A dry ice bomb is a simple explosive device consisting of dry ice and water in a sealed container.
Dry ice bombs are commonly made from a container such as a plastic bottle, water and dry ice. The bottle is partly filled with water. Chunks of dry ice are added and the container is closed tightly. As the solid carbon dioxide warms, it sublimates to gas and the pressure in the bottle increases. Bombs typically rupture within 30 seconds to half an hour, dependent largely on the temperature of the air outside the bottle. [1] A dry ice bomb may develop frost on its exterior prior to explosion. [1] After explosion, it appears to have shattered, with the overall shape of the device intact. [1]
Dry ice bombs can explode within seconds due to the rapid sublimation of dry ice, injuring the handler. The abrupt release of high-pressure gas creates a loud noise, which can cause hearing damage even at substantial distances. Fragments thrown at high speeds can cut or puncture. Bombs that fail to go off cannot be safely approached, as they can spontaneously explode.
Dry ice bombs can also be unintentionally made, especially if dry ice is left in an airtight container for extended periods of time. [2]
Injuries caused by dry ice bombs are common, with glass bottles in particular posing risks of serious injury or death. [3] [4] [5] [6] In one case, the explosive release of carbon dioxide gas ruptured the esophagus of a child, requiring emergency surgery. [7]
The examples and perspective in this article deal primarily with the United States and do not represent a worldwide view of the subject.(May 2012) |
Dry ice bombs are illegal in many jurisdictions. [8] [9] Manufacturing one or using one can lead to imprisonment. [10]
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
A bomb is an explosive weapon that uses the exothermic reaction of an explosive material to provide an extremely sudden and violent release of energy. Detonations inflict damage principally through ground- and atmosphere-transmitted mechanical stress, the impact and penetration of pressure-driven projectiles, pressure damage, and explosion-generated effects. Bombs have been utilized since the 11th century starting in East Asia.
Dry ice colloquially means the solid form of carbon dioxide. It is commonly used for temporary refrigeration as CO2 does not have a liquid state at normal atmospheric pressure and sublimes directly from the solid state to the gas state. It is used primarily as a cooling agent, but is also used in fog machines at theatres for dramatic effects. Its advantages include lower temperature than that of water ice and not leaving any residue (other than incidental frost from moisture in the atmosphere). It is useful for preserving frozen foods (such as ice cream) where mechanical cooling is unavailable.
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from Greek: πικρός (pikros), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye.
Ammonium nitrate is a chemical compound with the formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.
A pipe bomb is an improvised explosive device (IED) that uses a tightly sealed section of pipe filled with an explosive material. The containment provided by the pipe means that simple low explosives can be used to produce a relatively large explosion due to the containment causing increased pressure. The fragmentation of the pipe itself creates potentially lethal shrapnel.
An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent unwanted chemical reactions with the oxygen (oxidation) and moisture (hydrolysis) in the air from degrading a sample. Generally, all noble gases except oganesson, nitrogen, and carbon dioxide are considered inert gases. The term inert gas is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions.
Sublimation is the transition of a substance directly from the solid to the gas state, without passing through the liquid state. The verb form of sublimation is sublime, or less preferably, sublimate. Sublimate also refers to the product obtained by sublimation. The point at which sublimation occurs rapidly is called critical sublimation point, or simply sublimation point. Notable examples include sublimation of dry ice at room temperature and atmospheric pressure, and that of solid iodine with heating.
Acetone peroxide is an organic peroxide and a primary explosive. It is produced by the reaction of acetone and hydrogen peroxide to yield a mixture of linear monomer and cyclic dimer, trimer, and tetramer forms. The monomer is dimethyldioxirane. The dimer is known as diacetone diperoxide (DADP). The trimer is known as triacetone triperoxide (TATP) or tri-cyclic acetone peroxide (TCAP). Acetone peroxide takes the form of a white crystalline powder with a distinctive bleach-like odor when impure, or a fruit-like smell when pure, and can explode powerfully if subjected to heat, friction, static electricity, concentrated sulfuric acid, strong UV radiation, or shock. Until about 2015, explosives detectors were not set to detect non-nitrogenous explosives, as most explosives used preceding 2015 were nitrogen-based. TATP, being nitrogen-free, has been used as the explosive of choice in several terrorist bomb attacks since 2001.
