Cork taint is a broad term referring to an off-odor and off-flavor wine fault [1] arising from the presence of 2,4,6-trichloroanisole (TCA), a chemical compound that represents one of the strongest off-flavors, and one "generated naturally in foods/beverages", in particular wines, that considerably reduces the quality of these products. [2] [ better source needed ]
Cork taint is characterized by a set of undesirable smells or tastes found in a bottle of wine, especially spoilage that can only be detected after bottling, aging and opening.[ not verified in body ] Though modern studies have shown that other factors can also be responsible for taint—including wooden barrels, storage conditions and the transport of corks and wine[ not verified in body ]—the cork stopper is normally considered to be responsible, and a wine found to be tainted on opening is said to be corked or "corky". Cork taint can affect wines irrespective of price and quality level.[ not verified in body ]
The chief cause of cork taint is the presence of the chemical compounds 2,4,6-trichloroanisole (TCA) or 2,4,6-tribromoanisole (TBA) in the wine, which in many cases will have been transferred from the cork, but which also can have been transferred through the cork rather than from it.[ not verified in body ] TCA is a compound which does not occur naturally;[ dubious – discuss ] It is created when some fungi are treated with chlorinated phenolic compounds,[ dubious – discuss ] which are types of antimicrobial agents used in the processing of wood. This class of compounds is a chief factor responsible for the problem associated with mold liable to be found in corks; very small amounts of this compound, on the order of nanograms, can be responsible for this defect.[ not verified in body ]
Corked wine containing TCA has a characteristic odor, variously described as resembling a moldy newspaper, wet dog, damp cloth, or damp basement;[ not verified in body ] in almost all cases of corked wine, the wine's native aromas are reduced significantly, and a very tainted wine is quite unpalatable, although harmless.[ not verified in body ] While the human threshold for detecting TCA is measured in the single-digit parts per trillion, this can vary by several orders of magnitude depending on an individual's sensitivity,[ not verified in body ] where the detection limit is also complicated by the olfactory system's particularly quick habituation to TCA, making the smell less obvious on each subsequent sniff.[ not verified in body ]
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The primary chemical precursor to TCA is TCP (2,4,6-trichlorophenol), a solvent used for industrial cleaning.[ citation needed ] [3] Bacteria is able to de-toxify TCP, notably Pseudomonas and Stenotrophomonas, but both strains cannot de-toxify the TCP without the other. [ better source needed ] [4] Chlorinated phenols can form chemically when hypochlorous acid (HOCl, one of the active forms of chlorine) or chlorine radicals come in contact with wood (untreated, such as barrels or pallets).[ citation needed ] The use of chlorine or other halogen-based sanitizing agents is being phased out of the wine industry in favor of peroxide or peracetic acid preparations.[ citation needed ] Chlorine dioxide has not been shown to produce these spontaneous chlorophenols.[ citation needed ] Chlorine dioxide is a relatively new agent being used in the wine industry due to its obvious advantages, having shown no evidence of the possibility of TCA formation.[ citation needed ]
The production of TCA in cork or its transfer by other means into wine is complex, but most results when naturally occurring airborne fungi are presented with chlorophenol compounds, which they then convert into chlorinated anisole derivatives. Chlorophenols taken up by cork trees are an industrial pollutant found in many pesticides and wood preservatives, which may mean that the incidence of cork taint has risen in modern times. Chlorophenols can also be a product of the chlorine bleaching process used to sterilize corks (not in use anymore); this has led to the increasing adoption of methods such as peroxide bleaching.
TCA and TBA are responsible for the vast majority of cases of cork taint, but other less common and less known compounds that can cause different varieties of cork taint include guaiacol, geosmin, 2-methylisoborneol (MIB), octen-3-ol and also octen-3-one, each with its own particular aroma, but all considered objectionable in wine.
