Clinker is a generic name given to waste from industrial processes, particularly those that involve smelting metals, welding, burning fossil fuels and use of a blacksmith's forge, which commonly causes a large buildup of clinker around the tuyere. Clinker often forms a loose, dark deposit consisting of waste materials such as coke, coal, slag, charcoal, and grit. Clinker often has a glassy look to it, usually because of the formation of molten silica compounds during processing. Clinker generally is much denser than coke, and, unlike coke, generally contains too little carbon to be of any value as fuel. It is also applied to the byproduct of combustion and heating by those who use anthracite or lignite coal-fired boilers. [1]
Clinkers can occur naturally, for example in underground deposits of coal that has been altered by heat from nearby molten magma; volcanic clinkers are jagged pieces of lava that look similar to industrial clinker. [2]
"Clinker" is from Dutch, and was originally used in English to describe clinker bricks. The term was later applied to hard residue, due to its similar appearance.
Clinker often is reused as a cheap material for paving footpaths. It is laid and rolled, and forms a hard path with a rough surface that presents less risk of slipping than most loose materials. In sufficient thickness such a layer drains well and is valuable for controlling muddiness. However, if laid without sufficient adhesive, it needs frequent rolling and addition of more clinker to maintain the path in good condition if it is subject to heavy foot traffic.
In sewage treatment works, the foul water is first screened to remove floating debris. Then it is sedimented to remove insoluble particles. After this, it is sprayed over a filter bed of clinker. Aerobic microbes soon grow in hollows in the clinker, where they kill harmful anaerobic bacteria in the water and remove much of the offensive organic waste.
Historically, clinker from coal-burning steamships simply was discarded overboard, leaving detectable trails on the seabed of some prominent steamship routes. As such, the deposits have proven to be of biological, historical and archaeological interest. [3]
Naturally occurring clinkers exist. For example, in the Powder River Basin is covered by clinkers from coal-seam fires, i.e., "baked, welded and molded rocks formed by the natural burning of coal beds." [4] [5] [6]
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is a type of fossil fuel, formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous (Pennsylvanian) and Permian times.
Clinker may refer to:
Coke is a grey, hard, and porous coal-based fuel with a high carbon content and few impurities, made by heating coal or oil in the absence of air—a destructive distillation process. It is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges when air pollution is a concern.
Wrought iron is an iron alloy with a very low carbon content in contrast to that of cast iron. It is a semi-fused mass of iron with fibrous slag inclusions, which give it a wood-like "grain" that is visible when it is etched, rusted, or bent to failure. Wrought iron is tough, malleable, ductile, corrosion resistant, and easily forge welded, but is more difficult to weld electrically.
Bituminous coal, or black coal, is a type of coal containing a tar-like substance called bitumen or asphalt. Its coloration can be black or sometimes dark brown; often there are well-defined bands of bright and dull material within the seams. It is typically hard but friable. Its quality is ranked higher than lignite and sub-bituminous coal, but lesser than anthracite. It is the most abundant rank of coal, with deposits found around the world, often in rocks of Carboniferous age. Bituminous coal is formed from sub-bituminous coal that is buried deeply enough to be heated to 85 °C (185 °F) or higher.
Anthracite, also known as hard coal and black coal, is a hard, compact variety of coal that has a submetallic lustre. It has the highest carbon content, the fewest impurities, and the highest energy density of all types of coal and is the highest ranking of coals.
Pyroclastic rocks are clastic rocks composed of rock fragments produced and ejected by explosive volcanic eruptions. The individual rock fragments are known as pyroclasts. Pyroclastic rocks are a type of volcaniclastic deposit, which are deposits made predominantly of volcanic particles. 'Phreatic' pyroclastic deposits are a variety of pyroclastic rock that forms from volcanic steam explosions and they are entirely made of accidental clasts. 'Phreatomagmatic' pyroclastic deposits are formed from explosive interaction of magma with groundwater. The word pyroclastic is derived from the Greek πῦρ, meaning fire; and κλαστός, meaning broken.
Lapilli is a size classification of tephra, which is material that falls out of the air during a volcanic eruption or during some meteorite impacts. Lapilli is Latin for "little stones".
Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels include wood, charcoal, peat, coal, hexamine fuel tablets, dry dung, wood pellets, corn, wheat, rye, and other grains. Solid fuels are extensively used in rocketry as solid propellants. Solid fuels have been used throughout human history to create fire and solid fuel is still in widespread use throughout the world in the present day.
