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Bitumen is an immensely viscous constituent of petroleum. Depending on its exact composition it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In the U.S., the material is commonly referred to as asphalt. Whether found in natural deposits or refined from petroleum, the substance is classed as a pitch. Prior to the 20th century the term asphaltum was in general use. The word derives from the ancient Greek ἄσφαλτος ásphaltos, which referred to natural bitumen or pitch. The largest natural deposit of bitumen in the world, estimated to contain 10 million tons, is the Pitch Lake of southwest Trinidad.
An oil refinery or petroleum refinery is an industrial process plant where petroleum is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemical feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day.
A refinery is a production facility composed of a group of chemical engineering unit processes and unit operations refining certain materials or converting raw material into products of value.
In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking of carbon-carbon bonds in the precursors. The rate of cracking and the end products are strongly dependent on the temperature and presence of catalysts. Cracking is the breakdown of large hydrocarbons into smaller, more useful alkanes and alkenes. Simply put, hydrocarbon cracking is the process of breaking a long chain hydrocarbon into short ones. This process requires high temperatures.
A visbreaker is a processing unit in an oil refinery whose purpose is to reduce the quantity of residual oil produced in the distillation of crude oil and to increase the yield of more valuable middle distillates by the refinery. A visbreaker thermally cracks large hydrocarbon molecules in the oil by heating in a furnace to reduce its viscosity and to produce small quantities of light hydrocarbons.. The process name of "visbreaker" refers to the fact that the process reduces the viscosity of the residual oil. The process is non-catalytic.
Catalytic reforming is a chemical process used to convert petroleum refinery naphthas distilled from crude oil into high-octane liquid products called reformates, which are premium blending stocks for high-octane gasoline. The process converts low-octane linear hydrocarbons (paraffins) into branched alkanes (isoparaffins) and cyclic naphthenes, which are then partially dehydrogenated to produce high-octane aromatic hydrocarbons. The dehydrogenation also produces significant amounts of byproduct hydrogen gas, which is fed into other refinery processes such as hydrocracking. A side reaction is hydrogenolysis, which produces light hydrocarbons of lower value, such as methane, ethane, propane and butanes.
An upgrader is a facility that upgrades bitumen into synthetic crude oil. Upgrader plants are typically located close to oil sands production, for example, the Athabasca oil sands in Alberta, Canada or the Orinoco tar sands in Venezuela.
Heavy crude oil is highly viscous oil that cannot easily flow from production wells under normal reservoir conditions.
Asphaltenes are molecular substances that are found in crude oil, along with resins, aromatic hydrocarbons, and saturates. The word "asphaltene" was coined by Boussingault in 1837 when he noticed that the distillation residue of some bitumens had asphalt-like properties. Asphaltenes in the form of asphalt or bitumen products from oil refineries are used as paving materials on roads, shingles for roofs, and waterproof coatings on building foundations.
Fluid Catalytic Cracking (FCC) is the conversion process used in petroleum refineries to convert the high-boiling point, high-molecular weight hydrocarbon fractions of petroleum into gasoline, alkene gases, and other petroleum products. The cracking of petroleum hydrocarbons was originally done by thermal cracking, now virtually replaced by catalytic cracking, which yields greater volumes of high octane rating gasoline; and produces by-product gases, with more carbon-carbon double bonds, that are of greater economic value than the gases produced by thermal cracking.
The Gujarat Refinery is an oil refinery located at Koyali, Vadodara District in Gujarat, Western India. It is the third largest refinery owned by Indian Oil Corporation after Paradip and Panipat Refinery. The refinery is currently under projected expansion to 18 million tonnes per year.
Visakhapatnam Refinery, is one of the two oil refineries of HPCL in India, the other being Mumbai Refinery. This was one of the first major industries of Visakhapatnam and first oil refinery on the East Coast. After the nationalisation, HPCL has transformed itself into a mega Public Sector Undertaking and it is second largest integrated oil company in India.
Merox is an acronym for mercaptan oxidation. It is a proprietary catalytic chemical process developed by UOP used in oil refineries and natural gas processing plants to remove mercaptans from LPG, propane, butanes, light naphthas, kerosene, and jet fuel by converting them to liquid hydrocarbon disulfides.
Natural-gas processing is a range of industrial processes designed to purify raw natural gas by removing contaminants such as solids, water, carbon dioxide (CO2), hydrogen sulfide (H2S), mercury and higher molecular mass hydrocarbons (condensate) to produce pipeline quality dry natural gas for pipeline distribution and final use. Some of the substances which contaminate natural gas have economic value and are further processed or sold. Hydrocarbons that are liquid at ambient conditions: temperature and pressure (i.e., pentane and heavier) are called natural-gas condensate (sometimes also called natural gasoline or simply condensate).
Fawley Refinery is an oil refinery located at Fawley, Hampshire, England. The refinery is owned by Esso Petroleum Company Limited, a subsidiary of Exxon Mobil Corporation, which acquired the site in 1925. Situated on Southampton Water, it was rebuilt and extended in 1951 and is now the largest oil refinery in the United Kingdom, and one of the most complex refineries in Europe. With a capacity of 270,000 barrels (43,000 m3) per day, Fawley provides 20 per cent of the UK's refinery capacity. Over 2,500 people are employed at the site.
The Płock refinery is a large oil refinery and petrochemical complex located in Płock, Poland. It is owned by PKN Orlen, and is one of the two crude oil refineries in Poland, the other one is Gdansk refinery. The refinery has a Nelson complexity index of 9.5 and a capacity is 16.3 million tonnes per year or 276,000 barrels per day of crude oil.
Gdańsk oil refinery is a 10.5 million tonne per year refinery located near the Polish city of Gdańsk on the Baltic Sea. The refinery was established in 1975 to supply fuels and lubricants, and has undergone several upgrades and expansions to increase its capacity and the range of products available. It now has a Nelson complexity index of 11.1. It is one of two oil refineries in Poland, the other is Plock refinery.
The BPRefinery (Kent) was an oil refinery on the Isle of Grain in Kent. It was commissioned in 1953 and had a maximum processing capacity of 11 million tonnes of crude oil per year. It was decommissioned in August 1982.
Eastham Oil Terminal is situated close to the small town of Eastham on the Wirral Peninsula, beside the Manchester Ship Canal. It was commissioned in 1954 close to the Queen Elizabeth II Dock and is a storage and export facility for oil products refined at Stanlow Refinery, to which it is connected by pipeline. The site is currently operated by Nynas.
Bitumen froth treatment is a process used in the Athabasca oil sands (AOS) bitumen recovery operations to remove fine inorganics—water and mineral particles—from bitumen froth, by diluting the bitumen with a light hydrocarbon solvent—either naphthenic or paraffinic—to reduce the viscosity of the froth and to remove contaminants that were not removed in previous water-based gravity recovery phases. Bitumen with a high viscosity or with too many contaminants, is not suitable for transporting through pipelines or refining. The original and conventional naphthenic froth treatment (NFT) uses a naphtha solvent with the addition of chemicals. Paraffinic Solvent Froth Treatment (PSFT), which was first used commercially in the Albian Sands in the early 2000s, results in a cleaner bitumen with lower levels of contaminates, such as water and mineral solids. Following froth treatments, bitumen can be further upgraded using "heat to produce synthetic crude oil by means of a coker unit."
References
- Study of selected petroleum refining residuals by US EPA
- Lubricants and Lubrication (Second Edition)
- ↑ John J. McKetta (1992). Petroleum Processing Handbook. CRC Press. p. 536. ISBN 978-0-8247-8681-6.
