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Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares the abundance of a naturally occurring radioactive isotope within the material to the abundance of its decay products, which form at a known constant rate of decay. The use of radiometric dating was first published in 1907 by Bertram Boltwood and is now the principal source of information about the absolute age of rocks and other geological features, including the age of fossilized life forms or the age of Earth itself, and can also be used to date a wide range of natural and man-made materials.
The rubidium-strontium dating method (Rb-Sr) is a radiometric dating technique, used by scientists to determine the age of rocks and minerals from their content of specific isotopes of rubidium (87Rb) and strontium. One of the two naturally occurring isotopes of rubidium, 87Rb, decays to 87Sr with a half-life of 49.23 billion years. The radiogenic daughter, 87Sr, produced in this decay process is the only one of the four naturally occurring strontium isotopes that was not produced exclusively by stellar nucleosynthesis predating the formation of the Solar System. Over time, decay of 87Rb increases the amount of radiogenic 87Sr while the amount of other Sr isotopes remains unchanged.
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (BaSO4). Baryte is generally white or colorless, and is the main source of the element barium. The baryte group consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4.
Geochronology is the science of determining the age of rocks, fossils, and sediments using signatures inherent in the rocks themselves. Absolute geochronology can be accomplished through radioactive isotopes, whereas relative geochronology is provided by tools such as paleomagnetism and stable isotope ratios. By combining multiple geochronological indicators the precision of the recovered age can be improved.
Potassium–argon dating, abbreviated K–Ar dating, is a radiometric dating method used in geochronology and archaeology. It is based on measurement of the product of the radioactive decay of an isotope of potassium (K) into argon (Ar). Potassium is a common element found in many materials, such as feldspars, micas, clay minerals, tephra, and evaporites. In these materials, the decay product 40
Ar
is able to escape the liquid (molten) rock but starts to accumulate when the rock solidifies (recrystallizes). The amount of argon sublimation that occurs is a function of the purity of the sample, the composition of the mother material, and a number of other factors. These factors introduce error limits on the upper and lower bounds of dating, so that the final determination of age is reliant on the environmental factors during formation, melting, and exposure to decreased pressure or open air. Time since recrystallization is calculated by measuring the ratio of the amount of 40
Ar
accumulated to the amount of 40
K
remaining. The long half-life of 40
K
allows the method to be used to calculate the absolute age of samples older than a few thousand years.
Argon–argondating is a radiometric dating method invented to supersede potassium–argon (K/Ar) dating in accuracy. The older method required splitting samples into two for separate potassium and argon measurements, while the newer method requires only one rock fragment or mineral grain and uses a single measurement of argon isotopes. 40Ar/39Ar dating relies on neutron irradiation from a nuclear reactor to convert a stable form of potassium (39K) into the radioactive 39Ar. As long as a standard of known age is co-irradiated with unknown samples, it is possible to use a single measurement of argon isotopes to calculate the 40K/40Ar* ratio, and thus to calculate the age of the unknown sample. 40Ar* refers to the radiogenic 40Ar, i.e. the 40Ar produced from radioactive decay of 40K. 40Ar* does not include atmospheric argon adsorbed to the surface or inherited through diffusion and its calculated value is derived from measuring the 36Ar and assuming that 40Ar is found in a constant ratio to 36Ar in atmospheric gases.
Uranium–lead dating, abbreviated U–Pb dating, is one of the oldest and most refined of the radiometric dating schemes. It can be used to date rocks that formed and crystallised from about 1 million years to over 4.5 billion years ago with routine precisions in the 0.1–1 percent range.
