Dunt

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Dunting is a fault that can occur during the firing of ceramic articles. It is the "cracking that occurs in fired ceramic bodies as a result of a thermally induced stress" [1] and is caused by a "ware cooled too quickly after it has been fired". [2] [3]

Although usually occurring during, cooling dunts can also be caused by excessively fast heating rates. Heating dunts can be recognised by rounded edges to the cracks as the glaze matured after they occurred, whereas cooling dunts have sharp edges. [4] [5]

It has been found that bodies formulated with quartz rather than flint were more susceptible to dunting, especially on re-fire. It was postulated this may be related to the lower Young's modulus of the quartz based bodies. [6]

Dunting also occurs in wares produced from montmorillonite clay bodies due to the volume expansion of cristobalite during its inversion upon cooling. "The release of free silica, takes place in montmorillonite above 950 C, but almost double the silica is released, compared to kaolin. Therefore, clay bodies with high amounts of montmorillonite contain a high percentage of free silica after firing, which may cause the ware to crack during cooling.(Dunting)" [7]

See also

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<span class="mw-page-title-main">Earthenware</span> Nonvitreous pottery

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<span class="mw-page-title-main">Stoneware</span> Term for pottery or other ceramics fired at a relatively high temperature

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<span class="mw-page-title-main">Fire clay</span> Refractory clays used in ceramics manufacturing

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<span class="mw-page-title-main">Salt glaze pottery</span> Pottery with ceramic glaze made of salt

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<span class="mw-page-title-main">Frit</span> Fused, quenched and granulated ceramic

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This is a list of pottery and ceramic terms.

The room-temperature form of quartz, α-quartz, undergoes a reversible change in crystal structure at 573 °C to form β-quartz. This phenomenon is called an inversion, and for the α to β quartz inversion is accompanied by a linear expansion of 0.45%. This inversion can lead to cracking of ceramic ware if cooling occurs too quickly through the inversion temperature. This is called dunting, and the resultant faults are known as dunts. To avoid such thermal shock faults, cooling rates not exceeding 50 °C/hour have been recommended.

Pottery fracture results from stress within a ceramic body due to thermal expansion and contraction, shrinkage, and other forces. Poor drying or uneven compression and alignment of particles can result in low strength. Cracking may appear in greenware as well as each stage of the firing including bisqueware and glazed ware.

<span class="mw-page-title-main">Conservation and restoration of ceramic objects</span> Preservation of heritage collections

Conservation and restoration of ceramic objects is a process dedicated to the preservation and protection of objects of historical and personal value made from ceramic. Typically, this activity of conservation-restoration is undertaken by a conservator-restorer, especially when dealing with an object of cultural heritage. Ceramics are created from a production of coatings of inorganic, nonmetallic materials using heating and cooling to create a glaze. These coatings are often permanent and sustainable for utilitarian and decorative purposes. The cleaning, handling, storage, and in general treatment of ceramics is consistent with that of glass because they are made of similar oxygen-rich components, such as silicates. In conservation ceramics are broken down into three groups: unfired clay, earthenware or terracotta, and stoneware and porcelain.

<span class="mw-page-title-main">Biscuit (pottery)</span>

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<span class="mw-page-title-main">Kiln furniture</span>

Kiln furniture are devices and implements inside furnaces used during the heating of manufactured individual pieces, such as pottery or other ceramic or metal components. Kiln furniture is made of refractory materials, i.e., materials that withstand high temperatures without deformation. Kiln furniture can account for up to 80% of the mass of a kiln charge.

References

  1. "Standard Terminology of Ceramic Whitewares and Related Products." ASTM C242-01. ASTM International.
  2. "Dictionary of Ceramics", Third edition. A.Dodd A. D.Murfin. Institute of Materials. 1994. ISBN   0-901716-56-1
  3. "Dunting Temperature Measurement." K.Marshall, W.Roberts. British Ceramic Research Association. TN 143.1969.
  4. "Dictionary of Ceramics", Third edition. A.Dodd A. D.Murfin. Institute of Materials. 1994. ISBN   0-901716-56-1
  5. "Dunting - A Serious Problem Of Ceramics Industry." S.K.Mukherji. Indian Ceramics. 27, (2), 36, 1984.
  6. "Quartz V Flint. Pt.2. Aspects Related To Refire Dunting." K.Marshall, W.Roberts. British Ceramic Research Association. TN 141 Pt.2. 1969.
  7. "Clay Materials - For the self reliant potter", Henrik Norske. GTZ 1990; 98 pages