layer that keeps the liquid from boiling rapidly. Because of this repulsive force, a droplet hovers over the surface, rather than making physical contact with it. The effect is named after the German doctor Johann Gottlob Leidenfrost, who described it in A Tract About Some Qualities of Common Water.
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.
A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.
A chiller is a machine that removes heat from a liquid coolant via a vapor-compression, adsorption refrigeration, or absorption refrigeration cycles. This liquid can then be circulated through a heat exchanger to cool equipment, or another process stream. As a necessary by-product, refrigeration creates waste heat that must be exhausted to ambience, or for greater efficiency, recovered for heating purposes. Vapor compression chillers may use any of a number of different types of compressors. Most common today are the hermetic scroll, semi-hermetic screw, or centrifugal compressors. The condensing side of the chiller can be either air or water cooled. Even when liquid cooled, the chiller is often cooled by an induced or forced draft cooling tower. Absorption and adsorption chillers require a heat source to function.
Vacuum distillation or Distillation under reduced pressure is a type of distillation performed under reduced pressure, which allows the purification of compounds not readily distilled at ambient pressures or simply to save time or energy. This technique separates compounds based on differences in their boiling points. This technique is used when the boiling point of the desired compound is difficult to achieve or will cause the compound to decompose. Reduced pressures decrease the boiling point of compounds. The reduction in boiling point can be calculated using a temperature-pressure nomograph using the Clausius–Clapeyron relation.
In chemical engineering, a multiple-effect evaporator is an apparatus for efficiently using the heat from steam to evaporate water. Water is boiled in a sequence of vessels, each held at a lower pressure than the last. Because the boiling temperature of water decreases as pressure decreases, the vapor boiled off in one vessel can be used to heat the next, and only the first vessel requires an external source of heat. The multiple-effect evaporator was invented by the American engineer Norbert Rillieux. Although he may have designed the apparatus during the 1820s and constructed a prototype in 1834, he did not build the first industrially practical evaporator until 1845. Originally designed for concentrating sugar in sugar cane juice, it has since become widely used in all industrial applications where large volumes of water must be evaporated, such as salt production and water desalination.
A falling film evaporator is an industrial device to concentrate solutions, especially with heat sensitive components. The evaporator is a special type of heat exchanger.
Multi-stage flash distillation (MSF) is a water desalination process that distills sea water by flashing a portion of the water into steam in multiple stages of what are essentially countercurrent heat exchangers. Current MSF facilities may have as many as 30 stages.
A shell-and-tube heat exchanger is a class of heat exchanger designs. It is the most common type of heat exchanger in oil refineries and other large chemical processes, and is suited for higher-pressure applications. As its name implies, this type of heat exchanger consists of a shell with a bundle of tubes inside it. One fluid runs through the tubes, and another fluid flows over the tubes to transfer heat between the two fluids. The set of tubes is called a tube bundle, and may be composed of several types of tubes: plain, longitudinally finned, etc.
Continuous distillation, a form of distillation, is an ongoing separation in which a mixture is continuously fed into the process and separated fractions are removed continuously as output streams. Distillation is the separation or partial separation of a liquid feed mixture into components or fractions by selective boiling and condensation. The process produces at least two output fractions. These fractions include at least one volatile distillate fraction, which has boiled and been separately captured as a vapor condensed to a liquid, and practically always a bottoms fraction, which is the least volatile residue that has not been separately captured as a condensed vapor.
Vacuum evaporation is the process of causing the pressure in a liquid-filled container to be reduced below the vapor pressure of the liquid, causing the liquid to evaporate at a lower temperature than normal. Although the process can be applied to any type of liquid at any vapor pressure, it is generally used to describe the boiling of water by lowering the container's internal pressure below standard atmospheric pressure and causing the water to boil at room temperature.
Economizers, or economisers (UK), are mechanical devices intended to reduce energy consumption, or to perform useful function such as preheating a fluid. The term economizer is used for other purposes as well. Boiler, power plant, heating, refrigeration, ventilating, and air conditioning (HVAC) uses are discussed in this article. In simple terms, an economizer is a heat exchanger.
Vapor-compression evaporation is the evaporation method by which a blower, compressor or jet ejector is used to compress, and thus, increase the pressure of the vapor produced. Since the pressure increase of the vapor also generates an increase in the condensation temperature, the same vapor can serve as the heating medium for its "mother" liquid or solution being concentrated, from which the vapor was generated to begin with. If no compression was provided, the vapor would be at the same temperature as the boiling liquid/solution, and no heat transfer could take place.
An evaporator is a type of heat exchanger device that facilitates evaporation by utilizing conductive and convective heat transfer to provide the necessary thermal energy for phase transition from liquid to vapor. Within evaporators, a circulating liquid is exposed to an atmospheric or reduced pressure environment, causing it to boil at a lower temperature compared to normal atmospheric boiling.
In fluid thermodynamics, nucleate boiling is a type of boiling that takes place when the surface temperature is hotter than the saturated fluid temperature by a certain amount but where the heat flux is below the critical heat flux. For water, as shown in the graph below, nucleate boiling occurs when the surface temperature is higher than the saturation temperature by between 10 and 30 °C. The critical heat flux is the peak on the curve between nucleate boiling and transition boiling. The heat transfer from surface to liquid is greater than that in film boiling.
Circulation evaporators are a type of evaporating unit designed to separate mixtures unable to be evaporated by a conventional evaporating unit. Circulation evaporation incorporates the use of both heat exchangers and flash separation units in conjunction with circulation of the solvent in order to remove liquid mixtures without conventional boiling. There are two types of Circulation Evaporation; Natural Circulation Evaporators and Forced Circulation Evaporators, both of which are still currently used in industry today, although forced Circulation systems, which have a circulation pump as opposed to natural systems with no driving force, have a much wider range of appropriate uses.
A rising film or vertical long tube evaporator is a type of evaporator that is essentially a vertical shell and tube heat exchanger. The liquid being evaporated is fed from the bottom into long tubes and heated with steam condensing on the outside of the tube from the shell side. This is to produce steam and vapour within the tube bringing the liquid inside to a boil. The vapour produced then presses the liquid against the walls of the tubes and causes the ascending force of this liquid. As more vapour is formed, the centre of the tube will have a higher velocity which forces the remaining liquid against the tube wall forming a thin film which moves upwards. This phenomenon of the rising film gives the evaporator its name.
Polymer devolatilization, also known as polymer degassing, is the process of removing low-molecular-weight components such as residual monomers, solvents, reaction by-products and water from polymers.