Fission track dating is a radiometric dating technique based on analyses of the damage trails, or tracks, left by fission fragments in certain uranium-bearing minerals and glasses. Fission-track dating is a relatively simple method of radiometric dating that has made a significant impact on understanding the thermal history of continental crust, the timing of volcanic events, and the source and age of different archeological artifacts. The method involves using the number of fission events produced from the spontaneous decay of uranium-238 in common accessory minerals to date the time of rock cooling below closure temperature. Fission tracks are sensitive to heat, and therefore the technique is useful at unraveling the thermal evolution of rocks and minerals. Most current research using fission tracks is aimed at: a) understanding the evolution of mountain belts; b) determining the source or provenance of sediments; c) studying the thermal evolution of basins; d) determining the age of poorly dated strata; and e) dating and provenance determination of archeological artifacts.
Helium dating may refer to the traditional uranium–thorium dating or to a variety of He diffusion methods that utilize the mobility of He atoms to determine the thermal history of a rock. Helium diffusion experiments are often used to help interpret information retrieved from U–Th/He thermochronometric experiments. Kinematic parameters derived from He diffusion is done through estimating He diffusion over a range of temperatures. The use of density functional theory helps in estimating energy barriers for He to overcome as it diffuses across various crystallographic directions. Discrepancies, however, between observed and predicted He diffusion rates is still a problem and likely stem from unresolved problems in crystal defects and radiation damage in natural grains as opposed to theoretical grains. Depending on the mineral analyzed there are different assumptions to be made on He mobility. For example, He diffusion in minerals such as zircon, rutile, and monazite have been shown to be strongly anisotropic.
Thermochronology is the study of the thermal evolution of a region of a planet. Thermochronologists use radiometric dating along with the closure temperatures that represent the temperature of the mineral being studied at the time given by the date recorded to understand the thermal history of a specific rock, mineral, or geologic unit. It is a subfield within geology, and is closely associated with geochronology.
Tectonic Burial is the deformation of rocks caused by extreme pressure over millions of years. It often causes temperature evolutions and deep burials. Tectonic burial is usually the result of continental collisions or subduction in a region. An increase in burial depth leads to a weakened basin and basement but creates better preservation structure within the basement.
Provenance in geology, is the reconstruction of the origin of sediments. The Earth is a dynamic planet, and all rocks are subject to transition between the three main rock types: sedimentary, metamorphic, and igneous rocks. Rocks exposed to the surface are eventually broken down into sediments. Sediments are expected to be able to provide evidence of the erosional history of their parent source rocks. The purpose of provenance study is to restore the tectonic, paleo-geographic and paleo-climatic history.
Titanium in zircon geothermometry is a form of a geothermometry technique by which the crystallization temperature of a zircon crystal can be estimated by the amount of titanium atoms which can only be found in the crystal lattice. In zircon crystals, titanium is commonly incorporated, replacing similarly charged zirconium and silicon atoms. This process is relatively unaffected by pressure and highly temperature dependent, with the amount of titanium incorporated rising exponentially with temperature, making this an accurate geothermometry method. This measurement of titanium in zircons can be used to estimate the cooling temperatures of the crystal and infer conditions during which it crystallized. Compositional changes in the crystals growth rings can be used to estimate the thermodynamic history of the entire crystal. This method is useful as it can be combined with radiometric dating techniques that are commonly used with zircon crystals, to correlate quantitative temperature measurements with specific absolute ages. This technique can be used to estimate early Earth conditions, determine metamorphic facies, or to determine the source of detrital zircons, among other uses.
Electron spin resonance dating, or ESR dating, is a technique used to date materials which radiocarbon dating cannot, including minerals, biological materials, archaeological materials and food. Electron spin resonance dating was first introduced to the science community in 1975, when Japanese nuclear physicist Motoji Ikeya dated a speleothem in Akiyoshi Cave, Japan. ESR dating measures the amount of unpaired electrons in crystalline structures that were previously exposed to natural radiation. The age of a substance can be determined by measuring the dosage of radiation since the time of its formation.
Detrital zircon geochronology is the science of analyzing the age of zircons deposited within a specific sedimentary unit by examining their inherent radioisotopes, most commonly the uranium–lead ratio. Zircon is a common accessory or trace mineral constituent of most granite and felsic igneous rocks. Due to its hardness, durability and chemical inertness, zircon persists in sedimentary deposits and is a common constituent of most sands. Zircons contain trace amounts of uranium and thorium and can be dated using several modern analytical techniques.