A coal-seam fire is a burning of an outcrop or underground coal seam. Most coal-seam fires exhibit smouldering combustion, particularly underground coal-seam fires, because of limited atmospheric oxygen availability. Coal-seam fire instances on Earth date back several million years. Due to thermal insulation and the avoidance of rain/snow extinguishment by the crust, underground coal-seam fires are the most persistent fires on Earth and can burn for thousands of years, like Burning Mountain in Australia. Coal-seam fires can be ignited by self-heating of low-temperature oxidation, lightning, wildfires and even arson. Coal-seam fires have been slowly shaping the lithosphere and changing atmosphere, but this pace has become faster and more extensive in modern times, triggered by mining.
The Powder River Basin is a geologic structural basin in southeast Montana and northeast Wyoming, about 120 miles (190 km) east to west and 200 miles (320 km) north to south, known for its extensive coal reserves. The former hunting grounds of the Oglala Lakota, the area is very sparsely populated and is known for its rolling grasslands and semiarid climate.
Charring is a chemical process of incomplete combustion of certain solids when subjected to high heat. Heat distillation removes water vapour and volatile organic compounds (syngas) from the matrix. The residual black carbon material is char, as distinguished from the lighter colored ash. By the action of heat, charring removes hydrogen and oxygen from the solid, so that the remaining char is composed primarily of carbon. Polymers like thermoset, or most solid organic compounds like wood or biological tissue, exhibit charring behaviour.
A cyclone furnace is a type of coal combustor commonly used in large industrial boilers.
A fire iron is any metal instrument for tending a fire.
A pulverized coal-fired boiler is an industrial or utility boiler that generates thermal energy by burning pulverized coal that is blown into the firebox.
Bottom ash is part of the non-combustible residue of combustion in a power plant, boiler, furnace or incinerator. In an industrial context, it has traditionally referred to coal combustion and comprises traces of combustibles embedded in forming clinkers and sticking to hot side walls of a coal-burning furnace during its operation. The portion of the ash that escapes up the chimney or stack is, however, referred to as fly ash. The clinkers fall by themselves into the bottom hopper of a coal-burning furnace and are cooled. The above portion of the ash is also referred to as bottom ash.
Cement kilns are used for the pyroprocessing stage of manufacture of portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates. Over a billion tonnes of cement are made per year, and cement kilns are the heart of this production process: their capacity usually defines the capacity of the cement plant. As the main energy-consuming and greenhouse-gas–emitting stage of cement manufacture, improvement of kiln efficiency has been the central concern of cement manufacturing technology. Emissions from cement kilns are a major source of greenhouse gas emissions, accounting for around 2.5% of non-natural carbon emissions worldwide.
The Grootegeluk Coal Mine is an open cast coal mine within the Waterberg Coalfield of the Limpopo province of South Africa. It is operated by Exxaro. The mine is 25 kilometres (16 mi) from Lephalale, and employs 2,000 people.
Pyrometamorphism is a type of metamorphism in which rocks are rapidly changed by heat, e.g. coming from a rapidly emplaced extrusive or intrusive igneous rock or from a fossil fuel fire. The rocks produced by pyrometamorphism include buchite, clinker and paralava, formed due to melting and/or recrystallisation of sedimentary rocks. Both natural and anthropogenic examples of sites with active pyrometamorphism are known. One well-known area of natural pyrometamorphic rocks is the Hatrurim Formation with outcrops all around the Dead Sea Basin: in the Negev Desert in Israel, in the Judaean Desert on the West Bank, and in western Jordan. Xenoliths of sedimentary rocks trapped in volcanic lava may undergo pyrometamorphic transformation, as can some contact wallrocks. Anthropogenic pyrometamorphic rocks are found in burning coal-mining dumps. A great number of minerals, sometimes very rare, are found within these rocks. Of the silicate minerals, the typical ones are especially cordierite, indialite, fayalite, mullite, tridymite and cristobalite, and sekaninaite. Oxide minerals include corundum, hematite, hercynite, magnesioferrite, and magnetite. Some rare minerals typical of meteorites, like oldhamite, are also found in pyrometamorphic rocks.
A coal bin, coal store or coal bunker is a storage container for coal awaiting use or transportation. This can be either in domestic, commercial or industrial premises, or on a ship or locomotive tender, or at a coal mine or processing plant.
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