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Spectroscopy is the field of study that measures and interprets electromagnetic spectra. In narrower contexts, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.
The Mössbauer effect, or recoilless nuclear resonance fluorescence, is a physical phenomenon discovered by Rudolf Mössbauer in 1958. It involves the resonant and recoil-free emission and absorption of gamma radiation by atomic nuclei bound in a solid. Its main application is in Mössbauer spectroscopy.
Laser cooling, sometimes also referred to as Doppler cooling, includes several techniques where atoms, molecules, and small mechanical systems are cooled with laser light. The directed energy of lasers is often associated with heating materials, e.g. laser cutting, so it can be counterintuitive that laser cooling often results in sample temperatures approaching absolute zero. It is a routine step in many atomic physics experiments where the laser-cooled atoms are then subsequently manipulated and measured, or in technologies, such as atom-based quantum computing architectures. Laser cooling relies on the change in momentum when an object, such as an atom, absorbs and re-emits a photon. For example, if laser light illuminates a warm cloud of atoms from all directions and the laser's frequency is tuned below an atomic resonance, the atoms will be cooled. This common type of laser cooling relies on the Doppler effect where individual atoms will preferentially absorb laser light from the direction opposite to the atom's motion. The absorbed light is re-emitted by the atom in a random direction. After repeated emission and absorption of light the net effect on the cloud of atoms is that they will expand more slowly. The slower expansion reflects a decrease in the velocity distribution of the atoms, which corresponds to a lower temperature and therefore the atoms have been cooled. For an ensemble of particles, their thermodynamic temperature is proportional to the variance in their velocity, therefore the lower the distribution of velocities, the lower temperature of the particles.
A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible.
Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.
Plasma diagnostics are a pool of methods, instruments, and experimental techniques used to measure properties of a plasma, such as plasma components' density, distribution function over energy (temperature), their spatial profiles and dynamics, which enable to derive plasma parameters.
Hydrogen-alpha, typically shortened to H-alpha or Hα, is a deep-red visible spectral line of the hydrogen atom with a wavelength of 656.28 nm in air and 656.46 nm in vacuum. It is the first spectral line in the Balmer series and is emitted when an electron falls from a hydrogen atom's third- to second-lowest energy level. H-alpha has applications in astronomy where its emission can be observed from emission nebulae and from features in the Sun's atmosphere, including solar prominences and the chromosphere.
Robert Henry Dicke was an American astronomer and physicist who made important contributions to the fields of astrophysics, atomic physics, cosmology and gravity. He was the Albert Einstein Professor in Science at Princeton University (1975–1984).
Resolved sideband cooling is a laser cooling technique allowing cooling of tightly bound atoms and ions beyond the Doppler cooling limit, potentially to their motional ground state. Aside from the curiosity of having a particle at zero point energy, such preparation of a particle in a definite state with high probability (initialization) is an essential part of state manipulation experiments in quantum optics and quantum computing.
In spectroscopy, an absorption band is a range of wavelengths, frequencies or energies in the electromagnetic spectrum that are characteristic of a particular transition from initial to final state in a substance.
In atomic physics, Doppler broadening is broadening of spectral lines due to the Doppler effect caused by a distribution of velocities of atoms or molecules. Different velocities of the emitting particles result in different Doppler shifts, the cumulative effect of which is the emission (absorption) line broadening. This resulting line profile is known as a Doppler profile.
Doppler cooling is a mechanism that can be used to trap and slow the motion of atoms to cool a substance. The term is sometimes used synonymously with laser cooling, though laser cooling includes other techniques.
Mössbauer spectroscopy is a spectroscopic technique based on the Mössbauer effect. This effect, discovered by Rudolf Mössbauer in 1958, consists of the nearly recoil-free emission and absorption of nuclear gamma rays in solids. The consequent nuclear spectroscopy method is exquisitely sensitive to small changes in the chemical environment of certain nuclei.
Noise-immune cavity-enhanced optical-heterodyne molecular spectroscopy (NICE-OHMS) is an ultra-sensitive laser-based absorption technique that utilizes laser light to assess the concentration or the amount of a species in gas phase by absorption spectrometry (AS).
Atomic emission spectroscopy (AES) is a method of chemical analysis that uses the intensity of light emitted from a flame, plasma, arc, or spark at a particular wavelength to determine the quantity of an element in a sample. The wavelength of the atomic spectral line in the emission spectrum gives the identity of the element while the intensity of the emitted light is proportional to the number of atoms of the element. The sample may be excited by various methods.
Atomic Spectroscopy and Collisions Using Slow Antiprotons (ASACUSA), AD-3, is an experiment at the Antiproton Decelerator (AD) at CERN. The experiment was proposed in 1997, started collecting data in 2002 by using the antiprotons beams from the AD, and will continue in future under the AD and ELENA decelerator facility.
In astronomy and in astrophysics, for radiative losses of the solar corona, it is meant the energy flux radiated from the external atmosphere of the Sun, and, in particular, the processes of production of the radiation coming from the solar corona and transition region, where the plasma is optically-thin. On the contrary, in the chromosphere, where the temperature decreases from the photospheric value of 6000 K to the minimum of 4400 K, the optical depth is about 1, and the radiation is thermal.
Saturated absorption spectroscopy measures the transition frequency of an atom or molecule between its ground state and an excited state. In saturated absorption spectroscopy, two counter-propagating, overlapped laser beams are sent through a sample of atomic gas. One of the beams stimulates photon emission in excited atoms or molecules when the laser's frequency matches the transition frequency. By changing the laser frequency until these extra photons appear, one can find the exact transition frequency. This method enables precise measurements at room temperature because it is insensitive to doppler broadening. Absorption spectroscopy measures the doppler-broadened transition, so the atoms must be cooled to millikelvin temperatures to achieve the same sensitivity as saturated absorption spectroscopy.
In atomic physics, Raman cooling is a sub-recoil cooling technique that allows the cooling of atoms using optical methods below the limitations of Doppler cooling, Doppler cooling being limited by the recoil energy of a photon given to an atom. This scheme can be performed in simple optical molasses or in molasses where an optical lattice has been superimposed, which are called respectively free space Raman cooling and Raman sideband cooling. Both techniques make use of Raman scattering of laser light by the atoms.
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian, Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. Actual line shapes are determined principally by Doppler, collision and proximity broadening. For each system the half-width of the shape function varies with temperature, pressure and phase. A knowledge of shape function is needed for spectroscopic curve fitting and deconvolution.
References
- ↑ R. H. Dicke (1953). "The Effect of Collisions upon the Doppler Width of Spectral Lines". Physical Review. 89 (2): 472–473. Bibcode:1953PhRv...89..472D. doi:10.1103/PhysRev.89.472.
- ↑ Griem, Hans R. (1997). Principles of Plasmas Spectroscopy. Cambridge: University Press. ISBN 0-521-45504-9.
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