Monazite geochronology is a dating technique to study geological history using the mineral monazite. It is a powerful tool in studying the complex history of metamorphic rocks particularly, as well as igneous, sedimentary and hydrothermal rocks. The dating uses the radioactive processes in monazite as a clock.
Lutetium–hafnium dating is a geochronological dating method utilizing the radioactive decay system of lutetium–176 to hafnium–176. With a commonly accepted half-life of 37.1 billion years, the long-living Lu–Hf decay pair survives through geological time scales, thus is useful in geological studies. Due to chemical properties of the two elements, namely their valences and ionic radii, Lu is usually found in trace amount in rare-earth element loving minerals, such as garnet and phosphates, while Hf is usually found in trace amount in zirconium-rich minerals, such as zircon, baddeleyite and zirkelite.
The Pressure-Temperature-time path is a record of the pressure and temperature (P-T) conditions that a rock experienced in a metamorphic cycle from burial and heating to uplift and exhumation to the surface. Metamorphism is a dynamic process which involves the changes in minerals and textures of the pre-existing rocks (protoliths) under different P-T conditions in solid state. The changes in pressures and temperatures with time experienced by the metamorphic rocks are often investigated by petrological methods, radiometric dating techniques and thermodynamic modeling.
Hadean zircon is the oldest-surviving crustal material from the Earth's earliest geological time period, the Hadean eon, about 4 billion years ago. Zircon is a mineral that is commonly used for radiometric dating because it is highly resistant to chemical changes and appears in the form of small crystals or grains in most igneous and metamorphic host rocks.
Optically stimulated luminescence (OSL) thermochronometry is a dating method used to determine the time since quartz and/or feldspar began to store charge as it cools through the effective closure temperature. The closure temperature for quartz and Na-rich K-feldspar is 30-35 °C and 25 °C respectively. When quartz and feldspar are beneath the earth, they are hot. They cool when any geological process e.g. focused erosion causes their exhumation to the earth surface. As they cool, they trap electron charges originating from within the crystal lattice. These charges are accommodated within crystallographic defects or vacancies in their crystal lattices as the mineral cools below the closure temperature.
References
- 1 2 Braun, Jean; Peter van der Beek; Geoffrey Batt (2006). Quantitative Thermochronology: Numerical Methods for the Interpretation of Thermochronological Data . Cambridge: Cambridge University Press. pp. 24–27. ISBN 978-0-521-83057-7.
- ↑ Earth: a Portrait of a Planet Glossary W.W. Norton & Company Archived 2009-01-08 at the Wayback Machine
- 1 2 Rollinson, 1993. Using Geochemical Data: Evaluation, Presentation, Interpretation Longman Scientific & Technical. ISBN 978-0-582-06701-1
- ↑ Flowers, R.M.; Bowring, S.A.; Tulloch, A.J.; Klepeis, K.A. (2005). "Tempo of burial and exhumation within the deep roots of a magmatic arc, Fiordland, New Zealand". Geology. 33 (1): 17. Bibcode:2005Geo....33...17F. doi:10.1130/G21010.1.
- ↑ Toyoda, Shin; Ikeya, Motoji (1991). "Thermal stabilities of paramagnetic defect and impurity centers in quartz: Basis for ESR dating of thermal history". Geochemical Journal. 25 (6): 437–445. Bibcode:1991GeocJ..25..437T. doi: 10.2343/geochemj.25.437 . ISSN 0016-7002.
- ↑ Tsang, Man-Yin; Toyoda, Shin; Tomita, Makiko; Yamamoto, Yuzuru (2022-08-01). "Thermal stability and closure temperature of barite for electron spin resonance dating". Quaternary Geochronology. 71: 101332. Bibcode:2022QuGeo..7101332T. doi: 10.1016/j.quageo.2022.101332 . ISSN 1871-1014. S2CID 248614826.
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