A water rocket is a type of model rocket using water as its reaction mass. The water is forced out by a pressurized gas, typically compressed air. Like all rocket engines, it operates on the principle of Newton's third law of motion. Water rocket hobbyists typically use one or more plastic soft drink bottles as the rocket's pressure vessel. A variety of designs are possible including multi-stage rockets. Water rockets are also custom-built from composite materials to achieve world record altitudes.
Tannerite is a brand of binary explosive targets used for firearms practice and sold in kit form. The targets comprise a combination of oxidizers and a fuel, primarily aluminium powder, that is supplied as two separate components that are mixed by the user. The combination is relatively stable when subjected to forces less severe than a high-velocity bullet impact. A hammer blow, the product being dropped, or impact from a low-velocity bullet or shotgun blast will not initiate a reaction. It is also designed to be non-flammable, although its explosion can ignite flammable material.
A zinc–carbon battery (or carbon zinc battery in U.S. English) is a dry cell primary battery that provides direct electric current from the electrochemical reaction between zinc (Zn) and manganese dioxide (MnO2) in the presence of an ammonium chloride (NH4Cl) electrolyte. It produces a voltage of about 1.5 volts between the zinc anode, which is typically constructed as a cylindrical container for the battery cell, and a carbon rod surrounded by a compound with a higher Standard electrode potential (positive polarity), known as the cathode, that collects the current from the manganese dioxide electrode. The name "zinc-carbon" is slightly misleading as it implies that carbon is acting as the oxidizing agent rather than the manganese dioxide.
A chemical oxygen generator is a device that releases oxygen via a chemical reaction. The oxygen source is usually an inorganic superoxide, chlorate, or perchlorate. Ozonides are a promising group of oxygen sources, as well. The generators are usually ignited by a firing pin, and the chemical reaction is usually exothermic, making the generator a potential fire hazard. Potassium superoxide was used as an oxygen source on early crewed missions of the Soviet space program, in submarines for use in emergency situations, for firefighters, and for mine rescue.
A chlorine bomb is a small explosive device which uses the pressure of chemically produced chlorine gas or other chlorine-containing gases such as hydrogen chloride to produce an explosion. It is made with an airtight container part-filled with different types of chlorine tablet and other reagents. The reaction produces an expansive increase in pressure, eventually rupturing the container. Usually, such a device is not made on a large scale, often being manufactured from common household objects.
Dry-ice blasting is a form of carbon dioxide cleaning, where dry ice, the solid form of carbon dioxide, is accelerated in a pressurized air stream and directed at a surface in order to clean it.
Dimethylzinc, also known as zinc methyl, DMZ, or DMZn, is a toxic organozinc compound with the chemical formula Zn(CH3)2. It belongs to the large series of similar compounds such as diethylzinc.
An explosion is a rapid expansion in volume of a given amount of matter associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Explosions may also be generated by a slower expansion that would normally not be forceful, but is not allowed to expand, so that when whatever is containing the expansion is broken by the pressure that builds as the matter inside tries to expand, the matter expands forcefully. An example of this is a volcanic eruption created by the expansion of magma in a magma chamber as it rises to the surface. Supersonic explosions created by high explosives are known as detonations and travel through shock waves. Subsonic explosions are created by low explosives through a slower combustion process known as deflagration.
Many laboratories contain significant risks, and the prevention of laboratory accidents requires great care and constant vigilance. Examples of risk factors include high voltages, high and low pressures and temperatures, corrosive and toxic chemicals and chemical vapours, radiation, fire, explosions, and biohazards including infective organisms and their toxins.
The dry ice color show is a demonstration of the chemical formation of carbonic acid by the dissolution of dry ice in water. The dry ice color show is usually performed in classrooms to demonstrate the properties of acids and bases, their effect on pH indicators, and the sublimation of dry ice. Setup is simple and generally involves only minor hazards, the main one being the low temperature of dry ice, which can cause frostbite upon skin contact. The carbonic acid formed in the demonstration is a weak acid and is not hazardous, being present in numerous consumer products including tonic water, soda, and beer.
In fire and explosion prevention engineering, purging refers to the introduction of an inert purge gas into a closed system to prevent the formation of an ignitable atmosphere. Purging relies on the principle that a combustible gas is able to undergo combustion (explode) only if mixed with air in the right proportions. The flammability limits of the gas define those proportions, i.e. the ignitable range.