The cork-industry group APCOR cites a study showing a 0.7–1.2% taint rate. In a 2005 study of 2800 bottles tasted at the Wine Spectator blind-tasting facilities in Napa, California, 7% of the bottles were found to be tainted. [5]
In 2013, the Cork Quality Council ran over 25 thousand tests. The results, compared with data from eight years ago, show a sharp reduction in TCA levels, of around 81 percent. In the last test, 90 percent of samples of natural cork stopper shipments showed values of under 1.0 ppt and only 7 percent had showed results of 1.0–2.0 ppt. [6]
Improvements in cork and winemaking methodology continue to strive to lower the incidence, but the media attention given to cork taint has created a controversy in the winemaking community, with traditional cork growers on one side and the makers of newer synthetic closures and screw caps on the other. Screw caps and synthetic corks, however, are thought to be prone to another aroma taint: sulphidisation. This may arise from the reduced oxygen supply which concentrates sulphurous smells arising from wines with universal preservatives, however it is more likely that these wines contain excessive/imbalanced amounts of sulphite based preservatives to begin with. [7]
This section possibly contains original research .(June 2023) |
Systemic TCA tainting occurs when TCA has infiltrated a winery via means other than cork and can affect the entire production of wine instead of just a few bottles. [8] [ better source needed ] This occurs when wine barrels, drain pipes, wooden beams in the cellars, or rubber hoses are tainted by TCA. [8] [ better source needed ] Sometimes entire cellars have to be rebuilt in order to eliminate all potential systemic TCA culprits. [8] [ better source needed ][ verification needed ]
Rubber hoses or gaskets have a high affinity for TCA and therefore concentrate TCA from the atmosphere; wine or water that subsequently passes through infected hoses can become tainted with TCA.[ citation needed ] Another possible means of TCA contamination is through the use of bentonite, a swelling clay preparation (smectite) used in treating wine for heat stability; bentonite has a high affinity for TCA and will absorb TCA and related chemicals in the atmosphere, so if an open bag of bentonite is stored in an environment with a high (1–2 ng/g or ppb) TCA concentration, TCA will be absorbed in the bentonite and transferred to the wine lot to which the bentonite is added.[ citation needed ]
It is notable that this systemic TCA will often impart a trace (1–2 ng/L or ppt) to the wine, which itself is not detected by most consumers.[ according to whom? ][ citation needed ] However, with this high baseline level of TCA in bottled wine, even the additional contribution of a relatively clean cork can elevate the TCA level in the wine above threshold levels (4–6 ng/L or ppt), rendering the wine "corked".[ citation needed ]
Wine Spectator has reported that such California wineries as Pillar Rock Vineyard, Beaulieu Vineyard, and E & J Gallo Winery have had trouble with systemic TCA. [8] [ verification needed ]
Filtration and purification systems now exist that attempt to remove the TCA from corked wine to make it drinkable again, though there are few means of reducing the level of TCA in tainted wine that are approved by the TTB (formerly BATF).[ citation needed ]
One method of removing TCA from tainted wine is to soak polyethylene (a plastic used for applications such as milk containers and plastic food wrap) in the affected wine; the non-polar TCA molecule has a high affinity for the polyethylene molecule, thereby removing the taint from the wine.[ citation needed ] The surface area of polyethylene needed to reduce the taint to sub-threshold levels is based on the TCA level in the affected wine, temperature, and the alcohol level of the wine.[ citation needed ]
Some vintners have used the so-called half and half mix of milk and cream to remove TCA from wine (the TCA in the wine is sequestered by the butterfat in half and half).[ citation needed ] The French company Embag markets a product called "Dream Taste", which uses a copolymer shaped like a cluster of grapes that is designed to remove the TCA taint from wine.[ citation needed ]
As advocated by Andrew Waterhouse, professor of wine chemistry at University of California, Davis, this can be done at home by pouring the wine into a bowl with a sheet of polyethylene plastic wrap; for ease of pouring, a pitcher, measuring cup, or decanter can be used instead, and the 2,4,6-trichloroanisole will stick to the plastic in a process effective within a few minutes. [9]
Cork is an impermeable buoyant material. It is the phellem layer of bark tissue which is harvested for commercial use primarily from Quercus suber, which is native to southwest Europe and northwest Africa. Cork is composed of suberin, a hydrophobic substance. Because of its impermeable, buoyant, elastic, and fire retardant properties, it is used in a variety of products, the most common of which is wine stoppers.
An aroma compound, also known as an odorant, aroma, fragrance or flavoring, is a chemical compound that has a smell or odor. For an individual chemical or class of chemical compounds to impart a smell or fragrance, it must be sufficiently volatile for transmission via the air to the olfactory system in the upper part of the nose. As examples, various fragrant fruits have diverse aroma compounds, particularly strawberries which are commercially cultivated to have appealing aromas, and contain several hundred aroma compounds.
Brettanomyces is a non-spore forming genus of yeast in the family Saccharomycetaceae, and is often colloquially referred to as "Brett". The genus name Dekkera is used interchangeably with Brettanomyces, as it describes the teleomorph or spore forming form of the yeast, but is considered deprecated under the one fungus, one name change. The cellular morphology of the yeast can vary from ovoid to long "sausage" shaped cells. The yeast is acidogenic, and when grown on glucose rich media under aerobic conditions, produces large amounts of acetic acid. Brettanomyces is important to both the brewing and wine industries due to the sensory compounds it produces.
Malolactic conversion is a process in winemaking in which tart-tasting malic acid, naturally present in grape must, is converted to softer-tasting lactic acid. Malolactic fermentation is most often performed as a secondary fermentation shortly after the end of the primary fermentation, but can sometimes run concurrently with it. The process is standard for most red wine production and common for some white grape varieties such as Chardonnay, where it can impart a "buttery" flavor from diacetyl, a byproduct of the reaction.
Anisole, or methoxybenzene, is an organic compound with the formula CH3OC6H5. It is a colorless liquid with a smell reminiscent of anise seed, and in fact many of its derivatives are found in natural and artificial fragrances. The compound is mainly made synthetically and is a precursor to other synthetic compounds. Structurally, it is an ether with a methyl and phenyl group attached. Anisole is a standard reagent of both practical and pedagogical value.
2,4,6-Trichloroanisole (TCA) is an organic compound with the formula CH3OC6H2Cl3. It is the symmetric isomer of trichloroanisole. It is a colorless solid.
