 | This article needs additional citations for verification .(August 2014) |
Drag-reducing agents (DRA) or drag-reducing polymers (DRP) are additives in pipelines that reduce turbulence in a pipe. Usually used in petroleum pipelines, they increase the pipeline capacity by reducing turbulency and increasing laminar flow. [1]
Drag reducing agents can be broadly classified [2] under the following four categories – Polymers, Solid-particle suspensions, Biological additives, and Surfactants. These agents are made out of high molecular weight polymers or micellar systems. The polymers help with drag reduction by decreasing turbulence in the oil lines. This allows for oil to be pumped through at lower pressures, saving energy and money. Although these drag reducing agents are mostly used in oil lines, there is research being done to see how helpful polymers could be in reducing drag in veins and arteries.
Using just a few parts per million of the drag reducer helps to reduce the turbulence inside the pipe. Because the oil pushes up against the inside wall of the pipe, the pipe pushes the oil back down causing a swirling of turbulence to occur which creates a drag force. When the polymer is added, it interacts with the oil and the wall to help reduce the contact of the oil with the wall.
Degradation can occur on the polymers during the flow. Because of the pressure and temperature on the polymers, it is easier to break them down. Because of this, the drag reducing agent is re-injected after points like pumps and turns, where the pressure and temperature can be extra high. To safeguard against degradation at high temperature, a different class of drag reducing agents are at times used, namely, surfactants. [3] Surfactant is a very convenient contraction of the term Surface-active agent. It connotes an organic molecule or an unformulated compound having surface-active properties. All three classes of surfactants, namely, anionic, cationic and nonionic surfactants, have been successfully tried as drag-reducing agents. [4]
Knowing what will create the ideal drag reducer is key in this process. Ideal molecules have a high molecular weight, shear degradation resistance, are quick to dissolve in whatever is in the pipe, and have low degradation in heat, light, chemicals, and biological areas.
With drag reduction, there are many factors which play a role in how well the drag is reduced. A main factor in this is temperature. With a higher temperature, the drag reducing agent is easier to degrade. At a low temperature the drag reducing agent will tend to cluster together. This problem can be solved easier than degradation though, by adding another chemical, such as aluminum to help lower the drag reducing agent's inter-molecular attraction.
Other factors are the pipe diameter, inside roughness, and pressure. Drag is higher in smaller diameter pipe. The rougher the inside surface of the pipe, the higher the drag, or friction, which is measured by the Reynold's number. Increasing the pressure will increase flow and reduce drag, but is limited by the maximum pressure rating of the pipe.
Drag reducing agents have been found useful in reducing turbulence in the shipbuilding industry, for fire-fighting operations, oil-well fracturing processes, [5] in irrigation systems and in central heating devices. Drag reducers can work in a couple of different fields. The most popular are crude oil, refined products and non-potable water. Currently there are several studies with ongoing tests in rats looking to see if drag reducers can help with blood flow.
The earliest works that recorded a decrease in pressure drop during turbulent flow were undertaken in the thirties [6] [7] [8] and concerned the transportation of paper pulp. This was, however, not explicitly referred to as a drag reduction phenomenon. B. A. Toms [9] was the first to recognize the tremendous reduction in wall shear stress caused by the addition of small amount of linear macromolecules to a turbulent flowing fluid. This effect is known as the Toms effect. An extensive bibliography of the first 25 years of drag reduction by polymer additives literature identified over 270 references. [10]
Drag reducers were introduced into the market in the early 1970s by Conoco Inc. [11] (now known as LiquidPower Specialty Products Inc. (LSPI), a Berkshire Hathaway company). Its use has allowed pipeline systems to greatly increase in traditional capacity and extended the life of existing systems. The higher flow rates possible on long pipelines have also increased the potential for surge on older systems not previously designed for high velocities.
Both proprietary (such as Conoco T-83) and non-proprietary (such as poly-isobutylene) drag reduction additives have been evaluated by the U.S. Army Mobility Equipment Research and Development Center for enhancement of military petroleum pipeline systems. [12]
An emulsion is a mixture of two or more liquids that are normally immiscible owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion should be used when both phases, dispersed and continuous, are liquids. In an emulsion, one liquid is dispersed in the other. Examples of emulsions include vinaigrettes, homogenized milk, liquid biomolecular condensates, and some cutting fluids for metal working.
In physics, physical chemistry and engineering, fluid dynamics is a subdiscipline of fluid mechanics that describes the flow of fluids – liquids and gases. It has several subdisciplines, including aerodynamics and hydrodynamics. Fluid dynamics has a wide range of applications, including calculating forces and moments on aircraft, determining the mass flow rate of petroleum through pipelines, predicting weather patterns, understanding nebulae in interstellar space and modelling fission weapon detonation.
A lubricant is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.
Rheology is the study of the flow of matter, primarily in a fluid state but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is the branch of physics that deals with the deformation and flow of materials, both solids and liquids.
Guar gum, also called guaran, is a galactomannan polysaccharide extracted from guar beans that has thickening and stabilizing properties useful in food, feed, and industrial applications. The guar seeds are mechanically dehusked, hydrated, milled and screened according to application. It is typically produced as a free-flowing, off-white powder.
In colloidal and surface chemistry, the critical micelle concentration (CMC) is defined as the concentration of surfactants above which micelles form and all additional surfactants added to the system will form micelles.
