Vapor pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the attractive interactions between liquid molecules become less significant in comparison to the entropy of those molecules in the gas phase, increasing the vapor pressure. Thus, liquids with strong intermolecular interactions are likely to have smaller vapor pressures, with the reverse true for weaker interactions.
Boiling or ebullition is the rapid phase transition from liquid to gas or vapor; the reverse of boiling is condensation. Boiling occurs when a liquid is heated to its boiling point, so that the vapour pressure of the liquid is equal to the pressure exerted on the liquid by the surrounding atmosphere. Boiling and evaporation are the two main forms of liquid vapourization.
In thermal fluid dynamics, the Nusselt number is the ratio of convective to conductive heat transfer at a boundary in a fluid. Convection includes both advection and diffusion (conduction). The conductive component is measured under the same conditions as the convective but for a hypothetically motionless fluid. It is a dimensionless number, closely related to the fluid's Rayleigh number.
In fluid mechanics, the Grashof number is a dimensionless number which approximates the ratio of the buoyancy to viscous forces acting on a fluid. It frequently arises in the study of situations involving natural convection and is analogous to the Reynolds number.
In fluid mechanics, the Rayleigh number (Ra, after Lord Rayleigh) for a fluid is a dimensionless number associated with buoyancy-driven flow, also known as free (or natural) convection. It characterises the fluid's flow regime: a value in a certain lower range denotes laminar flow; a value in a higher range, turbulent flow. Below a certain critical value, there is no fluid motion and heat transfer is by conduction rather than convection. For most engineering purposes, the Rayleigh number is large, somewhere around 106 to 108.
The Leidenfrost effect is a physical phenomenon in which a liquid, close to a surface that is significantly hotter than the liquid's boiling point, produces an insulating vapor layer that keeps the liquid from boiling rapidly. Because of this repulsive force, a droplet hovers over the surface, rather than making physical contact with it. The effect is named after the German doctor Johann Gottlob Leidenfrost, who described it in A Tract About Some Qualities of Common Water.
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects to float on a water surface without becoming even partly submerged.
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.
A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.
In thermodynamics, the heat transfer coefficient or film coefficient, or film effectiveness, is the proportionality constant between the heat flux and the thermodynamic driving force for the flow of heat. It is used in calculating the heat transfer, typically by convection or phase transition between a fluid and a solid. The heat transfer coefficient has SI units in watts per square meter per kelvin (W/m²K).
Thermal hydraulics is the study of hydraulic flow in thermal fluids. The area can be mainly divided into three parts: thermodynamics, fluid mechanics, and heat transfer, but they are often closely linked to each other. A common example is steam generation in power plants and the associated energy transfer to mechanical motion and the change of states of the water while undergoing this process. Thermal-hydraulic analysis can determine important parameters for reactor design such as plant efficiency and coolability of the system.
The Marangoni effect is the mass transfer along an interface between two phases due to a gradient of the surface tension. In the case of temperature dependence, this phenomenon may be called thermo-capillary convection.
A zeotropicmixture, or non-azeotropic mixture, is a mixture with liquid components that have different boiling points. For example, nitrogen, methane, ethane, propane, and isobutane constitute a zeotropic mixture. Individual substances within the mixture do not evaporate or condense at the same temperature as one substance. In other words, the mixture has a temperature glide, as the phase change occurs in a temperature range of about four to seven degrees Celsius, rather than at a constant temperature. On temperature-composition graphs, this temperature glide can be seen as the temperature difference between the bubble point and dew point. For zeotropic mixtures, the temperatures on the bubble (boiling) curve are between the individual component's boiling temperatures. When a zeotropic mixture is boiled or condensed, the composition of the liquid and the vapor changes according to the mixtures's temperature-composition diagram.
In the study of heat transfer, critical heat flux (CHF) is the heat flux at which boiling ceases to be an effective form of transferring heat from a solid surface to a liquid.
In fluid mechanics, multiphase flow is the simultaneous flow of materials with two or more thermodynamic phases. Virtually all processing technologies from cavitating pumps and turbines to paper-making and the construction of plastics involve some form of multiphase flow. It is also prevalent in many natural phenomena.
In systems involving heat transfer, a condenser is a heat exchanger used to condense a gaseous substance into a liquid state through cooling. In so doing, the latent heat is released by the substance and transferred to the surrounding environment. Condensers are used for efficient heat rejection in many industrial systems. Condensers can be made according to numerous designs and come in many sizes ranging from rather small (hand-held) to very large. For example, a refrigerator uses a condenser to get rid of heat extracted from the interior of the unit to the outside air.
In engineering, physics, and chemistry, the study of transport phenomena concerns the exchange of mass, energy, charge, momentum and angular momentum between observed and studied systems. While it draws from fields as diverse as continuum mechanics and thermodynamics, it places a heavy emphasis on the commonalities between the topics covered. Mass, momentum, and heat transport all share a very similar mathematical framework, and the parallels between them are exploited in the study of transport phenomena to draw deep mathematical connections that often provide very useful tools in the analysis of one field that are directly derived from the others.
The vaporizing droplet problem is a challenging issue in fluid dynamics. It is part of many engineering situations involving the transport and computation of sprays: fuel injection, spray painting, aerosol spray, flashing releases… In most of these engineering situations there is a relative motion between the droplet and the surrounding gas. The gas flow over the droplet has many features of the gas flow over a rigid sphere: pressure gradient, viscous boundary layer, wake. In addition to these common flow features one can also mention the internal liquid circulation phenomenon driven by surface-shear forces and the boundary layer blowing effect.
A climbing/falling film plate evaporator is a specialized type of evaporator in which a thin film of liquid is passed over a rising and falling plate to allow the evaporation process to occur. It is an extension of the falling film evaporator, and has application in any field where the liquid to be evaporated cannot withstand extended exposure to high temperatures, such as the concentration of fruit juices.
The removal of heat from nuclear reactors is an essential step in the generation of energy from nuclear reactions. In nuclear engineering there are a number of empirical or semi-empirical relations used for quantifying the process of removing heat from a nuclear reactor core so that the reactor operates in the projected temperature interval that depends on the materials used in the construction of the reactor. The effectiveness of removal of heat from the reactor core depends on many factors, including the cooling agents used and the type of reactor. Common liquid coolants for nuclear reactors include: deionized water, heavy water, the lighter alkaline metals, lead or lead-based eutectic alloys like lead-bismuth, and NaK, a eutectic alloy of sodium and potassium. Gas cooled reactors operate with coolants like carbon dioxide, helium or nitrogen but some very low powered research reactors have even been air-cooled with Chicago Pile 1 relying on natural convection of the surrounding air to remove the negligible thermal power output. There is ongoing research into using supercritical fluids as reactor coolants but thus far neither the supercritical water reactor nor a reactor cooled with supercritical Carbon Dioxide nor any other kind of supercritical-fluid-cooled reactor has ever been built.