A wine fault is a sensory-associated (organoleptic) characteristic of a wine that is unpleasant, and may include elements of taste, smell, or appearance, elements that may arise from a "chemical or a microbial origin", where particular sensory experiences might arise from more than one wine fault. Wine faults may result from poor winemaking practices or storage conditions that lead to wine spoilage.
Wine corks are a stopper used to seal wine bottles. They are typically made from cork, though synthetic materials can be used. Common alternative wine closures include screw caps and glass stoppers. 68 percent of all cork is produced for wine bottle stoppers.
Alternative wine closures are substitute closures used in the wine industry for sealing wine bottles in place of traditional cork closures. The emergence of these alternatives has grown in response to quality control efforts by winemakers to protect against "cork taint" caused by the presence of the chemical trichloroanisole (TCA).
2,4,6-Trichlorophenol, also known as TCP, phenaclor, Dowicide 2S, Dowcide 2S, omal, is a chlorinated phenol that has been used as a fungicide, herbicide, insecticide, antiseptic, defoliant, and glue preservative. It is a clear to yellowish crystalline solid with a strong, phenolic odor. It decomposes on heating to produce toxic and corrosive fumes including hydrogen chloride and chlorine.
The aging of wine is potentially able to improve the quality of wine. This distinguishes wine from most other consumable goods. While wine is perishable and capable of deteriorating, complex chemical reactions involving a wine's sugars, acids and phenolic compounds can alter the aroma, color, mouthfeel and taste of the wine in a way that may be more pleasing to the taster. The ability of a wine to age is influenced by many factors including grape variety, vintage, viticultural practices, wine region and winemaking style. The condition that the wine is kept in after bottling can also influence how well a wine ages and may require significant time and financial investment. The quality of an aged wine varies significantly bottle-by-bottle, depending on the conditions under which it was stored, and the condition of the bottle and cork, and thus it is said that rather than good old vintages, there are good old bottles. There is a significant mystique around the aging of wine, as its chemistry was not understood for a long time, and old wines are often sold for extraordinary prices. However, the vast majority of wine is not aged, and even wine that is aged is rarely aged for long; it is estimated that 90% of wine is meant to be consumed within a year of production, and 99% of wine within 5 years.
This glossary of winemaking terms lists some of terms and definitions involved in making wine, fruit wine, and mead.
In winemaking, clarification and stabilization are the processes by which insoluble matter suspended in the wine is removed before bottling. This matter may include dead yeast cells (lees), bacteria, tartrates, proteins, pectins, various tannins and other phenolic compounds, as well as pieces of grape skin, pulp, stems and gums. Clarification and stabilization may involve fining, filtration, centrifugation, flotation, refrigeration, pasteurization, and/or barrel maturation and racking.
Storage of wine is an important consideration for wine that is being kept for long-term aging. While most wine is consumed within 24 hours of purchase, fine wines are often set aside for long-term storage. Wine is one of the few commodities that can improve in flavour and value with age, but it can also rapidly deteriorate if kept in inadequate conditions.
Organoleptic properties are the aspects of food, water or other substances as apprehended via the senses—including taste, sight, smell, and touch.
A screw cap is a metal, normally aluminium, cap that screws onto threads on the neck of a wine bottle, generally with a metal skirt down the neck to resemble the traditional wine capsule ("foil"). A layer of plastic, cork, rubber, or other soft material is used as wad to make a seal with the mouth of the bottle. Its use as an alternative to cork for sealing wine bottles is gaining increasing support. In markets such as Australia and New Zealand screw caps on bottles have overtaken cork to become the most common means of sealing bottles.
2,4,6-Tribromoanisole (TBA) is a chemical compound that is a brominated derivative of anisole. It is one of the chemicals responsible for cork taint.
Nomacorc now known as Vinventions, is a company producing engineered synthetic corks for wine bottles. Nomacorc closures are co-extruded to manage the oxygen transfer rate for wine, reducing 2,4,6-trichloroanisole (TCA), more commonly known as cork taint.
Adsorbable organic halides (AOX) is a measure of the organic halogen load at a sampling site such as soil from a land fill, water, or sewage waste. The procedure measures chlorine, bromine, and iodine as equivalent halogens, but does not measure fluorine levels in the sample.
Smoke taint is a broad term for a set of smoke imparted compounds found in affected wines, constituting a wine fault. Increasing incidences of smoke tainted wines are an important issue, given the recent occurrences of wildfires or bushfires in wine grape producing regions during the growing seasons. Examples of wildfires resulting in smoke tainted wines include the fires in South Africa in late 2017, October 2017 Northern California wildfires, the 2019–20 Australian bushfire season, and the 2020 Glass Fire in Northern California.
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: CS1 maint: multiple names: authors list (link)Over the last two decades, the incidence of mouldy and musty off-flavours in cork-sealed wines has increased significantly. 2,4,6-Trichloroanisole (TCA) has been identified as the primary chemical responsible for cork taint. The human olfactometry threshold for TCA is 4–10 ng L−1 in white wine and 50 ng L−1 in red wine. In the case of wine, a worldwide loss of roughly US$1 billion per year is attributed to cork taint.