Microemulsions are clear, thermodynamically stable, isotropic liquid mixtures of oil, water and surfactant, frequently in combination with a cosurfactant. The aqueous phase may contain salt(s) and/or other ingredients, and the "oil" may actually be a complex mixture of different hydrocarbons. In contrast to ordinary emulsions, microemulsions form upon simple mixing of the components and do not require the high shear conditions generally used in the formation of ordinary emulsions. The three basic types of microemulsions are direct, reversed and bicontinuous.
A static mixer is a device for the continuous mixing of fluid materials, without moving components. Normally the fluids to be mixed are liquid, but static mixers can also be used to mix gas streams, disperse gas into liquid or blend immiscible liquids. The energy needed for mixing comes from a loss in pressure as fluids flow through the static mixer. One design of static mixer is the plate-type mixer and another common device type consists of mixer elements contained in a cylindrical (tube) or squared housing. Mixer size can vary from about 6 mm to 6 meters diameter. Typical construction materials for static mixer components include stainless steel, polypropylene, Teflon, PVDF, PVC, CPVC and polyacetal. The latest designs involve static mixing elements made of glass-lined steel.
In geotechnical engineering, drilling fluid, also known as drilling mud, is used to aid the drilling of boreholes into the earth. Used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also used for much simpler boreholes, such as water wells.
Enhanced oil recovery, also called tertiary recovery, is the extraction of crude oil from an oil field that cannot be extracted otherwise. Whereas primary and secondary recovery techniques rely on the pressure differential between the surface and the underground well, enhanced oil recovery functions by altering the physical or chemical properties of the oil itself in order to make it easier to extract. When EOR is used, 30% to 60% or more of a reservoir's oil can be extracted, compared to 20% to 40% using only primary and secondary recovery.
Oil additives are chemical compounds that improve the lubricant performance of base oil. The manufacturer of many oils can use the same base stock for each formulation and can choose different additives for each use. Additives comprise up to 5% by weight of some oils.
In fluid dynamics, the Toms effect is a reduction of the drag of a turbulent flow thought a pipeline when polymer solutions are added.
In oil or gas well drilling, lost circulation occurs when drilling fluid, known commonly as "mud", flows into one or more geological formations instead of returning up the annulus. Lost circulation can be a serious problem during the drilling of an oil well or gas well.
2-Acrylamido-2-methylpropane sulfonic acid (AMPS) was a Trademark name by The Lubrizol Corporation. It is a reactive, hydrophilic, sulfonic acid acrylic monomer used to alter the chemical properties of wide variety of anionic polymers. In the 1970s, the earliest patents using this monomer were filed for acrylic fiber manufacturing. Today, there are over several thousands patents and publications involving use of AMPS in many areas including water treatment, oil field, construction chemicals, hydrogels for medical applications, personal care products, emulsion coatings, adhesives, and rheology modifiers. Lubrizol discontinued the production of this monomer in 2017 due to copy-cat production from China and India destroying the profitability of this product.
In fluid dynamics, the Reynolds number is a dimensionless quantity that helps predict fluid flow patterns in different situations by measuring the ratio between inertial and viscous forces. At low Reynolds numbers, flows tend to be dominated by laminar (sheet-like) flow, while at high Reynolds numbers, flows tend to be turbulent. The turbulence results from differences in the fluid's speed and direction, which may sometimes intersect or even move counter to the overall direction of the flow. These eddy currents begin to churn the flow, using up energy in the process, which for liquids increases the chances of cavitation.
A proppant is a solid material, typically sand, treated sand or man-made ceramic materials, designed to keep an induced hydraulic fracture open, during or following a fracturing treatment, most commonly for unconventional reservoirs. It is added to a fracking fluid which may vary in composition depending on the type of fracturing used, and can be gel, foam or slickwater–based. In addition, there may be unconventional fracking fluids. Fluids make tradeoffs in such material properties as viscosity, where more viscous fluids can carry more concentrated proppant; the energy or pressure demands to maintain a certain flux pump rate that will conduct the proppant appropriately; pH, various rheological factors, among others. In addition, fluids may be used in low-volume well stimulation of high-permeability sandstone wells to the high-volume operations such as shale gas and tight gas that use millions of gallons of water per well.
SNF is one of the largest manufacturers of polyacrylamides. These water-soluble polymers are used as flocculants and coagulants in solid/water separation to recycle water, rheology modifiers and friction reducers. These functionalities have many uses where water is used, in drinking water production, wastewater treatment, mining, paper, enhanced oil recovery, hydraulic fracturing, agriculture, textile and cosmetics.
Well cementing is the process of introducing cement to the annular space between the well-bore and casing or to the annular space between two successive casing strings. Personnel who conduct this job are called "Cementers".
Microbial Enhanced Oil Recovery (MEOR) is a biological-based technology involving the manipulation of functions or structures within microbial environments present in oil reservoirs. The primary objective of MEOR is to improve the extraction of oil confined within porous media, while boosting economic benefits. As a tertiary oil extraction technology, MEOR enables the partial recovery of the commonly residual 2/3 of oil, effectively prolonging the operational lifespan of mature oil reservoirs.
Liquid carryover refers to the unintended transport of liquids such as water, hydrocarbon condensates, compressor oil or glycol in a natural gas, hydrogen, carbon dioxide or other industrial gas pipeline or process. Ideally, only gas enters gas processing.